Rapid and efficient synthesis of 2-imidazolines and bis-imidazolines under ultrasonic irradiation

Rapid and efficient preparation of 2-imidazolines and bis-imidazolines by reaction of ethylenediamine with nitriles in the presence of catalytic amounts of sulfur under ultrasonic irradiation is reported. The advantages of this system are short reaction times, high yields and the ability to carry out large scale reactions.     

Scatter search for the vehicle routing problem with time windows

In this paper we use a scatter search framework to solve the vehicle routing problem with time windows (VRPTW). Our objective is to achieve effective solutions and to investigate the effects of reference set design parameters pertaining to size, quality and diversity. Both a common arc method and an optimization-based set covering model are used to combine vehicle routing solutions. A reactive tabu search metaheuristic and a tabu search with an advanced recovery feature, together with a set covering procedure are used for solution improvement. Our approach led to a robust solution method, generating solution quality that is competitive with the current best metaheuristics.     

Analytic Independence of an Ideal Relative to Certain Injective Module Over a Commutative Noetherian Ring

In this paper we will introduce the concepts of analytic independence and analytic spread for ideals relative to certain injective module over a commutative Noetherian ring.     

Bi(TFA)3-[nbp]FeCl4: a new, efficient and reusable promoter system for the synthesis of 4(3H)-quinazolinone derivatives

4(3H)-Quinazolinones have been synthesized in high to excellent yields through the one-pot condensation of anthranilic acid, trimethyl orthoformate and primary amines in the presence of 5 mol % of Bi(TFA)₃ immobilized on [nbp]FeCl₄ as a room temperature ionic liquid.     

Study of nitrogen ion implantation and diffusion phenomena on thin chromium layers followed by the atomic force microscopy and secondary ion mass spectroscopy techniques characterization

This research investigates the effect of ion implantation dosage level and further thermal treatment on the physical characteristics of chromium coatings on Si(1 1 1) substrates. Chromium films had been exposed to nitrogen ion fluencies of 1 × 10¹⁷, 3 × 10¹⁷, 6 × 10¹⁷ and 10 × 10¹⁷ N⁺ cm⁻² with a 15 keV energy level. Obtained samples had been heat treated at 450 °C at a pressure of 2 × 10⁻² Torr in an argon atmosphere for 30 h. Atomic force microscopy (AFM) images showed significant increase in surface roughness as a result of nitrogen ion fluence increase. Secondary ion mass spectroscopy (SIMS) studies revealed a clear increased accumulation of Cr₂N phase near the surface as a result of higher N⁺ fluence. XRD patterns showed preferred growth of [0 0 2] and [1 1 1] planes of Cr₂N phase as a result of higher ion implantation fluence. These results had been explained based on the nucleation-growth of Cr₂N phase and nitrogen atoms diffusion history during the thermal treatment process.     

Determination of a control parameter in a one-dimensional parabolic equation using the method of radial basis functions

In this work, the method of radial basis functions is used for finding the solution of an inverse problem with source control parameter. Because a much wider range of physical phenomena are modelled by nonclassical parabolic initial-boundary value problems, theoretical behavior and numerical approximation of these problems have been active areas of research. The radial basis functions (RBF) method is an efficient mesh free technique for the numerical solution of partial differential equations. The main advantage of numerical methods which use radial basis functions over traditional techniques is the meshless property of these methods. In a meshless method, a set of scattered nodes are used instead of meshing the domain of the problem. The results of numerical experiments are presented and some comparisons are made with several well-known finite difference schemes.     

A comparison of outbound dispatch policies for integrated inventory and transportation decisions

This paper investigates the impact of alternative outbound dispatch policies on integrated stock replenishment and transportation decisions. The logistics literature reports that two different types of such policies are popular in current practice. These are time-based and quantity-based dispatch policies. Considering the case of stochastic demand, the paper presents analytical and numerical results showing that the cost savings obtained through quantity-based policies can be substantial. However, under a quantity-based policy, a specific delivery time cannot be quoted when the customer places an order. Hence, the paper also investigates the cost and customer waiting time implications of hybrid policies and demonstrates that hybrid policies are superior to time-based policies in terms of the resulting costs. Furthermore, although hybrid policies are not superior to quantity-based policies in terms of the resulting costs, they are superior in terms of a service measure which is quantified by the long-run average cumulative waiting time.     

Hierarchy of rational order families of chaotic maps with an invariant measure

We introduce an interesting hierarchy of rational order chaotic maps that possess an invariant measure. In contrast to the previously introduced hierarchy of chaotic maps [1–5], with merely entropy production, the rational order chaotic maps can simultaneously produce and consume entropy. We compute the Kolmogorov-Sinai entropy of these maps analytically and also their Lyapunov exponent numerically, where the obtained numerical results support the analytical calculations.