全文获取类型
收费全文 | 3773篇 |
免费 | 471篇 |
国内免费 | 1041篇 |
专业分类
化学 | 3702篇 |
晶体学 | 10篇 |
力学 | 448篇 |
综合类 | 3篇 |
数学 | 265篇 |
物理学 | 857篇 |
出版年
2024年 | 7篇 |
2023年 | 160篇 |
2022年 | 134篇 |
2021年 | 140篇 |
2020年 | 174篇 |
2019年 | 111篇 |
2018年 | 106篇 |
2017年 | 134篇 |
2016年 | 98篇 |
2015年 | 133篇 |
2014年 | 229篇 |
2013年 | 297篇 |
2012年 | 334篇 |
2011年 | 333篇 |
2010年 | 293篇 |
2009年 | 300篇 |
2008年 | 267篇 |
2007年 | 316篇 |
2006年 | 379篇 |
2005年 | 198篇 |
2004年 | 152篇 |
2003年 | 85篇 |
2002年 | 100篇 |
2001年 | 99篇 |
2000年 | 109篇 |
1999年 | 77篇 |
1998年 | 77篇 |
1997年 | 73篇 |
1996年 | 33篇 |
1995年 | 53篇 |
1994年 | 39篇 |
1993年 | 34篇 |
1992年 | 16篇 |
1991年 | 12篇 |
1990年 | 6篇 |
1989年 | 9篇 |
1988年 | 22篇 |
1987年 | 56篇 |
1986年 | 74篇 |
1985年 | 13篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有5285条查询结果,搜索用时 31 毫秒
241.
242.
Tai-ran Wang Jian-cong Li Wu Shu Su-lei Hu Run-hai Ouyang Wei-xue Li 《化学物理学报(中文版)》2020,33(6):703-711
Over the last few years, machine learning is gradually becoming an essential approach for the investigation of heterogeneous catalysis. As one of the important catalysts, binary alloys have attracted extensive attention for the screening of bifunctional catalysts. Here we present a holistic framework for machine learning approach to rapidly predict adsorption energies on the surfaces of metals and binary alloys. We evaluate different machine-learning methods to understand their applicability to the problem and combine a tree-ensemble method with a compressed-sensing method to construct decision trees for about 60000 adsorption data. Compared to linear scaling relations, our approach enables to make more accurate predictions lowering predictive root-mean-square error by a factor of two and more general to predict adsorption energies of various adsorbates on thousands of binary alloys surfaces, thus paving the way for the discovery of novel bimetallic catalysts. 相似文献
243.
《Particuology》2022
As an innovative thermal energy technology, the spray-type packed bed has advantages of high efficiency and low cost. A liquid distributor is the key component for the spray-type packed bed for scattering heat-transfer liquid drops evenly. In this study, the distribution performance and pressure drop of the perforated plate distributors of different orifice diameters were studied experimentally. The experimental results indicate that orifice diameter has a greater effect on the distribution performance compared to flow rate. With an increase in flow rate, the flow pattern through the distributor changes from the uncovered drop to the covered drop and then to the jet flow. The covered drop pattern shows the best performance with a good distribution and a small pressure drop simultaneously, which is the design and optimization principle of the distributor for a spray-type packed bed. 相似文献
244.
《Particuology》2022
Screw conveyors are extensively used in modern industry such as metallurgy, architecture and pharmaceutical due to their high-efficiency in the transportation of granular materials. And substantial efforts have been devoted to the study of the screw conveyors. Numerical method is an effective way to study screw conveyor. However, previous studies have mainly focused in the regime of spherical particles while the in-depth investigations for non-spherical particles that should be the most encountered in practical applications are still limited. In view of the above situations, discrete element method (DEM), which has been widely accepted in simulating the discrete systems, is utilized to investigate the conveying process of non-spherical particles in a horizontal screw conveyor, with particles being modeled by super-ellipsoids. In addition, a wear model called SIEM (Shear Impact Energy Model) is incorporated into DEM to predict the wear of screw conveyor. The DEM simulation results demonstrate that the particle shape is influential for the flow behaviors of particles and the wear of conveyor. The conveying performance evaluated quantitatively of both mass flow rate and power consumption is subsequently obtained to investigate the effect of sphericity of particle with different operation parameters. Moreover, particle collision frequency and collision energy consumption are acquired to investigate the possible particle breakage between particles and screw blade. The comparisons between particle–particle collision and particle–wall collision reveal that particles with large shape index have more possibility to be damaged in particle–wall impingement. 相似文献
245.
