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Structural aspects of two α‐dihydrazones displaying a complete survey of intermolecular interactions
Carlos Bustos Luis Alvarez‐Thon Ricardo Baggio 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(12):1106-1113
The compounds (2′E,2′E)‐2,2′‐(propane‐1,2‐diylidene)bis[1‐(2‐nitrophenyl)hydrazine], C15H14N6O4, (I), and (2Z,3Z)‐ethyl 3‐[2‐(2‐nitrophenyl)hydrazinylidene]‐2‐[2‐(4‐nitrophenyl)hydrazinylidene]butanoate tetrahydrofuran hemisolvate, C18H18N6O6·0.5C4H8O, (II), are puzzling outliers deviating from a general synthetic route aimed at the preparation of substituted pyrazoles. Possible reasons for this outcome, which is exceptional in an otherwise firmly established synthetic procedure, are analyzed. Compound (I) is unsolvated, while compound (II) crystallizes with a tetrahydrofuran solvent molecule lying on an inversion centre. The ethoxycarbonyl chain of (II), in turn, appears disordered into two equally populated (50%) moieties. In both structures, a plethora of different commonly occurring weak intermolecular interactions [viz. π(phenyl)...π(phenyl), π(C=N)...π(C=N), π(phenyl)...π(C=N), N—H...O and C—H...O] appear responsible for the crystal stability. Much less common are the short O(nitro)...O(nitro) contacts which are observed in the structure of (I), an example of unusual `electron donor–acceptor' (EDA) interactions. 相似文献
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