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41.
《Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy》1994,50(5):891-896
Infrared spectroscopic analysis of solutions containing 4-hydroxyacetophenone (HAP) and the model surfactant 2-(2-hexyloxyethoxy)ethanol (HOEE) reveal a medium dependent hydrogen bonding competition between homomolecular association ([HAP]n + [HOEE]n) and heteromolecular association ([HAP-HOEE]n) with the former being favoured by low polarity solvents. 相似文献
42.
《Physica A》1996,231(4):534-550
We examine a simple two-lane cellular automaton based upon the single-lane CA introduced by Nagel and Schreckenberg. We point out important parameters defining the shape of the fundamental diagram. Moreover we investigate the importance of stochastic elements with respect to real life traffic. 相似文献
43.
Thermodynamics and weak cosmic censorship conjecture of BTZ black holes in extended phase space
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As a charged fermion drops into a BTZ black hole, the laws of thermodynamics and the weak cosmic censorship conjecture are investigated in both the normal and extended phase space, where the cosmological parameter and renormalization length are regarded as extensive quantities. In the normal phase space, the first and second law of thermodynamics, and the weak cosmic censorship are found to be valid. In the extended phase space, although the first law and weak cosmic censorship conjecture remain valid, the second law is dependent on the variation of the renormalization energy d K. Moreover, in the extended phase space, the configurations of extremal and near-extremal black holes are not changed, as they are stable, while in the normal phase space, the extremal and near-extremal black holes evolve into non-extremal black holes. 相似文献
44.
WU Yichao DENG Xiuqing MAO Yinchun ZHANG Yan LIU Jiaqin RONG Li XU Zhihong 《高等学校化学研究》2015,31(1):103-106
The transfer enthalpies and entropies of hydroxyl and nitryl in different mobile phase systems were compared by van't Hoff curve. Results suggest that the presence of acetonitrile and methanol in the mobile phase may decrease the interaction of solute and stationary phase with respect to subcritical water, thereby reducing the contribution of enthalpy to the retention. Retention mechanisms of phenolic compound appear to be more similar in subcritical water and water/methanol systems on the PRP-1 column. Hydrogen bond in subcritical water system plays a very important role in the retention of the phenols. 相似文献
45.
Titanium films were deposited on glass substrates at room temperature by direct current (dc) magnetron sputtering at fixed Ar pressure of 1.7 Pa and sputtering time of 4 min with different sputtering power ranging from 100 to 300 W. Atomic force microscopy (AFM) was used to study topographic characteristics of the films, including crystalline feature, grain size, clustering and roughening. The amorphous-like microstructure feature has been observed at 100-150 W and the transition of crystal microstructure from amorphous-like to crystalline state occurs at 200 W. The increase in grain size of Ti films with the sputtering power (from 200 to 300 W) has been confirmed by AFM characterization. In addition, higher sputtering power (300 W) leads to the transformation of crystal texture from globular-like to hexagonal type. The study has shown that higher sputtering power results in the non-linear increase in deposition rate of Ti films. Good correlativity between the surface roughness parameters including root mean square (RMS) roughness, surface mean height (Ra) and maximum peak to valley height (P-V) for evaluating the lateral feature of the films has been manifested. Surface roughness has an increasing trend at 100-250 W, and then drops up to 300 W. 相似文献
46.
47.
Qunchao Fan Weiguo Sun Hao Feng 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(4):911-916
A parameter-free analytical formula for dissociation energies of diatomic molecules is proposed by Fan and Sun (2009) [20] based on LeRoy and Bernstein's vibrational energy expression near dissociation limit. Using three highest vibrational energies which may be generated by the algebraic method (AM) presented in our previous study and by some other physical methods, the new formula is applied to study the molecular dissociation energies of 10 electronic states of KH, 7LiD, 7LiH, 6LiH, NaK, NaLI and NaRb heteronuclear diatomic molecules which have regular (Morse-like) potentials in this work. The results show that the AM energies and dissociation energies have excellent agreement with experimental values. 相似文献
48.
集值信息系统在相容关系下的属性约简 总被引:3,自引:0,他引:3
借助于属性集值的相似程度在集值信息系统上定义了一种新的相客关系,给出了这种相客关系下集值信息系统的属性约简与判定,得到了集值信息系统属性约简的具体探作方法,并讨论了相似水平对集值信息系统的属性约简的影响. 相似文献
49.
In this paper,we prove a Marcinkiewicz-Zygmund type inequality for multivariate entire functions of exponential type with non-equidistant spaced sampling points. And from this result,we establish a multivariate irregular Whittaker-Kotelnikov-Shannon type sampling theorem. 相似文献
50.
揭示了二阶变系数线性微分方程和Riccati方程之间的内在联系,证明了在对这两类方程求解时可以相互转化,从而对二阶变系数线性微分方程和Riccati方程的求解提供更多的思路和途径.. 相似文献