The role of hydroperoxides as a precursor in the radiation-induced graft polymerization of methyl methacrylate to ultra-high molecular weight polyethylene

A graft polymerization of methyl methacrylate (MMA) to ultra-high molecular weight polyethylene (UHMWPE) with Co-60 γ-ray irradiation in air at room temperature has been carried out. The grafting yields were measured as a function of the storage time (elapsed time from the end of irradiation to the start of grafting), and it was found that the yields reach at the maximum values at around several days since the end of irradiation. In order to clarify the precursor of the graft polymerization, changes of the radical yields and the carbonyl groups were measured as a function of storage time with ESR and microscopic FT-IR, respectively. From the similarities between the depth profiles of the hydroperoxide formation and the grafting products, it was concluded that the hydroperoxides can be main precursors of the grafting of the radiation-induced polymerization of MMA to UHMWPE under the given conditions.     

Ultrafast dissociation processes in the NO dimer studied with time-resolved photoelectron imaging

Ultraviolet photodissociation of the NO dimer is studied with femtosecond time-resolved photoelectron imaging (TR-PEI) spectroscopy. Pump pulses in the range 200–235 nm are employed, while probe pulses are kept at 300 nm. The time dependencies of the observed photoelectron kinetic energies and photoelectron angular distributions support a picture in which valence state optically excited in the dimer evolves on a time scale of <1 ps to the dimer 3s Rydberg state. This dimer Rydberg state then undergoes fragmentation on a time scale of a few ps. In this study we focus on dissociation into an NO ground state fragment and an NO fragment in its 3s Rydberg A²Σ⁺ state. Every stage of this continuous process, viz. the dimer valence state, the dimer 3s Rydberg state, the separating NO(X) + NO(A) fragments, and the isolated NO(A) fragment is interrogated with TR-PEI.     

Synthesis and characterization of (Pr0.75Sr0.25)1 − xCr0.5Mn0.5O3 − δ as anode for SOFCs

The complex perovskite (Pr_0.75Sr_0.25)_1 − xCr_0.5Mn_0.5O_3 − δ (PSCM) has been prepared and studied as possible anode material for high-temperature solid oxide fuel cells (SOFCs). PSCM exhibits GdFeO₃-type structure and is both physically and chemically compatible with the conventional YSZ electrolyte. The reduction of PSCM resulted in structural change from orthorhombic Pbnm to cubic Pm-3m. Selected area electron diffraction (SAED) analysis on the reduced phases indicated the presence of a √2 × √2 × 2 superlattice. The total conductivity values of ∼ 75% dense Pr_0.75Sr_0.25Cr_0.5Mn_0.5O_3 − δ at 900 °C in air and 5% H₂/Ar are 9.6 and 0.14 S cm^− 1 respectively. The conductivity of PSCM drops with decreasing Po₂ and is a p-type conductor at all studied Po₂. The average TEC of Pr_0.75Sr_0.25Cr_0.5Mn_0.5O_3 − δ is 9.3 × 10^− 6 K^− 1, in the temperature range of 100–900 °C and is close to that of YSZ electrolyte. The anode polarization resistance of PSCM in wet 5%H₂ is 1.31 Ω cm² at 910 °C and in wet CH₄ at 930 °C; the polarization resistance is 1.29 Ω cm². PSCM was unstable at 900 °C in unhumidified hydrogen. Cell performance measurements carried out using graded PSCM and La_0.8Sr_0.2MnO₃ as anode and cathode respectively yielded a maximum power density of 0.18 W cm^− 2 in wet 5%H₂/Ar at 910 °C and the corresponding current density was 0.44 A cm^− 2 at 0.4 V. The activation energy for the electrochemical cell operating in wet (3% H₂O) 5%H₂/Ar fuel is 85 kJ mol^− 1.     

