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81.
Sadeek SA El-Shwiniy WH Zordok WA El-Didamony AM 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(2):854-867
The preparation and characterization of the new solid complexes [Y(CIP)2(H2O)2]Cl(3)·10H2O and [ZrO(CIP)2Cl]Cl·15H2O formed in the reaction of ciprofloxacin (CIP) with YCl3 and ZrOCl(2)·8H2O in ethanol and methanol, respectively, at room temperature were reported. The isolated complexes have been characterized with elemental analysis, IR spectroscopy, conductance measurements, UV-vis and 1H NMR spectroscopic methods and thermal analyses. The results support the formation of the complexes and indicate that ciprofloxacin reacts as a bidentate ligand bound to the metal ion through the pyridone oxygen and one carboxylato oxygen. The activation energies, E*; entropies, ΔS*; enthalpies, ΔH*; Gibbs free energies, ΔG*, of the thermal decomposition reactions have been derived from thermogravimetric (TGA) and differential thermogravimetric (DTG) curves, using Coats-Redfern and Horowitz-Metzeger methods. The proposed structure of the two complexes was detected by using the density functional theory (DFT) at the B3LYP/CEP-31G level of theory. The ligand as well as their metal complexes was also evaluated for their antibacterial activity against several bacterial species, such as Staphylococcus aureus (S. aureus), Escherichia coli (E. coli) and Pseudomonas aeruginosa (P. aeruginosa) and antifungal screening was studied against two species (Penicillium (P. rotatum) and Trichoderma (T. sp.)). This study showed that the metal complexes are more antibacterial as compared to free ligand and no antifungal activity observed for ligand and their complexes. 相似文献
82.
83.
H.M. Barakat 《Journal of the Egyptian Mathematical Society》2011,19(1-2):28-32
In the first part of this review article some recent developments of maximal correlation coefficient, introduced by Gebelein (1941) [7], and its applications in various areas of statistics are discussed. The second part is devoted to find the distributions providing the maximal correlation coefficient between generalized order statistics (gos) and dual generalized order statistics (dgos), which are introduced by Kamps (1995) [8] and Burkschat et al. (2003) [4], respectively. Finally, in the third part, general theorems are presented, which give simple non-parametric criterion for the asymptotic independence between the different elements of gos, as well as dgos. 相似文献
84.
Summary Exact results on the single-spin-flip Glauber dynamics of six-coupled random field Ising spins with the coordination number
of four are presented. Two distributions of random fields (RF), binary (BD) and Gaussian (GD) ones, are investigated. The
effects of the static magnetic field are discussed. In the zero-magnetic-field case, the number of diverging relaxation times
is equal to the number of energy minima minus one. This rule breaks in the presence of a magnetic field. The longest relaxation
times in the absence of the field verify the Arrhenius law with the energy barrier determined by the energy needed to invert
the ground-state spin configuration. At low temperature, according to the Arrhenius law, the spectrum of relaxation times
shows a two-peaked distribution on a logarithmic scale. In the GD case of RF, the energy barrier distribution is continuous,
while it is quasi-discrete in the BD case. 相似文献
85.
《Radiation Physics and Chemistry》2007,76(8-9):1430-1434
The most important mechanical feature of poly(ε-caprolactone) (PCL) foams applied in bone tissue engineering as a scaffold, has been investigated as a function of irradiation dose. Radiation is proposed for the sterilization of the polymer before the implantation. Polycaprolactone scaffold foams were obtained by combination of compression molding and particulate leaching techniques. The porogen was changed in the range 74–96 w% and the irradiation dose was varied from 25 to 150 kGy. Our results show that yield strength is not a function of radiation dose, but is rather influenced by the porosity, while the critical strain is mainly dependent on the dose. All these together mean that the modulus of the elasticity of PCL foams is dependent on both the porosity and the dose. 相似文献
86.
《Journal of Computational and Applied Mathematics》2006,187(1):72-86
The problem of heat and mass transfer in an unsteady free-convection flow over a continuous moving vertical sheet in an ambient fluid is investigated for constant heat flux using the group theoretical method. The nonlinear coupled partial differential equation governing the flow and the boundary conditions are transformed to a system of ordinary differential equations with appropriate boundary conditions. The obtained ordinary differential equations are solved numerically using the shooting method. The effect of Prandlt number on the velocity and temperature of the boundary-layer is plotted in curves. A comparison with previous work is presented. 相似文献
87.
Summary Glass layers of (V2O5)1−x
(P2O5)
x
were prepared by melting appropriate mixtures of V2O5 and P2O5 powders. The measurements ofI–V characteristic curves show three regions of conduction, namely high-resistance state, turnover point with zero-differential
resistance region (∂V/∂I=0) and differential negative-resistance region. The turnover point is strongly dependent on composition, sample thickness
and temperature. It is found that the increase of the ratio of phosphorus/vanadium reduces conductance as well as it raises
the field required to produce turnover behaviour. The data in the range up to the turnover point are discussed on the basis
of an electrothermal process. Results of the negative-resistance state could be explained in terms of a hopping mechanism. 相似文献
88.
Subharmonic oscillations of order one-half for a single-degree-of-freedom system with quadratic, cubic, and quartic nonlinearities
under parametric excitation are investigated. Two approximate methods (multiple scales and generalized synchronization) are
used for comparison. The modulation equations (reduced equations) of the amplitudes and the phases are obtained. Steady-state
solutions (periodic solutions) and their stability are determined. Numerical solutions are carried out, and graphical representations
of the results are presented and discussed. The results obtained by the two methods are in excellent agreement. 相似文献
89.
The effect of mixed solvent on complex stability is discussed from a thermodynamic standpoint. The variation in the free energy of formation for a complex species in different solvent mixtures is an indication of solvent-solute and solvent-solvent interactions. The complexity of the systems in mixed solvents makes entropy data difficult to interpret. Evidence is given on solvent-solvent interactions. 相似文献
90.