光谱法锌离子检测系统的研究

采取标准锌显色剂与锌发生显色反应，生成不溶于水的絮状络合物。用光谱仪测它的吸光度，研究其特征谱与吸光度的特点，建立其浓度与特征波长吸光度间的数学模型。本文所采用的显色剂主要与锌、铜、镉、镍四种离子发生络合反应。因此分别探索了四种离子高浓度以及低浓度时显色反应的吸光度，最终通过得到锌离子浓度与吸光度的关系式以及锌离子浓度与四波长下四种离子混合溶液显色后的吸光度的关系式，给出了锌离子的吸光度与总吸光度的关系式。显色反应能否满足分光光度法的要求，主要与显色剂的性质有关，同时显色反应的条件也至关重要。因为在显色反应过程中，主要是锌离子与锌显色剂发生络合反应形成络离子，进而形成絮状络合物。络离子一般比较稳定，但在水溶液中也存在着电离平衡，也就是说当显色条件发生变化时，既有可能形成络离子，也有可能发生络离子的分解，从而影响络合反应的程度。显色条件包括显色剂用量、pH值、反应温度、显色时间、待测溶液的盐度以及浊度等。重点研究待测溶液的盐度对锌离子浓度测量值的影响，并通过实验给出影响规律以及校正模型。     

POSITIVE SOLUTIONS TO(k,n-k) NONHOMOGENEOUS BOUNDARYVALUE PROBLEM

By the Schauder fixed point theory,this paper establishes the existence of positive solutions to a(k,n k) m-point boundary value problem.We show that there exists a positive constant b such that the problem has at least one positive solution when the homogeneous boundary parameter is smaller than b,and no positive solution when this parameter is greater than b.     

Synthesis and characterization of Li1.05Co1/3Ni1/3Mn1/3O1.95X0.05 (X = Cl,Br) cathode materials for lithium-ion battery

In order to improve the thermal stability and dynamic performance of LiCo_1/3Ni_1/3Mn_1/3O₂ materials, Cl-doped and Br-doped materials were synthesized via the co-precipitation method. The morphology, structure, electrochemical performance and thermal stability were characterized by environment scanning electron microscopy (ESEM), X-ray diffraction (XRD), electrochemical impedance spectroscopy (EIS), charge–discharge cycling and differential scanning calorimetry (DSC). Results show that all materials had a stable layered structure with α-NaFeO₂ and that Cl-doping slightly increased the size of grains. Both Cl-doping and Br-doping improved the high rate of discharge capacity, cycle-life performance and thermal stability, but Cl-doping was better than Br-doping in improving the material structure stability, dynamic performance and thermal stability.     

Electronic structure and peculiar bonding properties of NdNiMg5 from first principles

The newly found ternary compound NdNiMg₅ has been studied within DFT based methodologies. Results of cohesive energy, charge transfers, elastic constants and electron localized function mapping as well as electronic structure and bonding properties have been compared with those of isostructural binary NdNi. The calculation results have shown that Mg substructures interlayering NdNi – like slabs exhibit different magnitudes of charge transfers all within range of metallic behavior and the different Mg substructures selectively bind with Nd and Ni substructures. As a consequence an enhanced cohesion with respect to binary intermetallic NdNi is identified. The whole set of elastic constants and their combinations in orthorhombic symmetry confirm the mechanical stability of NdNiMg₅ with larger compressibility and less ductility (more brittleness) with respect substructures to NdNi. While in an intermetallic compound such as NdNi the bonding is ensured mainly by Nd–Ni interaction, in NdNiMg₅ Nd–Ni, Nd–Mg, Ni–Mg as well as Mg–Mg participate to the bonding and the extra electrons brought by Mg are found within bonding states thus illustrating furthermore the enhanced cohesion of the ternary versus the binary systems.     

Regulating PdC3/PtC3···thiophene interaction by small molecule doping (AgOTf,CuBr, CuI,CuBr2, PdCl2)

Structural Chemistry - The influences of small molecule doping on PdC3/PtC3···thiophene interaction have been investigated by atoms in molecules (AIM) theory, electron location...     

脉冲电场测试中的激光供电技术

为解决脉冲电场测试系统中的供电问题，设计了一套激光光纤供电系统，该系统由激光器、多模光纤及光电池构成。重点研究了激光器与光纤的耦合问题，设计了透镜系统对激光器输出光束进行准直和压缩。通过MOCVD法研制了GaAs光电池，并制作了椭球形"光伏眼"来提高光电转换效率。仿真和实验表明:采用透镜耦合时，激光器与光纤的耦合效率可达80%以上，远远高于直接耦合时的16%，改进后的"光伏眼"耦合效率相比直接耦合时提高了54.5%，激光供电系统的转化效率在40%以上。该系统的研制为解决脉冲电场的供电问题提供了一种方案。     

The comparison of protecting methods to the amino group in 2-Aminomethylphenylacetic acid

2-Aminomethylphenylacetic acid is an important intermediate of ceforanide, and this article compared two different protecting agents for protecting the amino group in 2-aminomethylphenylacetic acid by BOC (Di-tert butyl dicarbonate) or acetacetic ester, and compared the deprotection condition. The yield was higher when BOC was used as protecting agent, but when it was deprotected, it was more difficult than when acetacetic ester was used as protecting agent.