Diastereoselective Friedel–Crafts reaction of α-trifluoromethyl imines derived from chiral amines

The Friedel–Crafts reactions of chiral N-(2,2,2-trifluoroethylidene)-1-arylethylamines 1a and 1b with various electron-rich aromatic compounds were examined. The reactions proceeded readily at room temperature in the presence of BF₃·Et₂O. Substituted products 2–12 were obtained in low to very high stereoselectivities (up to 100% d.e.). The absolute configuration of compound 12 was determined by X-ray analysis. Moreover, the chiral auxiliary from compounds 3 and 12 was selectively removed by palladium-catalyzed hydrogenolysis.     

Osmotic swelling behavior of globules of W/O/W emulsion liquid membranes

The osmotic swelling behavior of water-in-oil-in-water (W/O/W) type emulsion liquid membranes (ELMs) was investigated. Using an optical microscope equipped with a camera, the changes in the size of the W/O/W globules were monitored over a long period of time (up to about 4 h). The osmotic pressure gradient between the internal and external aqueous phases was induced by creating a concentration difference of d-glucose between the two aqueous phases. The results indicate that the swelling ratio, defined as the ratio of globule diameter at time t to globule diameter at t=0, decreases with the increase in ϕ_W/O(0) (initial volume fraction of internal aqueous phase droplets). The swelling ratio generally increases with the increase in the concentration of surfactant present in the membrane (oil) phase. The permeation coefficient of water also increases with the increase in the surfactant concentration. With the increase in ϕ_W/O(0) up to about 0.42, the permeation coefficient decreases only slightly. However, with further increase in ϕ_W/O(0), a sharp reduction in the permeation coefficient occurs. The mechanism of water transfer in ELMs of the present work is reasoned to be the diffusion of hydrated surfactants.     

Measures of Asymmetry Dual to Mean Minkowski Measures of Asymmetry for Convex Bo dies

We introduce a family of measures (functions) of asymmetry for convex bodies and discuss their properties. It turns out that this family of measures shares many nice properties with the mean Minkowski measures. As the mean Minkowski measures describe the symmetry of lower dimensional sections of a convex body, these new measures describe the symmetry of lower dimensional orthogonal projections.     

用具有负定非对称矩阵的梯度系统构造稳定的广义Birkhoff系统1）

Birkhoff系统是一类比Hamilton系统更广泛的约束力学系统,可在原子与分子物理,强子物理中找到应用.非定常约束力学系统的稳定性研究是重要而又困难的课题,用构造Lyapunov函数的直接方法来研究稳定性问题有很大难度,其中如何构造Lyapunov函数是永远的开放问题.本文给出一种间接方法,即梯度系统方法.提出一类梯度系统,其矩阵是负定非对称的,这类梯度系统的解可以是稳定的或渐近稳定的.梯度系统特别适合用Lyapunov函数来研究,其中的函数V通常取为Lyapunov函数.列出广义Birkhoff系统的运动方程,广义Birkhoff系统是一类广泛约束力学系统.当其中的附加项取为零时,它成为Birkhoff系统,完整约束系统和非完整约束系统都可纳入该系统.给出广义Birkhoff系统的解可以是稳定的或渐近稳定的条件,进一步利用矩阵为负定非对称的梯度系统构造出一些解为稳定或渐近稳定的广义Birkhoff系统.该方法也适合其他约束力学系统.最后用算例说明结果的应用.     

设施选址博弈问题的无支付机制设计研究

选址博弈是目前国际相关学术领域的重要前沿课题之一. 在选址博弈问题中, 存在n个相互影响的``理性"居民, 他们的住址等信息是其私有信息;设计者需要设计选址机制, 以居民汇报的住址信息为输入, 输出设施位置. 在进行机制设计的过程中, 如何在没有金钱的刺激下, 保证所有居民``说真话", 设计出防策略性无支付机制是其中的重要研究内容. 设施选址博弈问题的无支付机制设计是组合优化和理论计算机科学的交叉学科课题, 在管理科学、信息科学以及社会经济学等领域有着重要的应用, 具有重要的理论意义和实际的应用价值. 现根据不同设施类型及个数、不同个人偏好、不同度量空间以及不同社会总体目标等条件, 介绍各种类型的设施选址博弈模型, 罗列相关的研究成果, 并总结其中尚待解决的问题.