全文获取类型
收费全文 | 689篇 |
免费 | 14篇 |
国内免费 | 92篇 |
专业分类
化学 | 697篇 |
晶体学 | 7篇 |
力学 | 49篇 |
数学 | 2篇 |
物理学 | 40篇 |
出版年
2023年 | 10篇 |
2022年 | 10篇 |
2021年 | 13篇 |
2020年 | 20篇 |
2019年 | 13篇 |
2018年 | 8篇 |
2017年 | 16篇 |
2016年 | 20篇 |
2015年 | 12篇 |
2014年 | 15篇 |
2013年 | 45篇 |
2012年 | 46篇 |
2011年 | 44篇 |
2010年 | 35篇 |
2009年 | 45篇 |
2008年 | 54篇 |
2007年 | 56篇 |
2006年 | 30篇 |
2005年 | 29篇 |
2004年 | 33篇 |
2003年 | 24篇 |
2002年 | 16篇 |
2001年 | 22篇 |
2000年 | 15篇 |
1999年 | 22篇 |
1998年 | 12篇 |
1997年 | 10篇 |
1996年 | 11篇 |
1995年 | 20篇 |
1994年 | 19篇 |
1993年 | 13篇 |
1992年 | 12篇 |
1991年 | 7篇 |
1990年 | 6篇 |
1989年 | 6篇 |
1988年 | 6篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有795条查询结果,搜索用时 0 毫秒
1.
A method employing a wide pore polymeric reversed phase column has been developed for the separation of most of the chlorophylls and related compounds previously described as occurring in marine microalgae. The high selectivity toward molecular shape of this kind of stationary phase has enabled compounds of very similar structure, such as chlorophylls c1, c2 and Mg-divinylpheoporphyrin a5 monomethyl ester, and chlorophyll a and the phytol-substituted chlorophyll c-like pigments, which commonly coelute on monomeric bonded phases, to be resolved in a single run. Some of these pigments, formerly thought to be a single compound, have, in fact, been demonstrated to be groups of two or more. The method has been successfully applied to both algal cultures and natural sea water samples. When visible light absorbance detection was used, the method proved suitable for separation of various carotenoids. 相似文献
2.
Monodisperse polyaniline nanoparticles (PAPSSA) were synthesized from an oxidative dispersion polymerization using poly(sodium 4-styrenesulfonate) (PSSA) as both a polymeric stabilizer and a dopant agent due to its acidity. The nanoparticles were being stabilized with two different molecular weight of PSSA. Size effect of PAPSSA particles were examined by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and dynamic light scattering (DLS). The d.c. electrical conductivity of composite films on the glass substrate was measured by a four-probe method. It was found that the electrical properties of the composite films are affected by the content of nano-sized polyaniline and different molecular weights of stabilizer in the poly(vinyl alcohol) (PVA) matrix. 相似文献
3.
The chemical mechanism of the precipitation of lead titanium peroxohydroxide particles in a solution of nitrilotriacetate (NTA) complexes of lead and titanium peroxo-hydroxide is envisioned as the interaction between cations of lead hydroxide and anions of polymeric titanium peroxo-hydroxide. 相似文献
4.
GeunHyung Kim 《European Polymer Journal》2005,41(8):1729-1737
The effect of thermo-physical properties, relative humidity and stiffness on the warpage of a poly(methyl methacrylate) (PMMA) diffusing plate modified with glass fibers in a direct-lit backlight unit (BLU) of a liquid crystal display (LCD) was investigated. The warpage of the PMMA diffusing composites modified with a glass fiber were significantly reduced relative to that of a conventional PMMA diffusing plate. Luminance and scattering characteristics of the PMMA diffusing composites having 5, 10, 20 vol% of glass fibers were measured. Although the luminance of the composite was lowered as increasing the volume fractions of glass fibers in the PMMA composites, good brightness uniformity of the composites on a light source was obtained. 相似文献
5.
