全文获取类型
收费全文 | 29934篇 |
免费 | 3962篇 |
国内免费 | 5192篇 |
专业分类
化学 | 16839篇 |
晶体学 | 272篇 |
力学 | 3018篇 |
综合类 | 111篇 |
数学 | 7202篇 |
物理学 | 11646篇 |
出版年
2024年 | 103篇 |
2023年 | 849篇 |
2022年 | 1164篇 |
2021年 | 1149篇 |
2020年 | 1327篇 |
2019年 | 949篇 |
2018年 | 1113篇 |
2017年 | 1251篇 |
2016年 | 1394篇 |
2015年 | 1511篇 |
2014年 | 1942篇 |
2013年 | 2613篇 |
2012年 | 2531篇 |
2011年 | 2526篇 |
2010年 | 1987篇 |
2009年 | 1991篇 |
2008年 | 1644篇 |
2007年 | 1687篇 |
2006年 | 1615篇 |
2005年 | 1133篇 |
2004年 | 848篇 |
2003年 | 751篇 |
2002年 | 673篇 |
2001年 | 676篇 |
2000年 | 498篇 |
1999年 | 628篇 |
1998年 | 458篇 |
1997年 | 407篇 |
1996年 | 329篇 |
1995年 | 276篇 |
1994年 | 229篇 |
1993年 | 218篇 |
1992年 | 256篇 |
1991年 | 182篇 |
1990年 | 156篇 |
1989年 | 193篇 |
1988年 | 415篇 |
1987年 | 547篇 |
1986年 | 526篇 |
1985年 | 111篇 |
1984年 | 64篇 |
1983年 | 44篇 |
1982年 | 73篇 |
1981年 | 19篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1971年 | 4篇 |
1959年 | 3篇 |
1957年 | 7篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
281.
The nonlinear optical membrane used for image processing was prepared using tetraethyl silicate by sol-gel method under mild conditions. Ru(bpy)3Cl2 (bpy, bipyridine) was immobilized in the sol-gel matrix. This light-excitable membrane containing Ru(bpy)3Cl2 as photocatalyst could catalyze the Belousov-Zhabotinsky reaction by illumination. Our results indicated that a fine-definition image processing could be autoperformed when projecting a picture on this medium. The imaging process was an image evolution process, which was similar to that of the human vision process. 相似文献
282.
Daqing Shi Liangce RongJuxian Wang Qiya ZhuangXiangshan Wang Hongwen Hu 《Tetrahedron letters》2003,44(15):3199-3201
A short and facile synthesis of a series of quinazolin-4(3H)-ones and 1,2-dihydroquinazolin-4(3H)-ones was accomplished in good yields via the novel reductive cyclization of o-nitrobenzamides and triethyl orthoformate, aldehydes or ketones promoted by TiCl4/Zn. 相似文献
283.
根据CTP在离子交换树脂上的吸附容量和分离因数的大小,确定Duolite A-30树脂适合CTP与CDP,CMP之间的分离.对CTP在Duolite A-30树脂上的吸附动力学和热力学研究表明,在283.15K~303.15K之间,CTP的质量浓度在7.5g/L以上时,Duolite A-30树脂对CTP的吸附主要受颗粒扩散的控制,其有效扩散系数为D=3.47×10-7cm2/s,溶液的质量浓度≤1.0g/L时,CTP与Duolite A-30树脂之间的交换速率主要受液膜控制,其液膜扩散系数为Kf =4.112×10-4/s.同时测定了不同条件下三磷酸胞苷溶液在Duolite A-30树脂固定床离子交换柱中的穿透曲线,研究了进口浓度、进口流速、原料液温度、原料液的pH值及柱高对穿透曲线的影响.用二阶动力学推动力模型描述固定床动态过程,考察了轴向返混对穿透曲线的影响,并从穿透曲线回归得到总传质系数,模型计算值与实验数据符合良好. 相似文献
284.
J. A. Azizi D. Dollimore P. J. Dollimore G. R. Heal P. Manley W. A. Kneller W. Jin Yong 《Journal of Thermal Analysis and Calorimetry》1993,40(2):831-847
In this study a relationship between the surface and textural properties of carbon blacks and the gasification process induced thermally in air is noted. A temperature jump method was used to follow the gasification in air and to establish the relevant Arrhenius parameters. This can be associated with the activity of ‘basal’ plane carbon atoms as well as ‘edge’ carbon atoms at the surface. This is based on a model of carbon black structure consisting of the irregular packing of small graphite carbon structures. The carbon black surface was measured using a single measurement of adsorption based essentially on the BET volumetric method. The carbon black surface had a rate of oxidation per unit are which clearly indicated that the lower area carbon blacks had a predominately active area of ‘edge’ atoms at the surface while the surface of the higher area carbon blacks had a predominate amount of ‘basal’ plane graphite carbon atoms. 相似文献
285.
286.
287.
G. H. Wang X. Y. Li Y. Y. Lu Y. Z. Zhu H. W. Wang L. Dou R. X. Yu 《Zeitschrift für Physik B Condensed Matter》1987,65(3):347-351
12 MeV electron beams with different doses of 4, 8, 16 and 32 Mrad from LINAC designed by Nanjing University have been used to irradiate polypropylene films and their structures studied by X-ray diffraction afterwards. We have found that the electron irradiation does not change the total crystallinity of polypropylene but greatly inflences its crystal structure with increase of phase and decrease of phase as irradiation dose increases (within 16 Mrad). However, it is unexpected that the structure of irradiated sample with 32 Mrad are similar to that of the control sample. This behavior has also been observed in positron annihilation lifetime measurements. 相似文献
288.
289.
Chen-Xi Zhang Zhi-Liang Liu Dai-Zheng Liao Zong-Hui Jiang Shi-Ping Yan 《Journal of Molecular Structure》2003,650(1-3):21-26
A novel complex [Cu(NIT2Py)(PDA)(H2O)]·(CH3OH)(H2O) has been synthesized and structurally characterized by X-ray diffraction methods. It crystallizes in the monoclinic space group P2(1)/c. The structure consists of [Cu(NIT2Py)(PDA)(H2O)] moiety, one solvent methanol molecule and one water molecule. The copper(II) ion is in a distorted octahedral environment: one nitrogen atom and one oxygen atom from the NIT2Py, one nitrogen atom from the PDA (2,6-pyridine dicarboxylic acid) and one oxygen atom from the aqueous in the basal plane; two oxygen atoms from the PDA in the axial position. The units of [Cu(NIT2Py)(PDA)(H2O)] were connected as one dimension chain by the intermolecular hydrogen bonds. The complex exhibits intramolecular antiferromagnetic interactions between the Cu(II) ion and the NIT2Py. 相似文献
290.
对新型的代铬刷镀层Ni-Fe-W-P-S进行了耐腐蚀性能机理的分析研究。用扫描电镜(SEM)、透射电镜(TEM)、扫描隧道显微镜(STM)、X射线衍射及电子能谱(XPS)等的分析表明,基体组织为非品结构是代铬刷镀层优异耐腐蚀性的主要原因. 相似文献