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排序方式: 共有690条查询结果,搜索用时 15 毫秒
1.
Q. Sun Q. Wang X.G. Gong V. Kumar Y. Kawazoe 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(1):77-81
We report results of the atomic and electronic structures of Al7C cluster using ab initio molecular dynamics with ultrasoft pseudopotentials and generalized gradient approximation. The lowest energy structure is
found to be the one in which carbon atom occupies an interstitial position in Al7 cluster. The electronic structure shows that the recent observation [Chem. Phys. Lett. 316, 31 (2000)] of magic behavior of Al7C- cluster is due to a large highest occupied and lowest unoccupied molecular orbital (HOMO-LUMO) gap which makes Al7C- chemically inert. These results have further led us to the finding of a new neutral magic cluster Al7N which has the same number of valence electrons as in Al7C- and a large HOMO-LUMO gap of 1.99 eV. Further, calculations have been carried out on (Al7N)2 to study interaction between magic clusters.
Received 28 July 2001 相似文献
2.
P. Adamson 《Optics & Laser Technology》2002,34(7):561-568
The differential reflection characteristics for ultrathin inhomogeneous dielectric film on absorbing substrate are investigated in the long-wavelength approximation. The obtained first-order expressions for differential reflectivity and changes in the ellipsometric angles caused by ultrathin layer are of immediate interest to the solution of the inverse problem. The method to determine the averaged values (not the realistic profile) of refractive index for inhomogeneous nanometric films are shown. The novel possibilities for determining the dielectric constant and thickness of nanoscale homogeneous films by the differential ellipsometric and reflectivity measurements are developed, and a simple method to estimate whether the nanometric film is homogeneous or not is also discussed. 相似文献
3.
We discuss the spectral lineshapes of reflectance and modulated reflectance (MR) measurements on optoelectronic device structures such as epi-layers, quantum wells (QWs), vertical-cavity surface emitting-lasers (VCSELs) and resonant-cavity light-emitting diodes (RCLEDs). We consider the various methods for the extraction of built-in electric fields and band-gap energies from Franz-Keldysh oscillations (FKO), using the example of a tensilely strained InGaAs QW system, whose InGaAsP barriers yield strong FKO. We describe how critical point transition energies can be easily obtained by eye from Kramers-Kronig (KK) transforms of low field or QW modulation spectra, using the example of the modulated transmittance spectra of dilute-nitrogen InGaAsN p-i-n structures. We also discuss how the ordinary reflectivity spectrum, usually acquired at the same time as the MR signal, may also be exploited to extract layer thicknesses and compositions, and information about the active QW absorption spectrum in VCSEL and RCLED structures. 相似文献
4.
C. Bréchignac Ph. Cahuzac F. Carlier C. Colliex M. de Frutos N. Kébaïli J. Le Roux A. Masson B. Yoon 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):265-268
We studied shape relaxation of nano-fractal islands,
during annealing, after their growth from antimony cluster
deposition on graphite surface. Annealing at
180°C shows evidence of an increase
of the fractal branch width with time followed by branch
fragmentation, without changing the fractal dimension. The time
evolution of the width of the arm suggests the surface
self-diffusion mechanism as the main relaxation process. With
Monte Carlo simulations, we confirmed the observed behavior.
Comparison is done with our previous results on fragmentation of
nano-fractal silver islands when impurity added to the incident
cluster promotes rapid fragmentation by surface self-diffusion
enhancement [1]. 相似文献
5.
S. Sasa A. Nakashima Y. Nakajima M. Inoue 《Physica E: Low-dimensional Systems and Nanostructures》2004,20(3-4):224
We fabricated nanoscale open-dot structures in an InAs surface inversion layer using an atomic-force-microscope oxidation process. Due to its superior nanofabrication capability, small open-dot structures with the feature size ranging between 100 and 300 nm were successfully fabricated. The magnetoresistance signal measured at 4.2 K showed reproducible fluctuations and a periodic oscillation component that varies in both amplitude and periodicity depending on the dot size. We show that the period of the oscillations corresponds to that of the Aharonov–Bohm effect and propose that the possible mechanism for the oscillations is due to the formation of a one-dimensional electron channel enclosing the open-dot structure as a result of the electron transfer from the InAs oxide to InAs. 相似文献
6.
Microemulsions are becoming increasingly complex systems by containing more sophisticated surfactants, polymers, biomolecules, inorganic nanoparticles, etc. The detailed understanding of such more complex systems requires increasingly more refined and comprehensive characterisation. This is typically done by the combination of complementary techniques and is aided by the fact that several experimental methods have been improved (such as electron microscopy) in recent times, new ones have become available (such as fluorescence correlation spectroscopy), and the theoretical understanding of structural data is advancing. 相似文献
7.
J. H. Knox 《Chromatographia》1988,26(1):329-337
Summary Four Capillary Electroseparation methods are distinguished. All have an ultimate efficiency limited only by axial diffusion and are in principle capable of achieving 106 plates in <1 hour.The main limitation to performance arises from Ohmic heating of the electrolyte. While forced convection at 10ms–1 is recommended to keep tubes cool, the parabolic temperature profile within the electrolyte limits the tube bore which can be used. A simple limiting expression is derived: (dc/m)3 (E/kV m–1)3 (c/mol dm–3) <3.3×109.Values of constants underlined 相似文献
8.
Adam Bange Jian Tu Xiaoshan Zhu Chong Ahn H. Brian Halsall William R. Heineman 《Electroanalysis》2007,19(21):2202-2207
A microbead based sandwich immunoassay for MS2 bacteriophage was developed using an interdigitated array (IDA) electrode with nanoscale dimensions (220 nm electrode width, 620 nm gap). The IDA was fabricated using an electron beam lithographic lift‐off technique. After an antibody‐assisted capture of MS2 using paramagnetic microbeads, a β‐galactosidase labeled secondary antibody was used to convert p‐aminophenyl‐β‐D ‐galactopyranoside (PAPG) into the redox active p‐aminophenol (PAP). Amperometric detection of PAP with IDA electrodes at +300 and ?200 mV vs. a Ag/AgCl reference electrode was used to measure the result, detecting MS2 concentrations as low as 10 ng/mL. 相似文献
9.
Porous silica CPG-10 has been characterised by adsorption of benzene before and after modification with trimethylchlorosilane. The Brunauer–Emmet–Teller (BET) specific surface areas were determined where possible. Modification of CPG-10 reduces its adsorption for benzene and hence reduces the BET specific surface area, with the extent of reduction depending on the extent of modification. For a fully modified sample with the highest surface concentration of trimethylsilyl groups, the adsorption isotherm changes from type IV of the unmodified sample to type V. The hysteresis loop size and position are also altered. A mechanism for multilayer adsorption and capillary condensation in modified porous silica is proposed. 相似文献
10.
J. Zhu 《Mathematical Methods of Operations Research》1992,36(4):359-377
We present a primal-dual path following interior algorithm for a class of linearly constrained convex programming problems with non-negative decision variables. We introduce the definition of a Scaled Lipschitz Condition and show that if the objective function satisfies the Scaled Lipschitz Condition then, at each iteration, our algorithm reduces the duality gap by at least a factor of (1–/n), where is positive and depends on the curvature of the objective function, by means of solving a system of linear equations which requires no more than O(n3) arithmetic operations. The class of functions having the Scaled Lipschitz Condition includes linear, convex quadratic and entropy functions. 相似文献