全文获取类型
收费全文 | 534篇 |
免费 | 101篇 |
国内免费 | 42篇 |
专业分类
化学 | 248篇 |
晶体学 | 2篇 |
力学 | 2篇 |
数学 | 1篇 |
物理学 | 424篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 14篇 |
2021年 | 9篇 |
2020年 | 8篇 |
2019年 | 11篇 |
2018年 | 12篇 |
2017年 | 11篇 |
2016年 | 19篇 |
2015年 | 19篇 |
2014年 | 26篇 |
2013年 | 35篇 |
2012年 | 35篇 |
2011年 | 26篇 |
2010年 | 14篇 |
2009年 | 25篇 |
2008年 | 20篇 |
2007年 | 27篇 |
2006年 | 26篇 |
2005年 | 19篇 |
2004年 | 25篇 |
2003年 | 24篇 |
2002年 | 28篇 |
2001年 | 21篇 |
2000年 | 19篇 |
1999年 | 23篇 |
1998年 | 16篇 |
1997年 | 22篇 |
1996年 | 28篇 |
1995年 | 17篇 |
1994年 | 21篇 |
1993年 | 17篇 |
1992年 | 15篇 |
1991年 | 10篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1987年 | 6篇 |
1986年 | 2篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1967年 | 1篇 |
排序方式: 共有677条查询结果,搜索用时 15 毫秒
1.
Zhengmao Zhu 《Applied Surface Science》2005,252(2):303-310
The reactivity of the surface of poly(ethylene terephthalate) (PET) film under 172 nm UV irradiation (xenon excimer lamp) towards nitrogen-borne 1-octene, n-nonane and heptafluorodecene vapor was investigated. Materials receiving from 0 to 24 J/cm2 of UV were examined by X-ray photoelectron spectroscopy (XPS), time of flight secondary ion mass spectroscopy (ToF/SIMS), water and mineral oil contact angle measurement and atomic force microscopy (AFM). A uniform nanoscale layer developed on PET surface attributed to the grafting reaction between photolytically-produced polymer radicals and vapor phase molecules. 相似文献
2.
P. M. Larionov A. N. Malov M. M. Mandrik N. A. Maslov A. M. Orishich 《Journal of Applied Spectroscopy》2003,70(1):38-42
We investigated the laser-induced fluorescence spectra (LIF) of porcine cardiac tissues with different degrees of viability. The data obtained are compared with the results of routine histological investigations and also with the experiments performed with the use of fluorescent probes. It has been found with a high degree of reliability that the loss of the viability of the myocardium tissue leads to the alteration of its LIF spectra. This can be used for low-invasive rapid control of transplant viability in the process of its preparation and during surgery. 相似文献
3.
4.
In photochemical vapor deposition of aluminum film on silicon using dimethylaluminum hydride, (CH3)2AlH, a surface reaction dominated below a (CH3)2AlH pressure of 0.3 m Torr at 200°C, which was induced only with the 160 nm band emitted from a deuterium lamp. A gas-phase reaction occurred above 0.3 mTorr at 200°C, which could be induced by both 160 nm and 240 nm emission bands from the lamp. To distinguish between surface ad gas-phase reactions, a thickness profile was used. At 240°C the surface reaction could be induced even by the 240 nm band, while the deposits formed under illumination of the two bands were thinner than those obtained with only the 240 nm band, indicating occurrence of vacuum ultraviolet (VUV)-enhanced desorption. The mechanism responsible for the observed wavelength dependence in unclear. The electrical resistivity of the films deposited at 200°C was 4.5 μΩ cm, which did not change with wavelength. 相似文献
5.
本文采用了一种简单的功率监测法,观察了KrF准分子激光对掺锗光纤折射率影响的非线性过程。观察到子纤芯折射率扰动过程中非稳定现象、饱和现象和折射率扰动的非线性。 相似文献
6.
7.
8.
9.
Yoshihiro Itoh Masamitsu Inoue Tomoko Takahashi Akira Hachimori Satoshi Suzuki 《Journal of polymer science. Part A, Polymer chemistry》1995,33(7):1069-1074
Alternating and random copolymers of 9-phenanthrylmethyl methacrylate or 2-(9-carbazolyl)ethyl methacrylate with styrene were synthesized and their fluorescence properties were examined. There was no noticeable difference in the spectral features of the alternating and random copolymers in tetrahydrofuran (THF), demonstrating that this type of polymers have no quenching sites in the polymer chains. The fluorescence quenching studies indicated that the alternating copolymers permitted singlet-state energy migration as efficiently as the corresponding random copolymers but less efficiently than the random copolymers with higher chromophore contents. These results strongly suggest that to be chromophores close to each other is most important for facilitation of an intramolecular energy migration. © 1995 John Wiley & Sons, Inc. 相似文献
10.
L.M. Ilharco A.M. Santos M.J. Silva J.M.G. Martinho 《Journal of Sol-Gel Science and Technology》1997,8(1-3):877-882
The influence of the acid catalyst concentration on the structural evolution of a sol-gel system was studied by doping TEOS
based starting solutions with two fluorescent probes: a polystyrene chain (M
n
=1700) and a much shorter alkane chain (M=172), both of them labeled at both ends with 1-pyrenyl. For this purpose, each probe was incorporated in two TEOS∶H2O∶C2H5OH mixtures (molar ratios 1∶4∶1), one at pH 1.2 and the other at pH 2.5 (respectively below and above the isoelectric point
of silica). Very low concentrations of the probes were used (≤10−6
M), so the pyrene dimmers and excimers were formed only intramolecularly. The ratios of excimer to monomer fluorescence intensities
at excitation wavelength of 360 nm (where mainly the ground state pyrene dimmers are excited) were studied as a function of
time. Different evolutions of these ratios were observed, which allowed us to predict that the silica structure developsvia the formation of primary particles, even at pH values below the isoelectric point of silica, where it is not possible to
directly detect their formation. 相似文献