采用衍射掩模产生白光横向平顶光束

白光横向平顶光束在定向背光式自由立体显示器中有重要应用.本文提出一种采用带蝶形小孔阵列的衍射掩模片获得白光横向平顶光束的方法.根据广义惠更斯-菲涅耳衍射积分和多波长叠加原理,推导出光强分布计算式.设计一套实验装置,数值模拟并实验验证出射光束在不同距离的横向光强分布以及小孔蝶形凹度(蝶形中心高度与边长的比值)对横向光强分布的影响.结果表明:当选择小孔蝶形凹度为0.50—0.66时,可以得到平顶因子F 0.89的白光横向平顶光束,横向平顶光束的宽度随着传输距离的增大而增大,而平顶因子基本不变.实验还发现柱面透镜的折射色散和衍射色散可以互相抵消,使白光横向平顶光束基本无色散.     

Si(001)衬底上闪锌矿ZnO的制备与分析

采用分子束外延方法在室温下于Si(001)表面上生长ZnO材料。实验发现:样品为闪锌矿和六角结构的ZnO混合多晶薄膜,其表面分布着一系列具一定取向的近似长方形的纳米台柱结构。在不同参数的高温退火后,这些梯形台柱将变小,形成梯形纳米环,或分解为较小的纳米柱及其团簇结构等。分析表明:ZnO混合多晶薄膜的形成,以及表面纳米台柱的演变,与Si(001)衬底、较低温的生长温度及热效应等因素相关联。     

Deposition of Ag nanostructures on TiO2 thin films by RF magnetron sputtering

Ag nanostructures on TiO₂ films were deposited by RF magnetron sputtering under variable deposition parameters, such as DC potential, RF-power and total pressure. The concentration, shape, and distribution of the deposited nanostructures and continuous Ag films on thin films of TiO₂ can be tailored by careful variation of the deposition parameters. Controllable clusterlike, islandlike and film Ag structures on TiO₂ film were obtained, respectively. DC potential was found as an appropriate parameter to tailor the change of Ag nanostructure and the overall Ag amount. The compositions, nanostructures and morphologies of nanocomposite films appreciably influence the optical response.     

Resonant photoemission spectroscopy study of electronic structures of LiMn2O4

The valence-band resonant photoemission spectra (RPES) of LiMn₂O₄ have been measured throughout the Mn3p absorption edge. Based on the RPES data, the contribution of Mn3d states to the valence band of LiMn₂O₄ has been described and, consequently, the detailed hybridization between O2p and Mn3d states in the valence-band was determined.     

Surface dynamics studied by time-dependent tunneling current

Scanning tunneling microscopy (STM) is not only an excellent tool for the study of static geometric structures and electronic structures of surfaces due to its high spatial and energy resolution, but also a powerful tool for the study of surface dynamic behaviors, including surface diffusion, molecular rotation, and surface chemical reactions. Because of the limitation of the scanning speed, the video-STM technique cannot study the fast dynamic processes. Alternatively, a time-dependent tunneling current, I-t curve, method is employed in the research of fast dynamic processes. Usually, this method can detect about 1000 times faster dynamic processes than the traditional video-STM method. When placing the STM tip over a certain interesting position on the sample surface, the changing of tunneling current induced by the surface dynamic phenomena can be recorded as a function of time. In this article, we review the applications of the time-dependent tunneling current method to the studies of surface dynamic phenomena in recent years, especially on surface diffusion, molecular rotation, molecular switching, and chemical reaction.     

Structural optimization and segregation behavior of quaternary alloy nanoparticles based on simulated annealing algorithm

Alloy nanoparticles exhibit higher catalytic activity than monometallic nanoparticles, and their stable structures are of importance to their applications. We employ the simulated annealing algorithm to systematically explore the stable structure and segregation behavior of tetrahexahedral Pt–Pd–Cu–Au quaternary alloy nanoparticles. Three alloy nanoparticles consisting of 443 atoms, 1417 atoms, and 3285 atoms are considered and compared. The preferred positions of atoms in the nanoparticles are analyzed. The simulation results reveal that Cu and Au atoms tend to occupy the surface, Pt atoms preferentially occupy the middle layers, and Pd atoms tend to segregate to the inner layers. Furthermore, Au atoms present stronger surface segregation than Cu ones. This study provides a fundamental understanding on the structural features and segregation phenomena of multi-metallic nanoparticles.     

