金纳米微粒作探针共振瑞利散射光谱法测定亚甲蓝

在pH为6.5~9.5的中性或弱碱性介质中, 金纳米微粒可与亚甲蓝(MB)阳离子靠静电引力及疏水作用力结合, 形成粒径较大的聚集体(平均粒径从12 nm增至20 nm), 这种聚集体的形成导致共振瑞利散射(RRS)强度显著增强, 最大散射峰位于371 nm. 在适当条件下, 散射强度(ΔI)与亚甲蓝浓度成正比. 该法具有高灵敏度, 将金纳米微粒作为测定亚甲蓝的高灵敏RRS探针, 对亚甲蓝的检出限为21.17 ng/mL, 该法简便, 快速, 且有较好的选择性, 可用于血液中亚甲蓝的测定.     

软材料粘接结构界面破坏研究综述

软材料已经在软机器人、生物医学及柔性电子等各个领域得到广泛的应用. 实际应用中, 软材料多需要粘附于不同类型的基底上, 与之共同组成工程构件进而实现特定的功能, 粘接界面性能对构件的结构完整性与功能可靠性起着关键性作用. 本文对目前软材料粘接结构界面破坏行为方面的研究进行了系统总结. 首先通过与传统粘接结构的对比, 指出了“软界面”与“软基体”两种软材料粘接结构界面破坏行为的独特性及其物理本质. 接着分别总结了“软界面”与“软基体”两种粘接结构界面破坏行为的实验表征方面的研究成果, 对界面及基体黏弹性耗散对界面破坏机理的影响分别进行了分析. 然后从理论角度, 介绍了针对两种软材料粘接结构界面破坏行为的理论分析方法, 并对已建立的相关理论模型进行了总结. 之后以内聚力模型方法为基础, 介绍了软材料粘接结构界面破坏行为数值模拟方面的相关研究进展. 最后基于已有的研究成果, 提出了目前研究所面临的挑战, 并对可能的软材料粘接结构界面破坏的未来研究方向进行了讨论和展望.      

光助Fenton试剂氧化降解染料直接耐晒黑G的研究

文章研究了影响Fenton试剂氧化降解持久性有机污染物直接耐晒黑G的因素,如光源的选择、初始pH值、H₂O₂的用量、Fe2+的用量、阳离子交换树脂载体的引入等,通过研究确定了各因素的优化条件。研究结果表明：太阳光照能有效的促进直接耐晒黑G染料的降解脱色,大大缩短反应时间;引入阳离子交换树脂后,可增强Fenton氧化反应的活性,降解效果更好。     

O形与C形组合密封圈的力学性能对比分析

建立了 O形密封圈与C形组合密封圈的轴对称模型,分析了两种密封圈的静、动密封性能和过孔性能,并计算出了不同压力下密封圈的摩擦阻力.对比两种密封圈的性能,结果表明:O形密封圈适用于较低压力的静密封;高压静密封、压力超过15MPa时的动密封及过孔工况下,O形密封圈的使用需增加挡圈;因O形圈变形严重,局部应力较大,易发生疲劳...     

Correction to: Interlaboratory Reproducibility of Contour Method Data Analysis and Residual Stress Calculation

Experimental Mechanics - The original version of this article has been corrected to include authors middle initials in the author list. The details given in this correction are correct.     

Experimental study on wake flow structures of screen cylinders using PIV

Experiments were conducted in a water flume using Particle Image Velocimetry (PIV) to study the evolution of the vortical structures in the wakes of four types of screen cylinders at a Reynolds number of about 3200. The results were compared with that of a bare cylinder. The screen cylinders were made of stainless steel screen meshes of various porosities (37%, 48%, 61% and 67%) rolled into cylindrical shapes. Smoke wire flow visualisations in a wind tunnel were also conducted in support of the PIV tests. Depending on the porosity of the screen mesh, two vortex formation mechanisms for the screen cylinder wakes were identified. One was associated with wake instability and the other was associated with shear-layer (Kelvin-Helmholtz) convective instability which involved merging through pairing and tripling of small-scale vortices within the shear layers. The former was responsible for the formation of large-scale vortices in the bare cylinder and the screen cylinder wakes with 37% and 48% porosities, while the latter was responsible for the screen cylinder wakes with 61% and 67% porosities. The results also showed that with increasing porosity, the vortex formation region was extended farther downstream and the Reynolds shear stress, the Turbulent Kinetic Energy (TKE) and vortex intensity were decreased constantly.     

