Reactive and inhibiting adsorbates for the catalytic electrooxidation of carbon monoxide on gold (210) as characterized by surface infrared spectroscopy

Potential-dependent sequences of surface infrared spectra have been obtained during the voltammetric electrooxidation of solution carbon monoxide on ordered Au(210), in acidic, neutral, and alkaline aqueous media. Under optimal catalytic conditions, only a reactive form of adsorbed CO is detected, yielding a CO stretching frequency (v_CO) at ∼ 2100–2115 cm⁻¹. The occurrence of reaction inhibition is accompanied by the displacement of this adsorbate by a lower v_CO form, located at ∼1900–2000 cm⁻¹, its appearance being favored by increasing surface exposure time and more negative dosing potentials. The mechanistic implications of such combined real-time infrared/voltammetric results are noted.     

Duality in the U(1) Higgs model with an external field

An external electromagnetic field is coupled to the lattice U(1) Higgs model in a Villain form. Duality transformations are then used to express the partition function in terms of an effective lagrangian of topological excitations and their couplings to the external field. Consequences for the phase diagram are derived.     

Systematic approach to conformal systems with extended Virasoro symmetries

The Toda field theories, which exist for every simple Lie group, are shown to give realizations of extended Virasoro algebras that involve generators of spins higher than or equal to two. They are uniquely determined from the canonical lagrangian formalism. The quantization of the Toda field theories gives a systematic treatment of generalized conformal bosonic models. The well-known pattern of conformal field theories with non-extended Virasoro algebra, appears to be repeated for any simple group, leading to a “periodic table”, parallel to the mathematical classification of simple Lie groups.     

Thirring model partition functions and harmonic differentials

The partition function of the Thirring model on a Riemann surface is calculated using the representation of the model as a fermion interacting with an auxiliary vector potential. The Hodge decomposition of the potential is used and the integral over the harmonic forms is shown to reproduce exactly the soliton sum in the bosonic version of the theory.     

Sensitivity of continuous review stochastic (s,S) inventory systems to ordering delays

This paper examines continuous review stochastic (s, S) inventory systems with ordering delays. That is, systems where the difference between the time the order should be placed and the time the order is actually placed is non-trivial. The traditional inventory ordering, holding and penalty costs are included and the average cost for an (s, S) policy is developed and examined. Computational results are presented for two cases. In the first case, the manager is aware of the delay and uses the policy that minimizes all costs. We present the increase in cost due to having a delay. In the second case the manager is unaware of the delay and uses the (integer) square root formula. We present the increase in cost due to using the square root formula when it is inappropriate and in fact our computational results indicate that there may very well be a large increase in cost due to being unaware of the ordering delay.     

Anomaly cancelling terms from the elliptic genus

We calculate the heterotic string one-loop diagram in 2n + 2 dimensions with one external B_μν and n external gravitons and/or gauge bosons. The result is a modular integral over the weight zero terms of the character valued partition function (or elliptic genus) of the theory, and can be directly expressed in terms of the factor which multiplies TrF² − TrR² in the field theory anomaly. The integrands have a non-trivial dependence on the modular parameter τ, reflecting contributions not only from the physical massless states but also from an infinity of “unphysical” modes. Some of them are identical to integrands which have been discussed recently in relation with Atkin-Lehner symmetry and the cosmological constant. As a corollary we find a method to compute these integrals without using Atkin-Lehner transformations.     

基于模糊综合评判的大学数学考核方式改革

独立高校数学课程的开设旨在让学生掌握数学知识的基础上,提高数学应用能力.然而现行的考核方式存在重考试结果,轻学习过程等问题.从传统考核方式入手,指出其不足之处,基于模糊综合评判法建立新型评价体系和数学模型,通过试点运行验证了新的考核方式的可行性、客观性、合理性和科学性.