数字微镜器件反射效率测试方法及装置北大核心CSCD

为了获得数字微镜器件的真实光学特性,提出了其反射特性测试方法,并搭建实验装置对数字微镜器件的相对反射效率进行了测试,搭建了测试光路;利用该光路分别测得数字微镜器件和铝反射镜作为反射元件时相机接收到的光斑能量分布曲线,并对曲线进行积分;将2种测试条件下获得的积分值做除法,得到数字微镜器件的相对反射效率。测试结果表明,在使用632.8 nm波长激光器作为光源时数字微镜器件的相对反射效率为45.33%,在使用白光LED作为光源时数字微镜器件的相对反射效率为71.75%,经过多次测试发现2种测试模式下的重复精度均为±5%左右。上述测试结果可对今后使用数字微镜器件开发相关仪器时的能量传递效率计算以及器件选择起到一定参考作用。     

Controllable dissipative soliton and Q-switched pulse emission in a normal dispersion fiber laser using SESAM and cavity loss tuning mechanism

We report on the controllable generation of the dissipative soliton and the Q-switched pulse in a normal dispersion fiber ring laser. The hybrid saturable absorber is used to obtain the dissipative soliton or the Q-switched pulse by slightly adjusting the polarization controller. Based on the experimental results and theoretical analysis, the controllable dissipative soliton and Q-switched pulse emission can be induced by the cavity loss tuning mechanism of the fiber laser.     

Synthesis of Enantioenriched Sulfoxides by an Oxidation-Reduction Enzymatic Cascade

Chiral sulfoxides are versatile synthons and have gained a particular interest in asymmetric synthesis of active pharmaceutical and agrochemical ingredients. Herein, a linear oxidation–reduction bienzymatic cascade to synthesize chiral sulfoxides is reported. The extraordinarily stable and active vanadium-dependent chloroperoxidase from Curvularia inaequalis (CiVCPO) was used to oxidize sulfides into racemic sulfoxides, which were then converted to chiral sulfoxides by highly enantioselective methionine sulfoxide reductase A (MsrA) and B (MsrB) by kinetic resolution, respectively. The combinatorial cascade gave a broad range of structurally diverse sulfoxides with excellent optical purity (>99 % ee) with complementary chirality. The enzymatic cascade requires no NAD(P)H recycling, representing a facile method for chiral sulfoxide synthesis. Particularly, the envisioned enzymatic cascade not only allows CiVCPO to gain relevance in chiral sulfoxide synthesis, but also provides a powerful approach for (S)-sulfoxide synthesis; the latter case is significantly unexplored for heme-dependent peroxidases and peroxygenases.     

利用重叠分离机构进行纸张分离的纸张动态分析

介绍了重叠分离机构的工作原理,采用修正的库伦摩擦力模型建立纸张通过重叠分离机构的动力学方程,在纸张通过分离机构的过程中考虑了纸币所受变形力随时间的变化,并运用Matlab软件进行了数值仿真,分析了重叠分离机构对纸币分离的影响因素。结果表明,随着重叠分离机构的交叠量、剥离轮转矩和剥离轮摩擦系数的增加,对单张纸币通过分离机构延迟越大,而双张纸币通过分离机构时,对连张纸币的抑制作用增强,便于纸币分离;对于分离效果而言,剥离轮转矩的影响偏小。     

Ultra-short optical pulse shaping using semiconductor optical amplifier

Optical ultra-short pulse compression and amplification using semiconductor optical amplifier (SOA) is presented. Using pump-probe pulse configuration, we present an SOA model which includes the nonlinear effects such as, spectral hole burning (SHB), carrier heating (CH), two-photon absorption (TPA) and group velocity dispersion (GVD) taking into account gain spectrum effect. Then by adjusting time delay between the pump pulse and probe pulse we use the model for simultaneous compression and amplification of probe pulse. We also analyze the four wave mixing (FWM) signal during pulse compression process. It is shown that dispersive effect of GVD on output probe pulse becomes more important for larger cavity length and probe-pump pulses relative time delays.     

Enzymatic Electrosynthesis of Glycine from CO2 and NH3

Enzymatic electrosynthesis has gained more and more interest as an emerging green synthesis platform, particularly for the fixation of CO₂. However, the simultaneous utilization of CO₂ and a nitrogenous molecule for the enzymatic electrosynthesis of value-added products has never been reported. In this study, we constructed an in vitro multienzymatic cascade based on the reductive glycine pathway and demonstrated an enzymatic electrocatalytic system that allowed the simultaneous conversion of CO₂ and NH₃ as the sole carbon and nitrogen sources to synthesize glycine. Through effective coupling and the optimization of electrochemical cofactor regeneration and the multienzymatic cascade reaction, 0.81 mM glycine was yielded with a highest reaction rate of 8.69 mg L⁻¹ h⁻¹ and faradaic efficiency of 96.8 %. These results imply a promising alternative for enzymatic CO₂ electroreduction and expand its products to nitrogenous chemicals.     

Magnetocaloric effect in polycrystalline (La0.5Gd0.2)Sr0.3MnO3

In this paper, we present a study of magnetocaloric effect in the colossal magnetoresistance material (La_0.5Gd_0.2)Sr_0.3MnO₃. From the measurements of isothermal magnetization at different temperatures, we have discovered a large magnetic entropy change with a broad peak around Curie temperature (270.5 K) in (La_0.5Gd_0.2)Sr_0.3MnO₃ polycrystalline sample. Moreover, the maximum of magnetic entropy change exhibits a nearly linear dependence with applied high magnetic field. These results suggest that this material is a suitable candidate as working substance in magnetic refrigeration near room temperature.     

Stereocomplementary Synthesis of β-Aryl Propanamines by Enzymatic Dynamic Kinetic Resolution-Reductive Amination

Chiral β-aryl propanamine is an important structure unit of bioactive molecules or drugs. But its efficient synthesis remains a challenging task. In this study, several enantiocomplementary imine reductases capable of dynamic kinetic resolution-reductive amination of sixteen 2-phenylpropanal derivatives of diverse structural characteristics with four different amines were identified through screening 196 imine reductases. Furthermore, (S)-IR60, (R)-IR74 and (R)-IR207 were applied to access a series of different β-aryl propanamines with excellent ee values (90 to 99 %) and high isolated yields (36 to 79 %), and two of them were further transformed into 3-methylindolines through intramolecular Buchwald-Hartwig cross-coupling and deallylation, providing an effective method to construct this class of pharmaceutically important compounds.