受限亚音速气流中倒置悬臂壁板静气弹稳定性的理论及实验研究

板壳结构在航空航天、高速列车、能量采集等诸多工程领域已经得到了广泛应用. 将悬臂壁板倒置于轴向气流中并在壁板周围流场中设置刚性壁面可有效地调控壁板的失稳速度, 是俘能器优化设计的重要措施之一. 但针对刚性壁面作用下亚音速气流中倒置悬臂壁板的失稳机制仍需要开展深入研究. 本文以受限亚音速气流中倒置的二维悬臂壁板为对象, 以理论分析及风洞实验为手段, 研究了单侧刚性壁面效应对倒置悬臂壁板静态失稳特性的影响规律. 在理论分析中, 首先应用镜像函数法来处理壁面约束条件, 基于算子理论研究获得了以Possio积分方程为表征的壁板气动力, 壁面效应实际表征为一包含移位Tricomi算子的复合算子; 然后将壁板失稳方程的求解问题转化为定区间上的函数逼近问题; 最后, 依据Wererstrass定理并利用最小二乘法求解该最优函数, 以获得系统的失稳临界参数. 在试验研究中依据压杆稳定原理设计了壁板静态失稳的测试方法并完成了风洞实验. 理论分析结果表明, 壁板会发生发散(静气动弹性)失稳, 临界动压随壁板与壁面间距的增加而增大并最终趋于稳定(无壁面情况); 通过理论与风洞实验结果的对比分析, 验证了本文气动力及理论分析的适用性及准确性. 针对倒置悬臂壁板结构的气动弹性失稳问题, 本文提出的方法不涉及系统方程的离散及特征值求解问题, 而是将其转化为了定区间上的函数逼近问题进行求解, 这为弹性结构静气动弹性失稳问题的研究提供了一个可行的新思路.      

Twin-field quantum key distribution based on twisted photon

Quantum key distribution (QKD) is a promising application to establish unconditional secure communications by quantum mechanics. However, its widespread application still faces a great challenge, that is, the fundamental linear key-rate constraint called Pirandola-Laurenza-Ottaviani-Banchi (PLOB) bound. Recently, twin-field QKD (TF-QKD) was proposed (Lucamarini et al., 2018 [4]), it overcomes the constraint mentioned above. However, the original TF-QKD is based on the phase-encoding strategy, which requires active alignment. In this paper, we improve the original TF-QKD with the photon orbital angular momentum (OAM), and propose a novel reference frame independent protocol to overcome the reference frame dependence. No more alignment procedure is needed, and the intrinsic misalignment errors are eliminated by utilizing the rotation-invariance of OAM photons. Besides, the security performance is also improved.     

Thermal fluctuations of dyadosphere of Reissner-Nordström,Janis-Newman-Winicour and f(R) global monopole black holes

In this paper, we study the effects of thermal fluctuations on Dyadosphere of Reissner-Nordström, Janis-Newman-Winicour and the fragmentation of f(R) global monopole black holes. In the presence of these fluctuations, we obtain various thermodynamic quantities like pressure, entropy, specific heat, Canonical and Grand Canonical ensembles. We discuss the stability of these black holes using the γ (the ratio of heat capacities). We also discuss the phase transition and range of local and global stability. It is demonstrated that in Dyadoshpere of Reissner-Nordström, Janis-Newman-Winicour and fragmentation of f(R) global monopole black holes become locally and globally stable due to logarithmic correction term and large horizon radius.     

Electronic and optical properties of Ho-doped BYF crystal

First-principles methods have been applied to explore the electronic and optical properties of BYF single crystals heavily doped with the Ho³⁺ ion (16.33 and 30.36 mol%). The electronic properties calculations manifest that the top of the valence band is dominated by 2p-orbitals of the F atoms and 4f-orbitals of the Ho atoms. The new defect states are dominated by 4f-orbitals of the Ho atoms which exist in the forbidden band. The principal absorptionat around 5.13 eV (241.7 nm) and 5.75 eV (215.7 nm) occurs in ultra-violet range owing to the electronic transitions from the occupied 2p-orbitalsof the F atoms as well as 4f-orbitals of the Ho atoms to empty 4f-orbitals of neighboring Ho atoms. Moreover, the influence of crystal field will split the energy levels of rare earth ions and easily release the parity forbidden condition of free rare earth ions resulting in f-f transition. Therefore, there may be a 2 μm luminescence in the Ho-doped BYF crystal.