Enhancement of red emission by co-dopant Ln3+ ions in Eu3+ :LaOF nanoparticles

Fluoride nanoparticles of Ln3+(Ln3+=Pr3+,Nd3+,Sm3+,Gd3+,Tb3+Dy3+,Ho3+,Er3+,Tm3+,Yb3+)/Eu3+:LaOF and Eu3+ :LaOF with rhombohedral crystal structure were prepared by a hydrothermal-sintering method. The red fluorescence emission of Eu3+ ions was found to be enhanced with most of the co-dopant Ln3+ ions. Compared with strong fluorescence emission at 610 nm of Eu3+ :LaOF nanoparticles, the enhancement factors was up to ten times in Ln3+(Ln3+ =Gd3+,Dy3+,Tm3+)/Eu3+ :LaOF co-doped nanoparticles. The results show that the asymmetry of the local environment of Eu3+ ion was reduced by co-doping Ln3+ ion into the nanoparticles, and that energy transfer might occur between Eu3+ and codopant Ln3+ ions, which is suggested as the source of the observed fluorescence enhancement.     

电子舌及其在饮料区分辨识方面研究进展

电子舌技术是20世纪80年代中期发展起来的一种分析、识别液体味道的新型检测手段.它与普通化学仪器不同,得到的不是被测样品中的某种或某几种成分的定性或是定量结果,而是样品成分的整体信息.本文介绍了电子舌的工作原理及其在饮料区分辨识中的研究进展,并对电子舌的发展和趋势作了展望.     

Structural and electronic properties of a single C chain doped zigzag silicene nanoribbon

The structural and electronic properties of zigzag edge silicene nanoribbons (ZSiNRs) doped with a single C chain have been studied by first-principles projector augmented wave (PAW) potential within the density function theory (DFT) framework. The results show that the C chain is almost close to a straight one which results in a transverse contraction near C chain and thus the ribbon width. The C–Si and Si–H bonds are typical ionic bonds while the C–H bond is a covalence bond. ZSiNRs doped with a single C chain are all metallic independent of the position of the C chain. All these results have been explained satisfactory from the electronegativity difference and the bound force to the electrons because of the atom radius difference between the elements.     

Activity Coefficient Determination for the Ternary Systems CsCl in N-Methylformamide or Urea + Water Mixtures at T = 298.15 K

The mean activity coefficients for CsCl in N-methylformamide or urea (w) + H₂O (1 ? w) systems were determined in this work by potentiometry, using ion-selective electrodes at 298.15 K. The value of mass fraction w was varied between 0.00 and 0.40 in five unit-steps and the molality of CsCl was between 0.0020 and 1.4009 mol·kg^?1. The experimental data have been correlated with the Pitzer, modified Pitzer and the extended Debye–Hückel equations. The resulting values of the mean activity coefficients, the osmotic coefficients and the standard Gibbs energy of transfer, together with the Pitzer ion-interaction parameters (β ⁽⁰⁾, β ⁽¹⁾ and C ^φ), extended Debye–Hückel parameters (a, c and d), and modified Pitzer parameters (b, B _MX, C _MX) are reported for the investigated systems.     

Passively harmonic mode-locked fiber laser with controllable repetition rate based on a carbon nanotube saturable absorber

We have proposed and demonstrated a passively harmonic mode-locked fiber laser based on a single-walled carbon nanotube saturable absorber (SWCNT-SA) that has a controllable repetition rate. With the pump power fixed, we have experimentally observed harmonically mode-locked optical pulses with repetition rates that can be controlled over the range from the fundamental to the seventh-order mode through careful adjustment of the polarization controller only. From the experimental results, we deduce that the likely origin of the self-stabilization is the result of global and local soliton interactions induced by the continuous wave (CW) components.     

交通运输结构调整对碳排放的影响效应研究

近年来愈发严重的雾霾天气,使得交通运输行业的节能减排问题成为中国能源与环境战略研究领域的重中之重。因此,有必要研究交通运输结构调整对节能减排的影响效应。在考虑别国交通运输行业结构变化对我国交通节能减排示范效应以及数据可得性的基础上,本文利用1990~2011年公路、铁路、水运、民航客货周转量和交通碳排放量的数据,构建以中国、美国、欧盟以及日本为截面个体的面板数据模型。实证结果表明对于结构减排效应最明显的日本和欧盟来说,日本铁路周转量占比每提高1%,本国的单位周转量碳排放减少3.63%,欧盟水运周转量占比每提高1%,单位周转量碳排放将减少22.11%。而我国对应的这一数字分别为0.38%和0.06%,表明我国交通运输行业在结构性碳减排方面潜力很大。最后基于交通运输行业供给侧改革的背景,结合本文研究结果从客运和货运两方面提出了相关政策建议。     

Adiabatic approximation for the evolution generated by an <Emphasis Type="Italic">A</Emphasis>-uniformly pseudo-Hermitian Hamiltonian

We discuss an adiabatic approximation for the evolution generated by an A-uniformly pseudo-Hermitian Hamiltonian H(t). Such a Hamiltonian is a time-dependent operator H(t) similar to a time-dependent Hermitian Hamiltonian G(t) under a time-independent invertible operator A. Using the relation between the solutions of the evolution equations H(t) and G(t), we prove that H(t) and H^? (t) have the same real eigenvalues and the corresponding eigenvectors form two biorthogonal Riesz bases for the state space. For the adiabatic approximate solution in case of the minimum eigenvalue and the ground state of the operator H(t), we prove that this solution coincides with the system state at every instant if and only if the ground eigenvector is time-independent. We also find two upper bounds for the adiabatic approximation error in terms of the norm distance and in terms of the generalized fidelity. We illustrate the obtained results with several examples.     

三角代数上的一类非全局三重可导映射

设?=Tri(A,M,B)为三角代数,?={T∈?:T~2=0}且δ:?→?是一个映射(没有可加或线性假设).证明了:如果对任意A,B,C∈?且ABC∈?,有δ(ABC)=δ(A)BC+Aδ(B)C+ABδ(C),则δ是一个可加导子·作为应用,得到了上三角矩阵代数和套代数上此类非全局三重可导映射的具体形式.