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241.
熔制了掺铒碲铌玻璃样品(100-X)TeO2-XNb2O5(X=5,10,15,20mol%),测试了其密度、折射率、转变温度、析晶温度、维氏机械强度、吸收光谱、荧光光谱、荧光寿命等参量。利用Judd-Ofelt和McCumber理论分别计算了铒离子强度参量Ωt(t=2,4,6)和受激发射截面σemi的大小,研究了掺铒碲铌玻璃样品光谱参量对Nb2O5成分的依赖性,并与典型的碲锌钠玻璃(75TeO2-20ZnO-5Na2O)在热学、机械强度、光谱性质和放大品行四个方面进行了比较. 相似文献
242.
Hiroki Shigehisa 《Tetrahedron letters》2006,47(41):7301-7306
The first total synthesis of a spiro-isoquinoline alkaloid, (±)-annosqualine, was established by employing an enamide-phenol coupling of a 1-methylene-1,2,3,4-tetrahydroisoquinoline derivative with a hypervalent iodine reagent, where the formation of the phenoxide was recognized to be an essential step for the reaction of the phenolic hydroxyl group with the hypervalent iodine reagent leading to the formation of the desired product. 相似文献
243.
N Murakami T Tanase S Nagai Y Sato T Ueda J Sakakibara H Ando Y Hotta K Takeya 《Chemical & pharmaceutical bulletin》1991,39(8):1962-1966
The Diels-Alder reactions of a cardiac glycoside, proscillaridin (1), with some dienophiles were investigated. The reaction of 1 with alkenes such as methyl vinyl ketone and methyl acrylate afforded 3-oxo-2-oxabicyclo[2.2.2]oct-7-enes (2-5) and para-substituted benzene derivatives (6 and 7), while 1 reacted with alkynes (3-butyn-2-one, methyl propiolate) to yield para- or meta-substituted benzene derivatives (6-9). The biological activities of the resulting derivatives were evaluated by the use of isolated guinea-pig papillary muscle preparations and Na+,K(+)-adenosine triphosphatase (ATPase) preparation from dog kidney. Among the proscillaridin derivatives, compounds 4 and 7 moderately inhibited Na+,K(+)-ATPase activity. Furthermore, the concentration range of 7 over which its positive inotropic effect on guinea-pig papillary muscle preparations, increased from 5% to 95% of maximum was broader than that of 1, i.e., concentration dependency was maintained over a greater range of concentration. 相似文献
244.
O. Dumbrajs La Agusu T. Idehara 《International Journal of Infrared and Millimeter Waves》2006,27(9):1159-1171
Influence of magnetic field tapering on operation of a gyrotron working in the TE
4,12 mode at the second harmonic frequency 1013.67 GHz is investigated. It is found that the existing inhomogeneity of the magnetic
field of the order of 0.25%–0.50% in the cavity allows one to achieve higher efficiencies. It improves also mode competition
scenario by suppressing oscillations of the two parasitic TE
3,6+ and TE
5,5− modes at the fundamental frequencies 513.35 GHz and 503.64 GHz, respectively. 相似文献
245.
A. Borgschulte R. Gremaud S. de Man R.J. Westerwaal J.H. Rector B. Dam R. Griessen 《Applied Surface Science》2006,253(3):1417-1423
The optical properties, the switching kinetics and the lifetime of hydrogen switchable mirrors based on Mg-Ni alloys are determined with particular regard to the composition of the optically active metal-hydride layer in combination with the thickness of the catalytic capping layer. For this, a high-throughput experiment is introduced. The switching kinetics and the reversibility of switchable mirrors are strongly thickness dependent, though the details hinge on the fine structure of the clustered capping layer. Therefore, the kinetics is correlated with the surface structures of Pd on MgyNi1−y as investigated by scanning tunneling microscopy. The results are explained by the so-called strong metal-support interaction (SMSI) state, characterized by a complete encapsulation of the capping layer clusters by oxidized species originating from the support. The SMSI-effect is less important with increasing Pd-layer thickness, and is suppressed by a good wetting of the Pd-clusters on the optically active film. This explains the critical thickness for the catalyzed hydrogen uptake observed in many switchable mirror systems. Moreover, the degradation of the kinetics during cycling is found to depend on the Pd-layer thickness and on the gas environment. Only films, covered with at least 15 nm Pd, show small degradation caused by the SMSI-effect. The SMSI-effect is partly reversible: after changing the gas environment from hydrogen to oxygen, the oxide on the Pd-clusters can be partly removed. 相似文献
246.
We describe the fractal structure of expanding meromorphic maps of the form , where H and Q are rational functions whose most transparent examples are among the functions of the form with . In particular we show that depending upon whether the Hausdorff dimension of the Julia set is greater or less than 1, the
finite non-zero geometric measure is provided by the Hausdorff or packing measure. In order to describe this fractal structure
we introduce and explore in detail Walters expanding conformal maps and jump-like conformal maps.