Complex films of crosslinked poly(methylsiloxane-co-ethylene oxide) and lithium perchlorate were prepared. These solid state polymeric electrolytes show a markedly higher ionic conductivity, and excellent flexibility. The ionic conductivity of the network films closed to 10~(-5) Scm~(-1) at room temperature. The effects of Li~+ content, species and contents of crosslinking agents, molecular weight of poly(ethylene oxide) and temperature on the ionic conductivity of the network films were also investigated. 相似文献
6.
R. Dustan Myrex Gary M. Gray Young-Jin Wright Prakash C. Bharara Keith E. Branham 《European Polymer Journal》2003,39(6):1105-1115
Polymeric phosphonate esters are an interesting class of organophosphorus polymers because both the polymer backbone and phosphorus substituents can be modified. These polymers have been prepared by ring-opening polymerizations of cyclic phosphites, stoichiometric polycondensations of dimethyl phosphonate with diols in conjunction with diazomethane treatment and by transesterification of polyphosphonate oligomers. Our initial attempts to prepare high molecular weight polymeric phosphonate esters by the transesterification methods were unsuccessful. Results indicate that the reactions of dimethyl phosphonate with diols to form polyphosphonate oligomers with only methyl phosphonate end groups are plagued by a serious side reaction that forms phosphonic acid end groups. These end groups do not participate in the transesterification reaction and limit the molecular weights of the polymers that can be obtained. The phosphonic acid end groups can be converted into reactive methyl phosphonate end groups by treatment with diazomethane, however diazomethane is explosive and the polymerization is slow. An alternative route for the production of high molecular weight polymers is the transesterification of the 1,12-bis(methyl phosphonato)dodecane, formed by the reaction of excess dimethyl phosphonate and 1,12-dodecanediol, with a Na2CO3 promoter. This allows polymers with molecular weights of up to 4.5×104 to be prepared, and no phosphonic acid end groups are observed in these polymers. Thermal analyses of the poly(1,12-dodecamethylene phosphonate) have shown that this polymer has reasonable thermal stability (onset of thermal decomposition at 273 °C). This polymer also undergoes a cold crystallization process at 15 °C similar to that which has been observed in some polyesters, polyamides and elastomers. 相似文献
7.
8.
本文以多种聚醚为软段,二异氰酸酯(MDI和TDI)为硬段,合成了多嵌段聚醚聚氨酯,以此聚氨酯为基材,与NaH及1,3-丙碳酸内酯反应,进一步合成了一系列不同离子化程度的阴离子型碳化聚氨酯离聚物,用交流阻抗谱仪测定了样品的阻抗谱,由此计算出样品的离子电导率。研究结果表明其他条件相同时,以聚乙二醇(PEG)为软段的样品具有较高的离子电导率;以聚环氧丙烷(PPO)为软段的样品次之,以聚四氢呋喃(PTMO)为软段的样品最低,对于离子化程度不同的聚氨酯离聚物以金属离子和烷氧单元之比为0.05时导电性能最好。阳离子为Li+和Na+的样品具有相近的离子电导率。 相似文献
9.
Hidenobu Shimizu Tomonari Shiraishi Risei Wada Masaru Okabe 《Colloid and polymer science》2006,285(1):107-111
Soap-free emulsion copolymerization of 2, 2, 2-trifluoroethyl acrylate (3FEA) with styrene was carried out by using potassium persulfate as an initiator, and the effects of the weight fraction of 3FEA in the monomer feed on the kinetics and the particle size were investigated. Monomer conversions were followed by a gravimetric method, revealing that the overall polymerization rate increased exponentially with an increase in the weight fraction of 3FEA. According to dynamic light scattering measurement, the final particle size was found to decrease with an increase in the weight fraction of 3FEA. The number of particles for 3FEA homopolymerization was roughly twice as large as that at the fraction of 0.9, although both fractions had the almost same polymerization rates. These results indicate that soap-free emulsion homopolymerization of 3FEA would proceed not only inside the polymer particles but also in the aqueous phase throughout the polymerization. 相似文献
10.