Lift forces induced by phase lag between the vortex sheddings from two tandem bluff bodies

Flow-induced forces on two tandem circular cylinders of identical diameter are numerically studied at a Reynolds number of 200. The cylinder center-to-center spacing ratio is varied from 2 to 9. We focus on fluctuating (rms) lift coefficient of the upstream cylinder, vortex dynamics in the gap between cylinders, and phase lag between vortex shedding from the two cylinders. The phase lag was a linear function of the spacing ratio as known in the literature; but it is, as proved here, indeed a nonlinear function of the spacing ratio, Strouhal number and convection velocity of vortices in the gap between the cylinders. The shedding from the two cylinders turns out to be inphase and antiphase alternately as the spacing ratio increases. We unearth that both phase lag and spacing ratio influence the fluctuating lift of the upstream cylinder. With an increase in the spacing ratio, while the influence of the spacing ratio on fluctuating lift diminishes rapidly in an overdamped manner, that of the phase lag makes the fluctuating lift variation underdamped sinusoidal. The inphase and antiphase flows correspond to a local maximum and a local minimum, respectively, in the fluctuating lift variation. An equation is deduced, showing the relationship between the fluctuating lift, spacing ratio, and phase lag. The physics behind the damped-sinusoidal variation in the fluctuating lift is discussed. The investigation directs that the streamwise separation between two tandem wings of airplanes/submarines should be taken into account or optimized. It would also be interesting to see whether fish exploits phase-lag-induced lift to enhance its forward thrust.     

Decontamination of heavy metal complexes by advanced oxidation processes: A review

Heavy metal complexes with high mobility are widely distributed in wastewater from modern industries, which are more stable and refractory than free heavy metal ions. Their removals from wastewater draw increasing attentions and various technologies have been developed, among which advanced oxidation processes (AOPs) are more effectively and promising. Progresses on five representative types of AOPs, including Fenton (like) oxidation, electrochemical oxidation, photocatalytic oxidation, ozonation and discharge plasma oxidation for heavy metal complexes degradation are summarized in this review. Their rationales, advantages, applications, challenges and prospects are introduced independently. Combinations among these AOPs, such as electrochemical Fenton oxidation and photoelectrocatalytic oxidation, are also comprehensively highlighted. Future efforts should be made to reduce acid requirement and scale up for practical applications of AOPs for heavy metal complex degradation efficiently and cost-effectively.     

The carbon nanotubes-based materials and their applications for organic pollutant removal:A critical review

The carbon nanotubes(CNTs) as the emerging materials for organic pollutant removal have gradually become a burgeoning research field.Herein,a mini-review of CNTs-based materials curre ntly studies for organic pollutant elimination is presented.This review summarizes the preparation methods of CNTsbased materials.CNTs-based materials can be used as adsorbents to remove organic pollutants in wastewater.The adsorption mechanisms mainly include surface diffusio n,pore diffusion and adsorption reaction.Most importantly,an in-depth overview of CNTs-based materials currently available in advanced oxidation processes(AOPs) applications for wastewater treatment is proposed.CNTs-based materials can catalyze different oxidants(e.g.,hydrogen peroxide(H_2 O_2),persulfates(PMS/PDS),ozone(O_3) and ferrate/permanganate(Fe(Ⅵ)/Mn(Ⅶ)) to generate more reactive oxygen species(ROS) for organic pollutant elimination.Moreover,the possible reaction mechanisms of removing organic pollutants by CNTs-based materials are summarized systematically and discussed in detail.Finally,application potential and future research directions of CNTs-based materials in the environmental remediation field are proposed.     

Highly efficient degradation of emerging contaminants by magnetic CuO@FexOy derived from natural mackinawite（FeS） in the presence of peroxymonosulfate

In this study,natural mackinawite （Fe S）,a chalcophilic mineral,was utilized to prepare iron/copper bimetallic oxides （Cu O@Fe_xO_y） by displacement plating and calcination process.Various characterization methods prove that Cu⁰is successfully coated on the surface of Fe S,which were further oxidized to Cu O,Fe₃O₄and/or Fe₂O₃during calcination process,respectively.Cu O@Fe_xO_yperformed highly efficient...     

Temporal trends of deuterium excess in global precipitation and their environmental controls under a changing climate

Journal of Radioanalytical and Nuclear Chemistry - Sixty-three representative sites around the world were selected to analyze the long-term variability of deuterium excess (d-excess) and its...     

