全文获取类型
收费全文 | 29934篇 |
免费 | 3962篇 |
国内免费 | 5192篇 |
专业分类
化学 | 16839篇 |
晶体学 | 272篇 |
力学 | 3018篇 |
综合类 | 111篇 |
数学 | 7202篇 |
物理学 | 11646篇 |
出版年
2024年 | 103篇 |
2023年 | 849篇 |
2022年 | 1164篇 |
2021年 | 1149篇 |
2020年 | 1327篇 |
2019年 | 949篇 |
2018年 | 1113篇 |
2017年 | 1251篇 |
2016年 | 1394篇 |
2015年 | 1511篇 |
2014年 | 1942篇 |
2013年 | 2613篇 |
2012年 | 2531篇 |
2011年 | 2526篇 |
2010年 | 1987篇 |
2009年 | 1991篇 |
2008年 | 1644篇 |
2007年 | 1687篇 |
2006年 | 1615篇 |
2005年 | 1133篇 |
2004年 | 848篇 |
2003年 | 751篇 |
2002年 | 673篇 |
2001年 | 676篇 |
2000年 | 498篇 |
1999年 | 628篇 |
1998年 | 458篇 |
1997年 | 407篇 |
1996年 | 329篇 |
1995年 | 276篇 |
1994年 | 229篇 |
1993年 | 218篇 |
1992年 | 256篇 |
1991年 | 182篇 |
1990年 | 156篇 |
1989年 | 193篇 |
1988年 | 415篇 |
1987年 | 547篇 |
1986年 | 526篇 |
1985年 | 111篇 |
1984年 | 64篇 |
1983年 | 44篇 |
1982年 | 73篇 |
1981年 | 19篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1971年 | 4篇 |
1959年 | 3篇 |
1957年 | 7篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
261.
ADSORPTION OF 2,4-DICHLOROBENZOXYACETIC ACID ONTO HYPERCROSSLINKED RESIN MODIFIED BY PHENOLIC HYDROXYL GROUP (AM-1) 总被引:2,自引:0,他引:2
INTRODUCTIONAdsorption has been considered to be the best available technology for removing organics from water in the USSafe Drinking Water Act[1]. Due to many drawbacks of activated carbon[2-7], the most widely used adsorbent,hypercrosslinked polymeric adsorbents developed by Tsyurupa and Davankov[8] have been increasingly viewedas an alternative to activated carbon for selective removal of specific organic substances from contaminatedwater[9-12], and series of researches have been do… 相似文献
262.
The formation of covalently linked composites of multi–walled carbon nanotubes (MWCNT) and glucose oxidase (GOD) with high-function
density for use as a biosensing interface is described. The reaction intermediates and the final product were characterized
by using FT–IR spectroscopy, and the MWCNT-coated GOD nanocomposites were examined by atomic force microscopy (AFM) and transmission
electron microscopy (TEM). Interestingly, it was found that the GOD–MWCNT composites are highly water soluble. Electrochemical
characterization of the GOD–MWCNT composites that were modified on a glassy carbon electrode shows that the covalently linked
GOD retains its bioactivity and can specifically catalyze the oxidation of glucose. The oxidation current shows a linear dependence
on the glucose concentration in the solution in the range of 0.5–40 mM with a detection limit of 30 μM and a detection sensitivity
of 11.3 μA/mMcm2. The present method may provide a way to synthesize MWCNT related composites with other biomolecules and for the construction
of enzymatic reaction-based biofuel cells and biosensors.
Supported by grants from the National Natural Science Foundation of China (NSFC, No. 20125515; 90206037; 20375016) and the
Natural Science Foundation of Jiangsu Province (Grant No. BK 2004210) 相似文献
263.
264.
树脂吸附法处理水杨酸甲酯生产废水的研究 总被引:7,自引:0,他引:7
采用吸附树脂NDA—99处理水杨酸甲酯生产废水,结果表明该树脂时废水中的5磺基水杨酸及水杨酸均具有良好的吸附—脱附性能.废水经预处理和吸附处理后,CODCr由57000-59000mg/L降至6300mg/L左右,去除率接近89%.用IBV8%NaOH 3BVH2O作脱附剂,在温度为60℃、流量为IBV/h的条件下,脱附率接近100%,树脂可重复使用.高浓度脱附液经酸化、浓缩、冷却结晶,可回收5—磺基水杨酸,回收率为95%左右。纯度为78%。 相似文献
265.
266.
The basic theory of symplectic algorithm was introduced. A comparison between Runge-Kutta method and symplectic integration method was preformed in the simulation of the long time behavior of H + H2 system on BKMP potential energy surface. Our results reveal a dis-sipative behavior in the integral of ordinary differential equation by the fourth order Runge-Kutta method, which causes incorrect simulation results in QCT calculations. However, when the symplectic integration method is applied, the dissipative behavior is not found in the same system. When the initial state is the same, the energy deviation of fourth order symplectic integral method is almost one percent of that of fourth order Runge-Kutta method in a 60000-step simulation, and that of sixth order symplectic integral method is much less. These results show that the symplectic integral methods are always the better choice in the integral calculation of the long time behavior in maintaining energy conservation. 相似文献
267.
蒿甲醚在模拟体内酸碱环境中的代谢动力学研究 总被引:2,自引:0,他引:2
利用高效液相法对蒿甲醚进行了模拟体内酸碱环境的代谢动力学研究 ,测定了蒿甲醚及其代谢产物双氢青蒿素、蒿甲醚呋喃酯的代谢曲线。结果表明 ,蒿甲醚在模拟体内肠道和血液的弱碱性环境条件下半衰期为2 87 2min(计算值 ) ;在模拟体内胃液的酸性环境条件下半衰期为 74 6min ;在两种条件下的主要代谢产物均为双氢青蒿素和蒿甲醚呋喃酯。该方法克服了以往文献所报道方法的一些缺点 ,不仅简化了样品制备方法 ,也提高了检测结果的准确性。 相似文献
268.
Fourier transform infrared-attenuated total reflection (FTIR-ATR) spectra have been recorded of 11-layer Langmuir-Blodgett (LB) films of stearic acid deposited at various surface pressures (0.1, 15, and 35 mN/m), and the molecular orientation angles were evaluated quantitatively, which supplied insight into the molecular order with the alkyl chains tightly packed like crystal in the LB films deposited at the zero and higher surface pressures. These experimental results indicate that, in the Langmuir film as the precursor of LB films, stearic acid molecules self-aggregate to form two-dimensional crystalline domains already even at the zero surface pressure, which results in the inhomogeneity of monolayer. The analysis of dependence of nu(C=O) intensity on the surface pressure, surface density, and subphase temperature leads to the conclusion that the defects in LB films originate from the Langmuir film and be conserved upon deposition. Annealing below 50 degrees C and cooling could improve the monolayer homogeneity, and thus a defect-free or low-defect LB films can be deposited. Furthermore, ion exchange conducted in the LB films, on the other hand, confirms the existence of structure defects in LB films of stearic acid. The polar plane microstructure, lateral transport along the polar planes and the coordination types of stearic acid/cation system may be the rate-limiting process. The results have implication on the possible uses of stearic acid LB films as ion-exchange materials or sensors. Copyright 2001 Academic Press. 相似文献
269.
《Tetrahedron: Asymmetry》2006,17(4):574-577
Asymmetric catalysis of Mukaiyama aldol addition reactions of methyl 3-TMSO-2-diazo-3-butenoate 4 with aromatic aldehydes using AgF/(R)-BINAP at −20 °C produces chiral diazoacetoacetates in high chemical yields and with high enantiocontrol. 相似文献
270.