Asymmetric synthesis of abietane diterpenoids via B-alkyl Suzuki-Miyaura coupling. Formal total asymmetric synthesis of 12-deoxyroyleanone and cryptoquinone

A convergent synthetic strategy for abietane diterpenoids via B-alkyl Suzuki-Miyaura coupling and Lewis acid-mediated cyclization reactions is established. Asymmetric total synthesis of 12-deoxyroyleanone, an antileishmanial diterpene, is described.     

Lithium salt dissociation in non-aqueous electrolytes modeled by ab initio calculations

The dissociation of seven different lithium salts has been investigated using standard computational chemistry methods addressing the solvation via direct coordination by solvent molecules and via computing the total free energies in solution by a continuum method. The different methods to study lithium salt dissociation are evaluated with respect to total and partial contributions. Recommendations for further use as a qualitative tool are made.     

Continuum source atomic absorption spectrometry and detector technology: A historical perspective

The close relationship between the development of Continuum Source AAS (CS AAS) as a technique for element analysis and the availability of suitable detectors is reviewed, beginning with the photoplate and culminating in state of the art Charge-Coupled Devices (CCDs). The review is organized to follow the historical sequence of development but emphasizes in particular the appropriateness of detector technologies to the development for simultaneous and sequential CS AAS techniques. The essential role of certain aspects of detector performance is elucidated and it is shown that since only solid-state CCD detectors have become available can competitive CS AAS instrumentation be realized.     

Ultra <Emphasis Type="Italic">LI</Emphasis>-ideals in lattice implication algebras and <Emphasis Type="Italic">MTL</Emphasis>-algebras

A mistake concerning the ultra LI-ideal of a lattice implication algebra is pointed out, and some new sufficient and necessary conditions for an LI-ideal to be an ultra LI-ideal are given. Moreover, the notion of an LI-ideal is extended to MTL-algebras, the notions of a (prime, ultra, obstinate, Boolean) LI-ideal and an ILI-ideal of an MTL-algebra are introduced, some important examples are given, and the following notions are proved to be equivalent in MTL-algebra: (1) prime proper LI-ideal and Boolean LI-ideal, (2) prime proper LI-ideal and ILI-ideal, (3) proper obstinate LI-ideal, (4) ultra LI-ideal. This work was supported by the Zhejiang Provincial Natural Science Foundation of China (Grant No. Y605389) and K. C. Wong Magna Fund in Ningbo University.     

An asymptotic approach to the problem of the free oscillations of a beam

Equations describing the free small longitudinal and transverse oscillations of a straight elastic beam of rectangular cross section are obtained using the plane linear theory of elasticity and the method of integrodifferential relations. The initial system of partial differential equations is reduced to a system of ordinary linear differential equations with constant coefficients. The effect of the geometrical and elastic characteristics of the beam on the frequency and form of the natural oscillations is investigated. For longitudinal motions it is shown that different types of natural displacements and internal stresses of the beam exist. For transverse oscillations, it is found that there are frequency zones corresponding to different forms of the solutions of the characteristic equation obtained using the proposed model.     

THE DIMENSION FOR RANDOM SUB-SELF-SIMILAR SET

In this article,the Hausdorff dimension and exact Hausdorff measure function of any random sub-self-similar set are obtained under some reasonable conditions.Several examples are given at the end.     

Fractional green function for linear time-fractional inhomogeneous partial differential equations in fluid mechanics

This paper deals with the solutions of linear inhomogeneous time-fractional partial differential equations in applied mathematics and fluid mechanics. The fractional derivatives are described in the Caputo sense. The fractional Green function method is used to obtain solutions for time-fractional wave equation, linearized time-fractional Burgers equation, and linear time-fractional KdV equation. The new approach introduces a promising tool for solving fractional partial differential equations.     

A Markov model of financial returns

We address the general problem of how to quantify the kinematics of time series with stationary first moments but having non stationary multifractal long-range correlated second moments. We show that a Markov process is sufficient to model important aspects of the multifractality observed in financial time series and propose a kinematic model of price fluctuations. We test the proposed model by analyzing index closing prices of the New York Stock Exchange and the DEM/USD tick-by-tick exchange rates obtained from Reuters EFX. We show that the model captures the characteristic features observed in actual financial time series, including volatility clustering, time scaling and fat tails in the probability density functions, power-law behavior of volatility correlations and, most importantly, the observed nonuniversal multifractal singularity spectrum. Motivated by our finding of strong agreement between the model and the data, we argue that at least two independent stochastic Gaussian variables are required to adequately model price fluctuations.