Structure,Electrical and Oxygen Transport Properties of Fe-Doped SrCoO3?δ Perovskites

The structure-property relationship of Fe-doped SrCoO_3-δ was studied. With increase of Fe content in SrCo_1-xFe_xO_3-δ from x=0 to x=0.2, the phase composition changed progressively in the order of hexagonal→brownmillerite (main)+hexagonal→cubic (main)+brownmillerite→single cubic phase. Transition between the hexagonal/brownmillerite phase and the cubic phase took place with variation of the operating conditions, and was associated with remarkable changes in the electrical conductivity and oxygen permeation flux.     

Flapping dynamics of a piezoelectric membrane behind a circular cylinder

The flapping dynamics of a piezoelectric membrane placed behind a circular cylinder, which are closely related to its energy harvesting performance, were extensively studied near the critical regime by varying the distance between the cylinder and the membrane. A total of four configurations were used for the comparative study: the baseline configuration in the absence of the upstream circular cylinder, and three configurations with different distances (S) between the cylinder and the membrane (S/D=0, 1, and 2). A polyvinylidene fluoride (PVDF) membrane was configured to flutter at its second mode in these experiments. The Reynolds number based on the membrane’s length was 6.35×10⁴ to 1.28×10⁵, resulting in a full view of membrane dynamics in the subcritical, critical, and postcritical regimes. The membrane shape and the terminal voltage were simultaneously measured with a high-speed camera and an oscilloscope, respectively. The influence of the upstream cylinder on the membrane dynamics was discussed in terms of time-mean electricity, instantaneous variations and power spectra of terminal voltage and membrane shape, fluctuating voltage amplitude, and flapping frequency. The experimental results overwhelmingly demonstrated that the terminal voltage faithfully reflected various unsteady events embedded in the membrane’s flapping motion. For all configurations, dependency of the captured electricity on a flow speed beyond the critical status was found to follow the parabolic relationship. In the two configurations in which S/D=0 and 1, the extraneously induced excitation by the Kármán vortex street behind the circular cylinder substantially reduced the critical flow speed, giving rise to effective energy capture at a lower flow speed and a relatively high gain in power output. However, in the configuration in which S/D=2, the intensified excitation by the Kármán vortex street on the membrane considerably reduced the captured energy. Finally, a transient analysis of the membrane’s flapping dynamics in the configuration in which S/D=0 was performed in terms of phase-dependent variations of the membrane segment’s moving speed, membrane curvature, and terminal voltage; the analysis resulted in a full understanding of the energy harvesting process with consecutive inter transfer of elastic, kinetic, and electric energies.     

复合材料Reissner板中与界面相交的裂纹奇异性分析

基于切口尖端附近区域位移场的渐近展开,提出了分析复合材料板中与界面相交的切口应力奇异性的新方法。将位移场渐近展开式的典型项代入弹性板的基本方程,得到关于复合材料板中与界面相交的切口应力奇异性指数的一组非线性常微分方程的特征值;采用变量代换法,将非线性特征问题转化为线性特征问题,并用插值矩阵法求解获得了各向异性结合材料中与界面以任意角相交的裂纹尖端的应力奇异性指数随裂纹角的变化规律;最后将计算结果与现有结果进行对比。结果表明:两种结果吻合较好,表明本文方法是有效的。     

水体高光谱反演混合光谱空间信息分解模型研究

水体高光谱中的混合效应问题是水体定量遥感中的难点。已有研究表明,仅依赖标量光谱信息难以解决复杂的水体混合光谱问题。广域水体污染物除光谱信息之外,还具有明显的空间分布特性。充分利用其空间维信息,可以作为遥感光谱维信息的有益补充,有利于水体复杂光谱的解混。以巢湖为例,HJ-1A HSI高光谱数据为数据源,辅以水面光谱测量数据,在空间地统计学和遗传算法理论基础上,利用地统计学中的变异函数模拟相邻空间两像元的分布差异,将邻域像元空间变异函数作为遗传算法目标函数的约束条件,建立基于协同克里格遗传算法的湖泊水体高光谱反演混合光谱空间信息分解模型,并对悬浮物浓度反演结果进行检验。结果显示,与常规混合光谱分解模型相比,混合光谱空间信息分解模型对悬浮物浓度的预测值与实测值相关系数为0.82,均方根误差9.25 mg·L-1,相关系数提高了8.9%,均方根误差下降了2.78 mg·L-1,表明该模型对悬浮物浓度具有较强的预测能力。该方法将水体的空间信息与光谱信息有效结合,可以避免水色参数光谱信号弱导致反演结果失真,同时由于高光谱波段多、信息量大,带来信息提取计算量大而复杂等问题,也为复杂水体混合光谱模型的求解和模型反演精度的提高提供了有效途径。     

