Highly efficient oxidation of alcohols using Oxone as oxidant catalyzed by ruthenium complex under mild reaction conditions

Aromatic and alkyl alcohols were oxidized to the corresponding aldehydes or ketones at room temperature with high conversion and selectivity using Oxone （2KHSOs-KHSO4.K2SO4） as oxidant catalyzed by ruthenium complex Quin-Ru-Quin （where Quin = 8-hydroxyquinoline）. The reaction time is very short and the preparation of complex is simple.     

Optimal birth control of free horizon problems for predator-prey system with age-structure

We study optimal birth policies for three age-dependent populations in a predator-prey system, which is controlled by fertility. New results on problems with free final time and integral phase constraints are presented, the approximate controllability of system is discussed.     

Synthesis and decoloration capacity of well-defined and PMMA-grafted palygorskite nanocomposites

Structurally well-defined PMMA-grafted palygorskite nanoparticles were prepared by modifying the surface of palygorskite nanoparticles with initiators for reverse atom transfer radical polymerization (reverse ATRP) and by using these initiator-modified nanoparticles as macroinitiators. Reverse ATRP from palygorskite nanoparticles was then performed to attach well-defined polymer on to an inorganic core. It has been found that the dispersibility of palygorskite particles in organic solvents is significantly improved by grafting polymers onto the surface of palygorskite particles. The polymer-grafted palygorskite nanoparticles possess excellent decoloration capacity in organic solvents.     

相对平坦模的$\aleph$-积

设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中$0\leq A相似文献   

Optimal control for a population dynamics with age-dependent and diffusion in a periodic environment

Here we consider the optimal harvesting problem for a periodic age-dependent population dynamics with diffusion. Namely, we investigate the model with periodic vital rates and a periodic forcing term that sustains oscillations. By using Mazur’s theorem, we demonstrate existence of solutions of the optimal control problem and by the conception of normal cone, we also obtain the first order necessary conditions of optimality for the problem. Our results extend some known criteria.     

An inverse problem of identifying the coefficient of parabolic equation

This paper studies an inverse problem of identifying the coefficient of parabolic equation when the final observation is given, which has important application in a large fields of applied science. Based on the optimal control framework, the existence and necessary condition of the minimum for the control functional are established. Since the optimal control problem is nonconvex, one may not expect a unique solution. However, in this paper the solution is proved to be locally unique. After the necessary condition is transformed into an elliptic bilateral variational inequality, an algorithm and some numerical experiments are proposed in the paper. The numerical results show that the algorithm designed in this paper is stable and that the coefficient is recovered very well.     

Nonlinear dynamical stability of gap solitons in Bose-Einstein condensate loaded in a deformed honeycomb optical lattice

We investigate the existence and dynamical stability of multipole gap solitons in Bose-Einstein condensate loaded in a deformed honeycomb optical lattice. Honeycomb lattices possess a unique band structure, the first and second bands intersect at a set of so-called Dirac points. Deformation can result in the merging and disappearance of the Dirac points, and support the gap solitons. We find that the two-dimensional honeycomb optical lattices admit multipole gap solitons. These multipoles can have their bright solitary structures being in-phase or out-of-phase. We also investigate the linear stabilities and nonlinear stabilities of these gap solitons. These results have applications of the localized structures in nonlinear optics, and may helpful for exploiting topological properties of a deformed lattice.     

Discharge characteristic of very high frequency capacitively coupled argon plasma

The discharge characteristics of capacitively coupled argon plasmas driven by very high frequency discharge are studied. The mean electron temperature and electron density are calculated by using the Ar spectral lines at different values of power(20 W–70 W) and four different frequencies(13.56 MHz, 40.68 MHz, 94.92 MHz, and 100 MHz). The mean electron temperature decreases with the increase of power at a fixed frequency. The mean electron temperature varies nonlinearly with frequency increasing at constant power. At 40.68 MHz, the mean electron temperature is the largest. The electron density increases with the increase of power at a fixed frequency. In the cases of driving frequencies of 94.92 MHz and 100 MHz, the obtained electron temperatures are almost the same, so are the electron densities. Particle-in-cell/MonteCarlo collision(PIC/MCC) method developed within the Vsim 8.0 simulation package is used to simulate the electron density, the potential distribution, and the electron energy probability function(EEPF) under the experimental condition.The sheath width increases with the power increasing. The EEPF of 13.56 MHz and 40.68 MHz are both bi-Maxwellian with a large population of low-energy electrons. The EEPF of 94.92 MHz and 100 MHz are almost the same and both are nearly Maxwellian.     

Electrocatalytic oxidation of methanol at platinum electrode modified with Eu-Fe cyanide-bridged binuclear complexes

<正>The electrocatalytic oxidation of methanol at the platinum electrode modified with Eu-Fe cyanide-bridged binuclear complexes (Eu-Fe film) was investigated for the first time by cyclic voltammetry.Compared with the bare platinum electrode,the results showed that the modified electrode had excellent electrocatalytic activity for the oxidation of methanol;the oxidation peak potential shifted more negatively and the peak current increased about twenty times.The electrooxidation of methanol at the modified electrode with Eu-Fe cyanide-bridged binuclear complexes material exhibited the better tolerance capacity to poison of intermediate species;the peak current was proportional to the concentration of methanol in the range of 0.5-2.0mol/L (R~2 = 0.9991,n =7),which was a comparatively wider linear range.Moreover,based on the linear relationship between the peak current and the square root of scan rate,electrocatalytic oxidation process of methanol was confirmed to be a diffusion control process.Furthermore,according to the counting of electron transfer number(n_α) in the rate-limiting step and the slope of linear equation between acidity of electrolyte and the oxidation peak potential(E_p),the possible mechanism of the electrooxidation of methanol at the modified electrode was primarily discussed.     

One-pot three-component synthesis of α-aminonitriles using potassium hexacyanoferrate(II) as an eco-friendly cyanide source

An efficient and environmentally friendly method has been developed for the synthesis of α-aminonitriles via one-pot three-component condensation of carbonyl compounds, amines, and potassium hexacyanoferrate(II) in the presence of benzoyl chloride as a promoter. This protocol has the features of use of eco-friendly cyanide source, high yield, and simple work-up procedure.