Different non-radical oxidation processes of persulfate and peroxymonosulfate activation by nitrogen-doped mesoporous carbon

Activated persulfate oxidation is an emerging advanced oxidation process for organic pollutant degradation. Own to different molecular structures and oxidation potentials, persulfate (PDS) and peroxymonosulfate (PMS) may show different degradation performances due to various catalytic mechanisms even by the same catalysts. In this study, the nitrogen-doped mesoporous carbon (N-OMC) was applied to activate PDS and PMS for degrading a model organic pollutant phenol to reveal their activation mechanisms. Results show that both PDS and PMS could be efficiently activated by N-OMC. The degradation of phenol fitted well with pseudo-first-order kinetics, whose kinetic constants increased with the increase of pH, PDS/PMS dosage, and N-OMC dosage. Based on quenching experiments and electron spin resonance spin-trapping technique, the N-OMC was found to activate PDS and PMS via non-radical process of electron transfer and singlet oxygen formation, respectively, instead of the commonly observed radical process. This work will be useful to understand the activation processes of PDS and PMS, and benefit for the development of catalysts for pollutant degradation.     

中心直裂纹平台巴西圆盘复合型动态应力强度因子

为了指导用中心直裂纹平台巴西圆盘(CSTFBD)试样进行岩石复合型动态断裂试验,利用有限元法首先验证了文献中对中心直裂纹巴西圆盘(CSTBD)得到的有关结果,分析比较了不同无量纲裂纹长度(即裂纹半长和圆盘半径之比)时两种圆盘的I, II型动态应力强度因子的时间历程,发现两者的差异大部分在10{\%}以内,同时验证了该文数值方法的可靠性. 然后讨论了CSTFBD试样I, II型动态应力强度因子的复合比、起裂角以及纯II型加载角. 研究成果可为复合型动态断裂试验中CSTFBD试样的加工、试样上应变片的粘贴、起裂方向和起裂时间的估计等提供参考.     

拉伸偏心椭圆孔板的应力集中系数表达式

先用半解析半经验的方法推导出拉伸中心椭圆孔有限宽板应力集中系数的显式表达式．将其计算结果和Durelli的光弹性实验结果、Isida公式以及有限元分析结果比较可知,新推导公式的精度较高,且适用范围更广．再用类似的方法推导出拉伸偏心椭圆孔板应力集中系数的显式表达式．经与Isida的公式和有限元分析结果比较可知,该公式适用范围更广、精度更高．当偏心距在一定范围内,误差小于8%．根据应力集中系数与应力强度因子的关系,由已得到的应力集中系数得出拉伸中心裂纹有限宽板和拉伸偏心裂纹板的应力强度因子．经与已有公式以及有限元分析结果比较可知,该应力强度因子表达式也有足够的精度．     

Irreversibilities in a triple diffusive flow in various porous cavities

Entropy generation minimization approach is a very good method allowing to analyze the engineering systems to exclude technical failure. The present study deals with computational analysis of triple diffusive flow, energy transference and entropy production in different porous cavities from square to triangular through trapezoidal shape. The formulated boundary-value problem has been worked out using the finite element technique and non-primitive variables. The developed computational code has been verified using numerical results of other researchers. Analysis of entropy production due to energy and mass transport, motion friction, and porous material has been performed for different chamber's shapes. Entropy generation analysis in chambers of various geometries under the triple-diffusive flow is a novelty of the present research, where different entropy production mechanisms have been scrutinized for one complex problem. It has been ascertained that average total entropy generation strength raises with buoyancy ratios, Lewis and Rayleigh numbers, but it has the minimum value for the square chamber in comparison with triangular and trapezoidal shapes. Moreover, obtained results characterize a neglecting influence of motion friction on the total entropy generation.     

Circular motion of submillimeter-sized acoustic bubbles attached to a boundary by high-speed image analysis

The circular motion of submillimeter-sized bubbles attached to a boundary in an 18.5 kHz ultrasonic field are investigated experimentally by high-speed photography and image analysis. It is found that the vibration of gas bubbles with diameters of 0.2–0.4 mm is between spherical radial vibration and regular surface fluctuation. Different from the circular motion of suspended bubbles in water, the circular motion of gas bubbles attached to a boundary presents some new characteristics. These bubbles attached to a boundary (wandering bubbles) will rotate around a fixed bubble array (holding bubbles). Both the wondering bubbles and holding bubbles are “degas” bubbles. The primary Bjerknes force acting on wandering bubbles in the acoustic wave field and the secondary Bjerknes force between the wandering bubbles and the holding bubbles strongly affects the circular motion. The circling and residence behavior of gas bubbles is described and analyzed in detail, which is helpful to understand and improve industrial applications such as ultrasonic cleaning, sonochemical treatment, aeration and cavitation reduction.