Received: 3 May 2001 / Published online: 5 September 2002 相似文献
247.
《Solid State Ionics》2006,177(26-32):2711-2714
Ordered-mesoporous Al2O3 was synthesized by a sol–gel method using neutral copolymer surfactants as structure-directing agents. The pore size was controlled over the 3–15 nm range by the use of various surfactants. Composites composed of the synthesized mesoporous Al2O3 and a lithium ion conductor (LiI) were prepared. The maximum dc electrical conductivity, 2.6 × 10− 4 S cm− 1 at 298 K, was observed for 50 LiI·50 Al2O3 composite with 4.2 nm average mesopore size, which was considerably higher than the previously reported LiI-alumina composites. A systematic dependence of conductivity upon pore size was observed, in which conductivity increased with decreasing pore size, except for samples with a pore size of 2.8 nm. The lithium ion diffusion coefficient determined by the 7Li pulsed field gradient nuclear magnetic resonance (PFG-NMR) showed excellent agreement with the measured conductivity calculated by the Nernst-Einstein equation. On the other hand, lithium migration activation energies obtained by quasielastic neutron scattering (QENS) and 7Li NMR spin-lattice relaxation time (T1) were considerably smaller than those obtained from electrical conductivity and PFG-NMR. This could be explained by the ion migration mechanism in heterogeneous composites and a possible enhancement of conductivity in mesoscopically confined spaces. 相似文献
248.
《Tetrahedron: Asymmetry》2006,17(3):434-448
The conversion of enantiomerically enriched (ee >99%) 2α-hydroxypinan-3-one and its oxime (obtained in previously described procedures1 from α-pinene of 65% ee) into a range of derivatives with potential application in asymmetric synthesis was attempted. C2-Symmetrical compounds, ligands for potential catalysts, were synthesized from 2α-hydroxypinan-3-one and either aliphatic or aromatic diamines. Reduction or etherification/reduction of selected diiminodiols afforded respective diaminodiols and diaminoethers, which were further transformed into azolium salts. Reactions of dipinanediaminoethers with dichlorophenylphosphine and subsequent in situ oxidation of the products afford the respective stable phosphinediamide oxides. Four selected compounds were crystallographically studied. 相似文献
249.
Incorporation of Ag in the crystal lattice of Sb2Te3 creates structural defects that have a strong influence on the transport properties. Single crystals of Sb2−xAgxTe3 (x=0.0; 0.014; 0.018 and 0.022) were characterized by measurements of the temperature dependence of the electrical resistivity, Hall coefficient, Seebeck coefficient and thermal conductivity in the temperature range of 5-300 K. With an increasing content of Ag the electrical resistance, the Hall coefficient and the Seebeck coefficient all decrease. This implies that the incorporation of Ag atoms in the Sb2Te3 crystal structure results in an increasing concentration of holes. However, the doping efficiency of Ag appears to be only about 50% of the expected value. We explain this discrepancy by a model based on the interaction of Ag impurity with the native defects in the Sb2−xAgxTe3 crystal lattice. Defects have a particularly strong influence on the thermal conductivity. We analyze the temperature dependence of the lattice thermal conductivity in the context of the Debye model. Of the various phonon scattering contributions, the dominant influence of Ag incorporation in the crystal lattice of Sb2Te3 is revealed to be point-defect scattering where both the mass defect and elastic strain play a pivotal role. 相似文献
250.
《Solid State Ionics》2006,177(35-36):3205-3210
For application in solid oxide fuel cells La0.8Sr0.2CuO2.4+δ was synthesized and the phase evolution was characterized after quenching from different temperatures and after slow cooling. A single phase perovskite was found after quenching from 950 °C. The electrical conductivity of the La0.8Sr0.2CuO2.4+δ perovskite exhibited metallic behavior reaching values of about 270 S/cm at 800 °C in air. The thermal expansion between 30 and 800 °C gave a thermal expansion coefficient of 11.1 × 10− 6 K− 1.At higher temperatures, the perovskite was transformed to the K2NiF4-type structure via an intermediate stage that can be best described as a LaSrCuO4 phase with preferential growing of {020} lattice planes. After sintering at 1100 °C and slow cooling in the furnace a phase mixture of (La,Sr)CuO4+δ and (La,Sr)CuO2.4+δ perovskite was obtained. This phase mixture showed higher electrical conductivity (400 S/cm at 800 °C) and smaller thermal expansion coefficient (9.6 × 10− 6 K− 1) than the single phase La0.8Sr0.2CuO2.4+δ perovskite. 相似文献