Engineering of yolk-shelled FeSe2@nitrogen-doped carbon as advanced cathode for potassium-ion batteries

Potassium-ion batteries (KIBs) have become the most promising alternative to lithium-ion batteries for large-scale energy storage system due to their abundance and low cost. However, previous reports focused on the intercalation-type cathode materials usually showed an inferior capacity, together with a poor cyclic life caused by the repetitive intercalation of large-size K-ions, which hinders their practical application. Here, we combine the strategies of carbon coating, template etching and hydrothermal selenization to prepare yolk-shelled FeSe₂@N-doped carbon nanoboxes (FeSe₂@C NBs), where the inner highly-crystalline FeSe₂ clusters are completely surrounded by the self-supported carbon shell. The integrated and highly conductive carbon shell not only provides a fast electron/ion diffusion channel, but also prevents the agglomeration of FeSe₂ clusters. When evaluated as a conversion-type cathode material for KIBs, the FeSe₂@C NBs electrode delivers a relatively high specific capacity of 257 mAh/g at 100 mA/g and potential platform of about 1.6 V, which endow a high energy density of about 411 Wh/kg. Most importantly, by designing a robust host with large internal void space to accommodate the volumetric variation of the inner FeSe₂ clusters, the battery based on FeSe₂@C NBs exhibits ultra-long cycle stability. Specifically, even after 700 cycles at 100 mA/g, a capacity of 221 mAh/g along with an average fading rate of only 0.02% can be retained, which achieves the optimal balance of high specific capacity and long-cycle stability.     

大型结构变形及形貌摄像测量技术研究进展

船体、机翼、工程建筑等大型结构的变形与形貌的精确测量是实验力学的基本任务之一.摄像测量具有测量精度高、范围大、非接触、可动态测量等优点,是结构形貌与运动测量的重要手段.本文介绍了作者及其所在科研团队近年来利用摄像测量技术在大型结构变形、形貌测量等方面的研究成果和典型应用范例,主要包括:提出折线光路像机链摄像测量方法与技...     

抛撒药壳体对一次起爆型云爆弹威力的影响规律

在对抛撒药壳体的变形及破裂后运动规律进行理论分析的基础上,对2种不同结构的一次起爆型云爆装置进行静爆威力实验,实验结果表明:采用中心起爆抛撒结构时,适度减小中心抛撒药壳体的强度可以提高云爆弹的威力;而采用中心与周边辅助抛撒药同时起爆结构,适度增加抛撒药壳体的强度可以提高云爆弹的威力.     

Videometric research on deformation measurement of large-scale wind turbine blades

Utilization of wind energy is a promising way to generate power, and wind turbine blades play a key role in collecting the wind energy effectively. This paper attempts to measure the deformation parameter of wind turbine blades in mechanics experiments using a videometric method. In view that the blades experience small buckling deformation and large integral deformation simultaneously, we proposed a parallel network measurement (PNM) method including the key techniques such as camera network construction, camera calibration, distortion correction, the semi-automatic high-precision extraction of targets, coordinate systems unification, and bundle adjustment, etc. The relatively convenient construction method of the measuring system can provide an abundant measuring content, a wide measuring range and post processing. The experimental results show that the accuracy of the integral deformation measurement is higher than 0.5 mm and that of the buckling deformation measurement higher than 0.1 mm.     

Symplectic and multi-symplectic wavelet collocation methods for two-dimensional Schrödinger equations

In this paper, we develop symplectic and multi-symplectic wavelet collocation methods to solve the two-dimensional nonlinear Schrödinger equation in wave propagation problems and the two-dimensional time-dependent linear Schrödinger equation in quantum physics. The Hamiltonian and the multi-symplectic formulations of each equation are considered. For both formulations, wavelet collocation method based on the autocorrelation function of Daubechies scaling functions is applied for spatial discretization and symplectic method is used for time integration. The conservation of energy and total norm is investigated. Combined with splitting scheme, splitting symplectic and multi-symplectic wavelet collocation methods are also constructed. Numerical experiments show the effectiveness of the proposed methods.     

复变函数的可视化问题

首先简单介绍了复变函数基础理论的内容可视化和其基于数学软件的直观演示资源建设情况,然后通过幅角函数可视化问题介绍利用数学软件开发应用于数学教学实践的演示素材的方法,解决了Mathematica中的标准幅角函数不能直接表示复数幅角变化量的问题.     

高能固态激光阵列光束合成技术浅析

建立了高能固态激光阵列合成的模型,对相干合成型和非相干合成型的高能固态激光系统进行了分析和比较.引入光束传输因子(BPF)作为评价合成光束的光束质量,对湍流大气对板条激光器和光纤激光器相干合成与非相干合成远场光束质量的影响进行了定量分析.计算模型和结果为工程实际中合成方案的选择和评估提供了参考.     

光纤布拉格光栅及其构成的法布里-珀罗腔的相位谱特性研究

光纤光栅的相位谱对光纤光栅法布里-珀罗(F-P)腔的光谱特性有重要影响.对光纤布拉格光栅(FBG)光谱,特别是FBG相位谱进行了深人分析,推导了低反射率FBG的线性相位谱的一般表达式,提出了高反射率FBG的三段线性相位近似方法,得到了简洁直观的相位谱数学表达式.然后采用和普通F-P腔对比的方式,以等效腔长的概念分析了F...     

车载激光多普勒测速仪参数估计的Cramer-Rao下限

考虑到加速度和高斯型包络对激光多普勒测速仪的影响,在引入加速度分量的基础上,研究了高斯包络型多普勒信号的参数估计.根据数理统计的理论,分析了多普勒圆频率及其一阶变化率估计方差的Cramer-Rao下限(CRLB),给出了参数估计方差的CRLB计算公式,并讨论了各参数带修正的功率谱估计.理论分析及仿真结果表明:参数估计方...