Enhanced electrochemical properties and thermal stability of LiNi<Subscript>1/3</Subscript>Co<Subscript>1/3</Subscript>Mn<Subscript>1/3</Subscript>O<Subscript>2</Subscript> by surface modification with Eu<Subscript>2</Subscript>O<Subscript>3</Subscript>

Layered LiNi_1/3Co_1/3Mn_1/3O₂ cathode material is synthesized via a sol-gel method and subsequently surface-modified with Eu₂O₃ layer by a wet chemical process. The effect of Eu₂O₃ coating on the electrochemical performances and thermal stability of LiNi_1/3Co_1/3Mn_1/3O₂@Eu₂O₃ cells is investigated systematically by the charge/discharge testing, cyclic voltammograms, AC impedance spectroscopy, and DSC measurements, respectively. In comparison, the Eu₂O₃-coated sample demonstrates better electrochemical performances and thermal stability than that of the pristine one. After 100 cycles at 1C, the Eu₂O₃-coated LiNi_1/3Co_1/3Mn_1/3O₂ cathode demonstrates stable cyclability with capacity retention of 92.9 %, which is higher than that (75.5 %) of the pristine one in voltage range 3.0–4.6 V. Analysis from the electrochemical measurements reveals that the remarkably improved performances of the surface-modified composites are mainly ascribed to the presence of Eu₂O₃-coating layer, which could efficiently suppress the undesirable side reaction and increasing impedance, and enhance the structural stability of active material.     

大尺寸物体彩色全息图制作的研究

通过分析两步法制彩色全息图中全息图空间带宽积与物体大小、全息图记录距离的关系,提出了一种拍摄大尺寸物体彩色全息图的方法。经编码,设置参数,在视窗处平面记录下三分色全息图, 以保证用最小的幅面记录下物体的完整信息,并且H1rgb处于同一平面经原参考光的共轭光再现时,他们的再现像能完全重合;将H1rgb再现,获得大视场的物光波信息,三基色物波信息重合后,用光学方法记录大幅面的彩色全息。该方法能提高全息图再现像的视场和解决大尺寸物体的全息图难拍摄问题。 经实验验证,该方法能将全息图再现像的视场提高6倍左右。     

基于铟锡氧化物/Ti复合电极的高亮度碳纳米管场致发射冷阴极

通过制作亲碳性铟锡氧化物(ITO)/Ti复合电极,改善移植型碳纳米管(CNT)冷阴极的导电电极与CNT膜层之间附着性能,从而消除CNT与电极间的界面势垒和非欧姆接触对CNT阴极场发射均匀性和稳定性的影响.采用磁控溅射技术和丝网印刷工艺制作了ITO/Ti基CNT阴极.用X射线衍射仪和场致发射扫描电子显微镜表征CNT阴极结构,结果显示热处理后的ITO/Ti基CNT阴极中可能有TiC相生成,从而使得导电电极与CNT形成有中间物的强作用体系.该体系降低甚至消除电极与CNT之间的界面势垒,增加了CNT与电极间形成欧姆接触的概率.用四探针技术分析电阻率,结果表明ITO/Ti复合电极具有电阻并联效果,CNT阴极导电性能提高.场致发射特性测试表明ITO/Ti基CNT阴极的场致发射电流达到384μA/cm2,较普通ITO基CNT阴极的场致发射电流有显著提高,能够激发测试阳极发出均匀、稳定的高亮度荧光.制作ITO/Ti复合电极是实现场致发射稳定、均匀的低功耗CNT阴极的有效途径.     

杂质对量子环上荷负电激子的影响

讨论了在杂质电荷的电场影响下,量子环上荷负电激子X-的能-光谱及其Aharonov-Bohm振荡.当轨道总角动量不守恒的情况下,提出如何按轨道角动量分类构成基矢组并用典型的对角化方法求解体系的本征值和本征矢的方案.该方案计算简单,计算结果令人满意.还讨论了运用等效电荷变换公式和变换图,把位于三维空间的杂质简化为二维平面(或x轴上)的杂质处理,使计算变得更简单,对结果的分析也更明晰.