《Particuology》2022
We explored such issues as the formation mechanism, structure and propriety of the solid solutions of anthracene (ANT)–phenanthrene (PHE). Solution crystallization and solid-state grinding were employed to prepare solid solutions under different conditions. The thermal behavior and PXRD scanning results revealed the formation of discontinuous solid solutions, whose melting points and crystal lattices varied linearly with mixed ratio. Combing with Materials Studio, the formation possibility of solid solutions were investigated by evaluating the change of the energy. The crystal morphology of the solid solutions have a positive correlation with the change of the major part. Finally, the solution crystallization process of solid solution were studied using the population balance model. 相似文献
246.
《Particuology》2022
The analytical infinite series solution of submicron particle transport in a circular tube bounded by a porous wall, such as a pinhole, is determined under the slip velocity boundary condition, and the solution is verified by using the experimental data in the previous studies for the specific cases. The results show that particle penetration rate increases with the increase of the porous parameter, the axial pressure drop, and the pinhole radius, whereas it decreases with increasing the pinhole length. The penetration rate of nano-particles are more sensitive to the variation of these parameters. However, the differences between the penetrations of particles ranging from 0.3 μm to 1 μm are not evident because the diffusion becomes weak gradually in this size range. In addition, a further comparison is performed between the analytical solution and the existing studies, and approximate expressions are presented for accurate calculation of particle penetration rate through pinholes appearing in porous materials including filter devices and masks. 相似文献
247.
通过升高色谱柱温度,结合线性梯度洗脱的分离模式调整色谱分离的选择性,提出了一种测定脑蛋白水解物注射液中氨基酸含量的2,4-二硝基氟苯(DNFB)柱前衍生高效液相色谱方法。本法采用Kromasil C18(250×4.6 mm i.d.,5μm)色谱柱,柱温44℃,在30 min内以3个线性梯度能完全分离17种氨基酸,定量线性范围为0.2~1.0mg/L;加标回收率为89%~108%。该法具有适用性好、稳定性高等特点,也可以应用于其它种类样品中氨基酸的测定。 相似文献
248.
《Chemical physics letters》1987,141(6):503-507
The first excited triplet state of dimesitylcarbene has been generated in solution at room temperature. It has a lifetime of 60 ns and shows fluorescence with λmax = 501 nm and absorption with λmax = 360 nm. This species is quenched by oxygen and carbon tetrachloride with rate constants of (4.4 ± 0.8) × 1010 and (7.3 ± 0.6) × 109 M−1 s−1, respectively. 相似文献
249.
以牛血清白蛋白和胰岛素为研究对象, 经1,5-I-AEDANS衍生后, 采用高效液相色谱(HPLC)进行分离分析, 发现两者的衍生存在明显的协同作用. 相似文献
250.
LIU Xiu-dong YU Wei-ting LIN Jun-zhang MA Xiao-jun YUAN Quan 《高等学校化学研究》2007,23(5):579-584
Alginate has been widely used in cell microencapsulation and drug delivery systems in the form of gel beads or microcapsules.Although an alternative novel emulsification-internal gelation technology has been established and both the properties and the potential applications of the beads in drug delivery systems have been studied,the mechanism has not been well understood compared with the traditional droplet method(external gelation technology).On the basis of our previous knowledge that the novel technology is composed of complicatedly consecutive processes with multistep diffusion and reaction,and the diffusion of acetic acid across oil/water interface being the prerequisite that determines the occurrence and rate for the reactions and the structures and properties of final produced gel beads,a special emphasis was placed on the diffusion process.With the aid of diffusion modeling and simple experimental design,the diffusion rate constant and diffusion coefficient of acetic acid across oil/water interface were determined to be in the orders of magnitude of 10-6 and 10-16,respectively.This knowledge will be of particular importance in understanding and interpreting the formation,structure of the gel beads and the relationship between the structure and properties and guiding the preparation and quality control of the gel beads. 相似文献