SnPc在Ag(111)表面吸附特性的第一性原理研究

采用第一性原理研究了SnPc分子在Ag(111)表面的吸附构型和电子结构. Sn-up和Sn-down两种优化的吸附构型与实验测量结果非常吻合,SnPc以Sn-down构型吸附在Ag(111)表面显得更稳定. Sn原子在两种吸附构型之间转换所需要能量与转换方向有关,由Sn-up向Sn-down构型转换时需翻越一个1.68 eV的能垒,反之需要2.17 eV. 扫描隧道显微镜理论模拟图像给出实验观测结果的主要特征,Sn-up分子的中心处为一个亮斑,而Sn-down分子中心为一个空洞. 计算结果验证了实验提出的Sn原子吸附位置的转换机理.     

Comparisons of ZnO codoped by group IIIA elements (Al, Ga, In) and N: a first-principle study

The electronic structures and effective masses of the N mono-doped and Al-N,Ga-N,In-N codoped ZnO system have been calculated by a first-principle method,and comparisons among different doping cases are made.According to the results,the impurity states in the codoping cases are more delocalised compared to the N mono-doping case,which means a better conductive behaviour can be obtained by codoping.Besides,compared to the Al-N and Ga-N codoping cases,the hole effective mass of In-N codoped system is much smaller,indicating the p-type conductivity can be more enhanced by In-N codoping.     

Investigation on the combustion efficiency and residual of nitrocellulose–alcohol humectant mixtures

To have an insight into the fire properties of nitrocellulose–isopropanol and –ethanol mixtures, the experimental data in previous work are further extracted and analyzed carefully. Generally, the effective heats of combustion of the two samples characterized by both the peak and mean heat release rates decrease with the increasing external irradiance levels. The combustion efficiencies characterized by the ratio of carbon dioxide (CO₂) to carbon monoxide (CO), regardless of the maximum and mean values, also show the similar decreasing tendency, exhibiting a lower combustion efficiency at elevated external radiation. With respect to the X-ray photoelectron spectroscopy results, the two nitrocellulose–alcohol mixtures appear to yield the similar species of combustion residuals, but slightly different in the atomic concentrations, which may be due to the differences in the alcohol humectant and nitrogen content in nitrocellulose substrate. These findings are expected to provide further understanding of fire properties of nitrocellulose–alcohol mixtures and help with fire investigation of such type of fires.

     

