不同变质程度煤尘爆炸压力特性变化规律实验研究

为研究不同变质程度煤尘爆炸压力特性变化规律,以最大压力pmax和最大压力上升速率(dp/dt)max表征压力特性,使用近球形煤尘爆炸装置对褐煤、长焰煤、不黏煤和气煤的爆炸压力特性变化规律展开分析。研究发现:在4种煤尘样品中,褐煤的pmax和(dp/dt)max均最大,分别达0.71 MPa和65.69 MPa/s。随变质程度增大,长焰煤、不黏煤和气煤的pmax和(dp/dt)max均明显减小,说明以爆炸压力特性为标准,4种煤尘爆炸强度由高到低依次是褐煤、长焰煤、不黏煤和气煤。通过对比爆炸前后煤尘挥发分含量,得出参与爆炸的挥发分含量所占质量分数为46.28%~68.19%。在喷尘压力 p0=2.0 MPa,点火延迟时间t0=100 ms时,4种煤尘pmax值均达最大,分别为0.71、0.60、0.55和0.47 MPa。褐煤、不黏煤和气煤在 p0=2.0 MPa,t0=80 ms时(dp/dt)max达最大,而长焰煤则在 p0=2.0 MPa,t0=100 ms时(dp/dt)max达到最大。     

Gross-Pitaevskii方程的数值解及其动力学研究

采用辛-打靶法求解了简谐势阱中碱金属玻色-爱因斯坦凝聚原子在T=0时的基态波函数,检验了波函数的稳定性,并研究了当简谐势阱突然改变时波函数随时间演化的动力学.     

Synthesis and reactivity of bis(trimethylsilylcyclopentadienyl)- niobium compounds with cumulene ligands

The reduction of Nb(η⁵-C₅H₄SiMe₃)₂Cl2 (I) with Na/Hg in a 1/1 molar ratio gives Nb(η⁵-C₅H₄SiMe₃)₂Cl (II). Reactions of II with some cumulenes give the corresponding niobocene derivatives with the functional groups anchored to the bis(trimethylsilylcyclopentadienyl)niobium unit, Nb(η⁵-C₅H₄SiMe₃)₂Cl(CS₂), Nb(η⁵-C₅H₄SiMe₃)₂Cl(PhNCX) (X = O or S) and Nb(η³-C₅H₄SiMe₃)₂Cl(CyCN- Cy). The imido compound Nb(η⁵-C₅H₄SiMe₃)₂Cl(NPh) has been prepared. The chemical properties and structural features of the compounds are described.     

Growth and Characterization of Trumpet-Shaped ZnO Microtube Arrays on Si Substrates

Aligned trumpet-shaped zinc oxide microtube arrays have been successfully prepared on silicon （100） substrates via the chemical vapour deposition method with a mixture of ZnO and active carbon powders as reactants. The results show that two types of trumpet-shaped ZnO microtubes can be obtained. A plausible growth mechanism based on the studies of scanning electron microscopy （SEM）, transmission electron microscopy （TEM）, x-ray diffraction （XRD）, and room-temperature photoluminescence spectroscopy is proposed and discussed. The initial metastable zinc-rich ZnOx embryos play a key role in the formation of trumpet-shaped ZnO microtubes. On the different surfaces of metastable zinc-rich ZnOx （x 〈 1）, embryos exhibit different stabilities and resistivities to oxidation; these tiny embryos are gradually extended with different growing rates along the directions of its long axis and circular boundary around its oxide shell. Just this special reason creates the formation of trumpet-shaped microtubes and results in the inerratic and imperfect hexagonshaped cross section that appears. Moreover, the analytical results also show that the as-synthesized ZnO microtube arrays can exhibit better room-temperature photoluminescence behaviour.     

动脉中脉搏波传播分析

将血管简化为弹性管,并考虑组织对血管壁的约束,利用力学方法建立血液流过血管的力学模型．通过理论分析对脉搏波在血管中的传播规律进行研究,同时分析了血液粘性、血管壁弹性模量、管径对波的传播的影响．通过对考虑血液粘性和不考虑血液粘性的结果比较,发现血液的粘性对脉搏波的传播的影响不能忽略,并且当弹性模量增大时,传播速度增大,血流的压力值增高;血管直径减小时,血流压力也增高,脉搏波速度增大．理论分析得到的结果也有助于利用脉搏波的信息来分析和辅助诊断一些人体疾病的病因．     

基于CPLD的线阵CCD光谱检测数据采集系统的研究

血液成分无创检测已成为生物医学工程领域关注的焦点和热点,其中以近红外血液成分检测最为突出,而动态光谱检测方法以能消除近红外血液成分检测中的个体差异和测量条件的影响备受研究者 的青睐。但是,由于动态光谱检测系统要求较高的幅值精度和高的时间分辨率,因此要求所采用的CCD(charge coupled device)系统进行较长时间的实时输出,其数据量较大,需要匹配高速数据传输模块 。文章介绍了一种基于CPLD(complex programmable logic device)的CCD数据采集系统,整个系统以CPLD为主芯片,它不仅为CCD提供工作时序信号,同时还控制信号调理、转换、传输模块中的采样率、 相关双采样的时序和数据的存储与传输。采用CPLD器件不但简化了系统结构,提高了整个系统的速度,而且达到了幅值精度和时间分辨率的要求。     

Fluid-solid coupling mathematical model of contaminant transport in unsaturated zone and its asymptotical solution

IntroductionThetransportofcontaminantsinunsaturatedzonehascausedmuchattention .Inearly1960s,contaminationproblemsofsoilandgroundwaterhadbeenstudiedathomeandabroad[1].Andinrecentyears ,thetransformationandtransportationofcontaminantshavebeendeeplystudiedinthefieldsofhydrogeology ,petroleumengineering ,environmentalengineeringandsoon[2 ,3].Somecontaminanttransportmodelshavebeenpresentedsofar.Forexample ,Paker[4 ]etal.presentedaconstitutivemodelgoverningparametersofwater,gasandcontaminantswhenth…     

污染物在非饱和带内运移的流固耦合数学模型及其渐近解

污染物在非饱和带中运移过程是多组分多相渗流问题.在考虑气相的存在对水相影响的前提下,基于流固耦合力学理论,建立了污染物在非饱和带内运移的流固耦合数学模型.对该强非线性数学模型采用摄动法及积分变换法进行拟解析求解,得出了解析表达式.对非饱和带内的孔隙压力分布、孔隙水流速以及污染物的浓度在耦合与非耦合气相条件下的分布规律进行解析计算.对该渐近解与Faust模型的计算结果进行了对比分析,结果表明:该模型解与Faust解基本吻合,且气相作用以及介质的变形对溶质的输运过程产生较大的影响,从而验证了解析表达式的正确性和实用性.这为定量化预报预测污染物在非饱和带中迁移转化和实验室确定压力-饱和度-渗透率三者之间的关系提供了可靠的理论依据.