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1.
Marius Lupu Adnana Zaulet Prof. Dr. Francesc Teixidor Prof. Dr. Eliseo Ruiz Prof. Dr. Clara Viñas 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(18):6888-6897
The metallacarborane [3,3′‐Co(1,2‐closo‐C2B9H11)2]? has been synthesized. This species allows the formation of redox couples in which both partners are negatively charged. The E1/2 potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3′‐Co(1,2‐closo‐C2B9H7I4)2]? is the most favorable, as it is isolatable and stable in air. A DFT study on stability and redox potentials of complexes has been performed. 相似文献
2.
本文证明了d2k =δ2k =d2k ≥b2k,其中d2k ,δ2k , b2k分别表示A(BlMp)在lNq下的Kolmogorov,线性,Bernstein 2k-宽度,d2k 表示AT(BlN相似文献
3.
The potential response of the platinum indicator electrode in the uncatalyzed bromate oscillator (UBO) with three different
substrates, namely gallic acid (GA), pyrogallol (PG) and veratraldehyde (VA) has been analyzed. The large amplitude oscillations
obtained with a Pt electrode are due to the sequential response of the indicator electrode to the varying concentration ratios
of the redox couples present in the reaction mixture. 相似文献
4.
林乃煊 《广东微量元素科学》1995,2(10):60-63
通过对人体五行微量元素与食物吸收微量元素影响因素分析,采用“健脾开胃”均衡食疗配方,对百草元营养包的研制作了全面的介绍和论述。经临床患者食疗结果表明:总有效率为98%.该产品达到了预期设计目标与均衡食疗要求. 相似文献
5.
采用活化酯法,将马兜铃酸A分别与牛血清蛋白(BSA)和卵清蛋白(OVA)偶联,得到免疫抗原马兜铃酸A-BSA和包被抗原马兜铃酸A-OVA.利用马兜铃酸A-BSA免疫Bal b/c小鼠,制得鼠单克隆抗体1A11,单抗效价为2×104;单抗为IgG1类,轻链为κ型;与其结构类似物马兜铃酸B、C和D的交叉反应率分别为2.8%,3.5%和31.2%.基于抗马兜铃酸A单克隆抗体的间接竞争酶联免疫分析方法(icELISA)的IC50为1.9 μg/L,检测范围为0.5~7.5 μg/L.icELISA添加回收率为86%~97%,相对标准偏差在5.2%~11.1%之间.利用所建立的icELISA测定了6个中药材和5个中成药中马兜铃酸A的含量,并用高效液相色谱法(HPLC)进行了验证,其中关木通、广防己、天仙藤、马兜铃和青木香中均检测出马兜铃酸A,而川木通和5个中成药中未检测到马兜铃酸A.结果表明: 本方法可用于中药中马兜铃酸A的快速检测. 相似文献
6.
John Greenberg 《Physics in Perspective (PIP)》2005,7(1):66-106
Nobel laureate William A. Fowler recalls his early education in physics; his part in the history of nuclear physics at the California Institute of Technology in the 1930s; parallel efforts elsewhere, particularly at Berkeley and the Department of Terrestrial Magnetism in Washington,D.C.; his contacts with J. Robert Oppenheimer; and his work with Charles C. Lauritsen and Tommy Lauritsen before and after World War II.John Greenberg received his Ph.D. degree from the University of Wisconsin and was Caltech research fellow in history from 1980–1984. The Editors were saddened to learn that he died while this interview was in press. Requests for reprints may be directed to Judith R. Goodstein, Institute Archives 015A-74, Caltech, Pasadena, CA 91125 USA; e-mail: jrg@caltech.edu. 相似文献
7.
Properties of GaAs single crystals grown at low temperatures by molecular beam epitaxy (LTMBE GaAs) have been studied. The
results show that excessive arsenic atoms of about 1020 cm−3 exist in LTMBE GaAs in the form of arsenic interstitial couples, and cause the dilation in lattice parameter of LTMBE GaAs.
The arsenic interstitial couples will be decomposed, and the excessive arsenic atoms will precipitate during the annealing
above 300°C. Arsenic precipitates accumulate in the junctions of epilayers with the increase in the temperature of annealing.
The depletion regions caused by arsenic precipitates overlap each other in LTMBE GaAs, taking on the character of high resistivity,
and the effects of backgating or sidegating are effectively restrained. 相似文献
8.
Phoebe Y.T. Hon 《Microchemical Journal》2011,98(1):44-50
This paper presents an international proficiency testing program (APLAC T065) on two trace elements, cadmium and lead, in an herbal sample, Herba Desmodii Styracifolii. The program was registered with a total of 109 laboratories from 42 countries. The assigned reference values of the analytes for performance assessment were provided by the organizers using an accurate gravimetric isotope dilution inductively coupled plasma-mass spectrometry technique. z-Score was used as the numerical indicator to interpret participants' competence. The between-laboratory variations for cadmium and lead were respectively 18.7% and 19.8% and the consensus values were found to be consistent with the assigned reference values. Twenty-two participants gave at least one unsatisfactory z-score, but the performance of the majority of participants on the analysis of cadmium and lead in herbal matrix was generally good when compared with the assigned reference values. 相似文献
9.
Paul D. Beer Christopher G. Crane Jonathan P. Danks Philip A. Gale Jerome F. McAleer 《Journal of organometallic chemistry》1995,490(1-2):143-148
New polyferrocene bis benzo-15-crown-5 ligands have been prepared and shown to form 1:1 intramolecular sandwich complexes with the potassium cation. Electrochemical investigations reveal that both receptors undergo small anodic perturbations of the respective ferrocene-ferrocenium redox couples in the presence of alkali metal cations. 相似文献
10.
荆芥中微量元素的初级形态分析 总被引:1,自引:0,他引:1
对荆芥中微量元素铁、铜、锰、锌的初级形态进行了研究,采用火焰原子吸收光谱法(FAAS)测定了各微量元素的含量。结果表明,以HNO3和H2O2混合液作为消解剂能彻底消解样品。各元素在水提液中的含量均低于原药材中的含量,微量元素铁、铜、锰、锌的提取率分别为:19.7%,20.5%,38.6%和34.5%,大部分微量元素仍残留在残渣中。 相似文献