短波段光学减反膜的溶胶-凝胶法制备及性能分析

 随着大型激光器的发展，对短波段减反膜的要求日益提高，其中钕玻璃激光三倍频（355nm）的减反射成为新的技术要点。采用溶胶-凝胶工艺合成SiO₂溶胶，采用提拉镀膜法制备纳米多孔SiO₂薄膜，薄膜厚度为75nm，折射率控制在1.22，镀制在石英基底上的薄膜其355nm波长的反射率仅为0.2%。通过氨处理工艺和薄膜的表面修饰，薄膜的抗磨擦性能和疏水性能大大提高，薄膜经过蘸有灰尘、乙醇的棉花球擦洗20次和50次后，透射率最大值仅分别降低0.13% 和 0.39%，与水珠的接触角达到110°。     

Large acoustic polaron states and bifurcation in three coupled parallel molecular chains

We consider the properties of the large acoustic polarons in a media composed of three parallel coupled identical macromolecular chains in an equilateral triangular arrangement. The existence of the truly three-dimensional large polarons has been demonstrated. Their appearance demands the complex interference of the effects of the reduced dimensionality, the nature and strength of the interchain coupling and particular geometrical arrangement of molecular chains. Different types of solutions were found and criteria for their existence were formulated in terms of the dimensionless interchain coupling parameter.     

基于状态分析的电子系统抗辐射性能评估方法

建立了一种基于状态分析的电子系统抗辐射能力评估方法，该方法以电子系统中单元器件的辐射效应实验数据为基础，采用行为级电路仿真方法对电子系统功能状态进行分析，并应用蒙特卡罗方法模拟辐射损伤随机性对系统功能状态的影响，最终结合系统功能阈值，给出系统功能的裕量及不确定度估计，进而对系统抗辐射能力进行评估。为了验证评估方法的可行性，应用该方法对某模数转换电子系统的抗总剂量能力进行了评估，并将评估结果与该电子系统的总剂量效应实验结果进行了对比。结果表明该评估方法能够定量给出系统功能在受到辐射损伤后的变化，评估方法给出结果与实验结果在变化趋势和评估结论上基本一致。     

Synthesis,structure and catalytic polymerization activity of half‐sandwich cyclometallated iridium complexes

A series of mononuclear half‐sandwich cyclometallated iridium complexes with Schiff base ligands were synthesized in good yields. Five air‐stable C,N‐chelate mode complexes were obtained smoothly through metal‐mediated C─H bond activation. Treatments of dimeric metal complexes [Cp*IrCl₂]₂ with ligands L1–L5 afforded the corresponding C,N‐chelate mononuclear half‐sandwich iridium(III) complexes 1 – 5 . These iridium complexes exhibit high catalytic activity for norbornene polymerization. Both steric and electronic effects of the substituted groups have influences on the behaviors of the polymerization process. All complexes were characterized using infrared and NMR spectroscopies and elemental analysis. Molecular structures of complexes 1 , 2 and 5 were further confirmed using single‐crystal X‐ray analysis.     

基于灰色数学的洗胃液量的软测量

鉴于洗胃液量实时在线检测与求解的困难,提出利用灰色数学的累加生成方法,把液量作为主导变量,管路二处压力差的累积压力作为二次变量,根据二者之间的一一映射关系,仿真实验研究洗胃液量的软测量技术,给出了实验结果,为液量的工程检测提供了一种数学方法.     

Effect of atmospheric parameters on fine particulate concentration in suburban Shanghai

A study was conducted on the effect of atmospheric parameters,including temperature,wind speed,and relative humidity,on fine particulate mass concentrations measured in Jiading District of Shanghai,China, during the period from January 2009 to January 2010.A sensitivity analysis was applied to investigate the interaction between atmospheric parameters and particulate mass concentration.The experiment revealed that the concentration of particulates increased with particle size from 0.1 to 1.0μm,and decreased with the increase of particle size from 1.0 to 2.5μm.The effects of atmospheric parameters on fine mass concentrations were significantly particle size-dependent.The PM_1.0-2.5 may come from the size increase of smaller particulates after moisture absorption.And the variation of concentrations of PM_0.1-1.0 was mainly attributed to the accumulation of PM_0.1.The ventilation index and dilution index were calculated on the basis of data collected in December 2009.A correlation analysis indicated that there was a significant relation between these two indexes and the particulate concentration by examining the three particle size ranges,0.0-0.1,0.1-1.0,and 1.0-2.5μm.The Spearman correlation coefficients that related the ventilation index to the concentration for the three particle size ranges were -0.45,-0.56 and -0.47, respectively,while the coefficients that related the dilution index to the concentration were -0.36,-0.42 and -0.45,respectively.     

Valuation perspectives and decompositions for variable annuities with GMWB riders

The guaranteed minimum withdrawal benefit (GMWB) rider, as an add on to a variable annuity (VA), guarantees the return of premiums in the form of periodic withdrawals while allowing policyholders to participate fully in any market gains. GMWB riders represent an embedded option on the account value with a fee structure that is different from typical financial derivatives. We consider fair pricing of the GMWB rider from a financial economic perspective. Particular focus is placed on the distinct perspectives of the insurer and policyholder and the unifying relationship. We extend a decomposition of the VA contract into components that reflect term-certain payments and embedded derivatives to the case where the policyholder has the option to surrender, or lapse, the contract early.     

Mathematical modeling of electromagnetic wave propagation in heterogeneous lossy coaxial cables with variable cross section

In this work, we focus on the time-domain simulation of the propagation of electromagnetic waves in non-homogeneous lossy coaxial cables. The full 3D Maxwell equations, that described the propagation of current and electric potential in such cables, are classically not tackled directly, but instead a 1D scalar model known as the telegraphist's model is used. We aim at justifying, by means of asymptotic analysis, a time-domain “homogenized” telegraphist's model. This model, which includes a nonlocal in time operator, is obtained via asymptotic analysis, for a lossy coaxial cable whose cross section is not homogeneous.     

Z-scan analysis and ab initio studies of β-BaTeMo2O9 single crystal

The Z-scan measurements for the non-centrosymmetric optical crystals β-BaTeMo₂O₉ (BTMO) were performed. The corresponding experiments were carried out using the 5 ns pulses of the second harmonic of a nanosecond Nd:YAG laser at the 532 nm wavelength. It was shown that the studied crystals possess promising third-order optical susceptibilities, which allow to use the crystal as optical limiters. The comparison with other oxide materials is presented. To clarify the origin of the observed effect, the electronic and optical properties of BTMO were calculated using the density functional theory (DFT)-based method. The performed calculations of the electronic and optical properties revealed certain peculiar features that can be suitable for the nonlinear optical applications. The relation between the observed nonlinear optical features and the calculated band structure is emphasized. The values of the calculated band gap and refractive index for β-BaTeMo₂O₉ are also reported.