The layered structure oxide Ca3Co4O9 particle was synthesized by two routes of citrate sol–gel method. The structure, morphology and surface property of Ca3Co4O9 was characterized by XRD, SEM and XPS, respectively. The catalytic activity of Ca3Co4O9 for methane combustion was tested in a fixed bed quartz tubular microreactor. The catalysis results reveal that the catalytic
activity is sensitive to the texture of Ca3Co4O9 by different route. TG measures confirm that the small particle size of Ca3Co4O9 favors the oxygen transformation on the surface, which can be ascribed the random distribution of the crystal axes in irregular
Ca3Co4O9 particle. 相似文献
Using the nanosecond single-pulse laser-induced breakdown-spectroscopy (LIBS) technique, we determine the LIBS spectrum of a mixed solution of soluble compounds as a sample. Based on the LIBS measurement system established and the best experimental parameters, we measure the plasma emission spectrum of some lines of the Cr element. When the ICCD gate delay is measured from 500 to 2500 ns every 500 ns, and the liquid sample flow rate is set in the range of 35 ml · min?1?55 ml · min?1 with an interval of 5 ml · min?1, the partial emission line of the Cr element in the laser plasma is measured, and the Boltzmann oblique line is drawn after the integrated intensity obtained. We calculate the evolution characteristics of the laser-plasma electron temperature with experimental parameters. The results show that the electron temperature values obtained from the intensity of the spectral lines of different elements are consistent with each other, indicating the reliability of the experimental measurement data. The range of electron temperature is obtained from the intensity of the Cr element line in the plasma range from 4071.0 K to 5628.4 K. As the flow rate continues to increase, the plasma electron temperature also increases but gradually becomes gentle. We select Cr 357.87 nm as the analytical line in the experiment and measure the particle density ratios of the Cr element in the ground state at different ICCD gate delays and sample flow rates. It provides experimental parameter support for further LIBS quantitative analysis of trace heavy metal elements in a liquid matrix.
Acridinediones were synthesized by the one-pot Hantzsch condensation of an aromatic aldehyde, 5,5-dimethyl-1,3-cyclohexanedione, and aniline/4-methylaniline in re?uxing water. This method has then been extended to the four-component reaction of an aromatic aldehyde, 5,5-dimethyl-1,3-cyclohexanedione, ethyl acetoacetate and ammonium acetate for the synthesis of polyhydroquinoline derivatives. This is an environmentally friendly and efficient procedure providing good to excellent yields. 相似文献
A small fluctuation of the photon beam position will affect the intensity and polarization characteristics of synchrotron radiation (SR) when it enters an endstation through the related beamline. In this paper, by changing the electron orbit equilibrium position in the vertical direction, we have measured the corresponding changes in the absorption strength of the SR with a gold mesh in different chopper aperture positions. It is found that for three aperture positions, the absorption intensity of the gold mesh shows a good Gaussian distribution as the photon beam position moves, while the ratio of the SR intensity passing through the upper and lower apertures shows a monotonous variation. This suggests a new method for estimating the circular polarization degree of SR originating from the bending magnet based on our current measurement. 相似文献
In this paper, cooperative predator–prey system with impulsive effects and Beddington–DeAngelis functional response is studied. By using comparison theorem and some analysis techniques as well as the coincidence degree theory, sufficient conditions are obtained for the permanence, extinction and the existence of positive periodic solution. 相似文献