KAlF4：Ce,Tb磷光体的发光特性及Ce^3＋对Tb^3＋的敏化作用

采用溶液反应法和高温固相反应法合成了ＫＡ１Ｆ４基质化合物及ＫＡ１Ｆ：Ｃｅ，Ｔｂ磷光体，测定了磷光体的激发光谱和发射光谱，研究了在碱金属氟铝酸盐基质中Ｃｅ＾３＋对Ｔｂ＾３＋的能量传递，根据Ｃｅ＾３＋，Ｔｂ＾３＋在ＫＡｌＦ４中的能级关系，分析了其发光特性和Ｃｅ＾３＋对Ｔｂ＾３＋能量传递过程。     

Molecule-Based Magnets with 1D Chain Structure of Bifurcated H-Bonding: Syntheses,Structure, and Magnetic Properties

Two complexes [PyH][Ni(Mnt)₂] (I) and [QlH][Ni(Mnt)₂] (II) (Mnt^2– = maleonitriledithiolate, [PyH]⁺ = pyridinium, [QlH]⁺ = quinolinium) were synthesized and characterized by elemental analysis and IR spectra. ESR spectra of polycrystalline samples collected at room temperature are isotropic with g = 2.039 for Iand anisotropic with g _z = 1.997, g _y g _x = 2.102 (g _av = 2.068) for II. The magnetic susceptibility data of I and II have been measured in the temperature range of 2–300 K. The results obtained suggest the antiferromagnetic coupling interactions between neighboring Ni³⁺ ions for I and ferromagnetic coupling interactions for II, respectively. Based on the crystal structure analysis of I, the magnetic properties of two complexes were discussed.     

值得玩味的几道竞赛题

Through the analysis of several valuable chemical contest problems, the students' spatial visualization and divergent thinking abilities were improved, and the teaching's advice was provided.     

直线上时间随机环境下随机游动的渐近性质

在状态空间是可数情形下,本文给出了时间随机环境下随机游动的一个一般模型.随后,在环境是独立同分布情形下得到了直线上时间随机环境下紧邻随机游动的一个常返与暂留准则和强大数定律;最后讨论了其中心极限定理,它类似与简单随机游动的相应结果.     

Sierpinski 地毯上S4模型的临界特性

通过键移动重整化群的方法, 分析了Sierpinski 地毯上S⁴模型的临界行为, 得到了系统的临界点. 由得到的结果可知, 本系统不仅有一个高斯不动点, 而且还存在着一个Wilson Fisher不动点, 把它与Sierpinski 地毯上的高斯模型相互对比, 发现本系统的临界点变化很大. 这说明这两个系统隶属于两个不同的普适类.     

双连续微乳体系中PbS纳米管的控制合成(英文)

PbS nanotubes were synthesized by the tiny water channels in bicontinuous microemulsions consisted of p-octyl polyethylene glycol phenylether (OP)/n-amyl alcohol/cyclohexane/water. The possible formation mechanism of PbS nanotubes is also discussed based on their shape evolutions. The results indicate that the formation of PbS nanotubes is probably via the process of the nucleation, growth, assemblage and crystallization.     

离子对化合物[(IBz)_2Im](TCNQ)的合成与结构表征(英文)

A novel compound [(IBz)2Im](TCNQ) [(IBz)2Im=1,3-bis(4-iodobenzyl) imidazole cation, TCNQ-=7,7,8,8-tetracyanoquinodimethanide anion] was synthesized by the reaction of [(IBz)2Im]Br and LiTCNQ in CH3OH and its structure was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P21/c with a=1.147 35(18) nm, b=2.028 1(3) nm, c=1.264 1(2) nm, β=104.73(0)°, V=2.666(65) nm3, Z=4, C29H19I2N6, Mr= 705.30, Dc=1.757 g·cm-3, R1=0.053 2 and wR2=0.111 2. The structure analysis shows that the anions are stacked into column with isolated π-dimers, and there is one type of TCNQ entries (TCNQ-), in agreement with the IR spectra analysis of the compound. The most prominent structural features are the completely segregated stacking columns of the TCNQ-anions and [(IBz)2Im]+ cations. CCDC: 759523.     

迭代法计算多元酸碱滴定的pH

介绍了迭代法计算多元弱酸碱滴定pH计算原理,使用一个公式,用Excel计算多元酸碱滴定过程中溶液pH值,列举了H3PO4和Na2CO3滴定的pH值计算方法.     

Preparation and crystal structure determination of Eu27Ti20X2S54O12 (X ≈ I0.35 Cl0.65)

The structure of the new compound Eu₂₇T₂₀X₂S₅₄O₁₂ (X ≈ I_0.35 Cl_0.65), prepared by solid state reaction, contains _∞²[(Ti₄S₂O₄)(Ti₂S₁₀)_4/2] planes built up from rutile-like chains that cross perpendicularly. Two [TiS₆] octahedra separate the [Ti₄S₂O₄] clusters at the chain intersections. These planes are separated by a corrugated layer of [Ti₃S₈O₄] triplets of face-sharing Ti-centered octahedra. Five crystallographically independent europium ions are seven- to nine-coordinated.     

一维链状配合物[BrBzPy][Ni(dmit)2]的合成和红外光谱研究

合成了一种新的化合物[BrBzPy][Ni(dmit)2](1),并进行了红外光谱表征.晶体的结构结果表明它的空间点群为P21/c,a=0.627 5(1)nm,b=1.743 8(3)nm,c=2.283 9(3)nm,α=90°,β=9.187(1)nm,γ=90°,V=2.497(7)nm3,Z=4,Mr=700.57,Dc=1.863 g·cm-3.晶体中[Ni(dmit)2]-非常接近平面,共轭性相当显著,且成为一维链状结构.