XRD与SEM的钢渣尾渣物理激发机理研究

钢渣是冶金工业中产生的主要固体废弃物,其产量约为每年粗钢产量的15%~20%。由于技术的局限,导致我国钢渣利用率较低,仅为年钢渣产量的10%;同时加之管理制度的不健全,导致钢渣大量露天堆放,对土地资源、地下水源,以及空气质量造成严重影响。固体废弃物再利用是资源可持续发展的重要途径之一,由于钢渣的主要化学成分(CaO,SiO₂,A1₂O₃,MgO,Fe₂O₃,MnO,f-CaO等)、主要矿物组成(硅酸三钙、硅酸二钙、钙镁橄榄石、钙镁蔷薇辉石、铁酸二钙等)与水泥熟料的主要化学成分、主要矿物组成极为相似,是一种具有潜在胶凝活性的胶凝材料。以钢渣尾渣作为研究对象,采用机械研磨的方式对钢渣尾渣处理,即物理激发,获得不同粒径钢渣尾渣微粉。依据《用于水泥和混凝土中的钢渣粉》(GB/T 20491-2006)与《水泥胶砂强度检验方法(ISO法)》(GB/T 17671-1999)制备一系列钢渣尾渣胶砂试块(分别标记为A₄₀,A₆₀,A₈₀,A₁₀₀和A₁₂₀)。研究对钢渣尾渣胶凝活性的影响,以及不同水化时间对钢渣尾渣胶凝活性的影响,即3 d钢渣尾渣胶砂强度、7 d钢渣尾渣胶砂强度与28 d钢渣尾渣胶砂强度。利用激光粒度分析仪(LPSA)对钢渣尾渣微粉的粒径分布进行测试与分析,X射线衍射仪(XRD)对钢渣尾渣微粉与钢渣尾渣胶砂的矿物组成进行测试与分析,扫描电子显微镜(SEM)进行微观形貌测试与分析,从而获得钢渣尾渣的物理激发机理。结果表明,随着钢渣尾渣微粉粒径的减小,其胶凝活性呈现先增加后降低的趋势,当研磨时间为80 min时,A₈₀钢渣尾渣微粉的胶凝活性最高,即3 d活性指数为67.55%、7 d活性指数为71.96%和28 d活性指数为73.61%。随着钢渣尾渣微粉粒径的减小,钢渣尾渣微粉中RO相的XRD特征峰强度稳定,Ca₂SiO₄与Ca₃SiO₅的XRD特征峰强度呈现先增加后降低的趋势,Ca₃SiO₅与Ca₂SiO₄参与水化反应,生成一定量的Ca(OH)₂与C-S-H凝胶,具有良好的胶凝活性。A₈₀钢渣尾渣微粉中Ca₂SiO₄含量较少,而Ca₃SiO₅含量较多,均可以生成一定量的Ca(OH)₂与C-S-H凝胶,小幅提高A₈₀钢渣尾渣胶砂的早期(3~7 d)力学性能,大幅提高A₈₀钢渣尾渣胶砂的中、后期(7 d~28 d)力学性能。当水化时间3 d时,A₈₀钢渣尾渣胶砂中存在少量水化产物且大量分散小颗粒;当水化时间7 d时,A₈₀钢渣尾渣胶砂中水化产物大幅增加且形成较大颗粒;当水化时间28 d时,A₈₀钢渣尾渣胶砂中形成大量水化产物且几乎不存在分散小颗粒。从而进一步实现固体废弃物的资源化再利用,达到钢铁企业增加效益,环境缓解压力的目的。     

主应力轴旋转下黏土累积变形的分数阶元件模型

在长期交通载荷作用下土体塑性累积变形本构模型对路基沉降计算至为关键.元件组合模型可以计算岩土体循环累积应变,但现有的各类元件模型未能反映饱和软黏土的主应力轴循环旋转现象.在对饱和软黏土进行等向固结条件下的主应力轴循环旋转加载试验及非等向固结下的循环扭剪试验基础上,将Abel黏壶代替Burgers模型中的Newton黏壶,得到分数阶Burgers模型;利用遗传算法优化循环塑性累积应变的Burgers模型和分数阶Burgers模型的参数,通过对比两组模型的计算值与试验值,发现分数阶模型更适合模拟计算循环载荷下饱和软黏土的累积变形.     

SHPB试验中岩石试件的端面不平行修正

为研究短圆柱体岩石试件端面不平行对岩石动力学特性测试结果的影响,采用有限元分析软件LS-DYNA对9种端面不平行度和5种杨氏模量的岩石试件开展SHPB(split Hopkinson pressure bar)试验数值模拟,对岩石选用HJC(Holmquist-Johnson-Cook)本构模型。数值模拟结果表明,当端面不平行度在0.40%以内时,端面不平行对动态应力测试结果的影响可忽略不计;但对动态应变测试结果的影响较大。当杨氏模量一定时,平均应变率测试误差和峰值应变测试误差随端面不平行度增大呈线性增大;当端面不平行度一定时,平均应变率测试误差和峰值应变测试误差随杨氏模量增大也呈线性增大。对数值模拟得到的平均应变率测试误差和峰值应变测试误差实施二元线性回归分析,提出了SHPB试验中端面不平行岩石试件平均应变率和峰值应变的修正公式。