加压毛细管电色谱法分离美西律对映体

采用加压毛细管电色谱法,以羟丙基-β-环糊精作为手性选择剂,对美西律对映体进行手性分离。在优化的试验条件下,16 g·L~(-1)羟丙基-β-环糊精为手性选择剂,pH 2.5的乙腈与10 mmol·L~(-1)磷酸盐缓冲溶液以体积比1比1混合溶液为流动相,运行电压10 kV,毛细管柱温20℃,美西律对映体在4 min内成功分离,分离度为1.51。     

A off–on pH fluorescence probe derived from phenanthro[9,10-d]imidazol-fluorescein based on ESIPT and ICT

Research on Chemical Intermediates - A novel pH fluorescence probe (PIF), derived from phenanthro[9,10-d]imidazole bound to the fluorescein, is designed and synthesized based on the intramolecular...     

碳量子点纳米材料在铅卤钙钛矿太阳能电池中的应用研究进展

碳量子点（CQDs）是一类粒径较小,光学性能显著,且电荷传输性能优异的类半导体纳米材料,在钙钛矿太阳能电池的性能调控和改善中得到广泛的应用。从CQDs纳米材料的合成、性能及应用出发,综述了CQDs纳米材料在钙钛矿太阳能光电器件中电子传输层、钙钛矿光吸收层和空穴传输层等方面的应用进展,并展望了该类材料调控钙钛矿太阳能器件性能的发展趋势。     

Recent advances in the application of metal organic frameworks using in advanced oxidation progresses for pollutants degradation

Metal-organic frameworks (MOFs) materials with highly ordered and porous crystalline structure, have excellent performance in advanced oxidation progresses (AOPs) for organic contaminants degradation in water treatment. This review intends to summarize the timely references and insights for the recent advances in MOFs that are used in AOPs. Starting with the preparation methodologies, including conventional hydrothermal method, electrochemical method, sol-gel method, and emerging microwave and ultrasound assisted synthesis methods. Application and mechanism for MOFs using in various AOPs of Fenton-like, photocatalysis, catalytic ozonation, persulfate catalysis and other emerging oxidation methods are emphatically discussed. We hope this review can comprehensively summarize the research and application progress of MOFs in AOPs, deepen the understanding of the catalytic mechanisms.     

电机设备运行参数远程监控系统设计

本文根据电动机的运行特点,采集电动机的电压、电流、转速和温度四个基本参数,用以观察电动机是否在正常工作状态中,如果出现工作异常,可以及时发现,并及时处理。该系统将电参数检测采集、无线网络技术、工业现场总线技术,以及计算机用户软件有机的结合,实现了对电机远行状态的远程实时监测、控制与管理,使整个系统实现了智能化、网络化、系统化的管理,解决了多地点分布的电机系统无法实现实时控制和系统管理的技术问题。     

基于C#的湿度传感器校准平台设计

针对大量湿度传感器出厂或使用前需要定标或进行误差补偿的技术需求,本文基于C#语言和SQL数据库技术,构建了一种采用传感器融合算法的大批量湿度传感器数据自校准平台。首先通过饱和盐溶液构建标准湿度环境,然后通过MT4080D数字电桥对待校准湿度传感器进行多次测量,之后把测量值矩阵和标准值导入基于最小二乘和加权融合算法的平台进行处理,得到不同固定点湿度环境下传感器标定和补偿的校准数据。该设计实现了操作简单,成本低廉,响应时间短,运算速度快的湿度传感器的软件校准算法平台,具有一定实际应用价值。     

Preparation of ZIF-8 membranes supported on macroporous carbon tubes via a dipcoating–rubbing method

In the present work, a new dipcoating–rubbing method (DCRM) was developed to seed the surface of a macroporous carbon tube with a mixture of graphite and ZIF-8 nanoparticles. A continuous and low-defect ZIF-8 membrane was well formed on the seeded carbon tube by solvothermal growth. The DCRM involved a two-step process including first dipcoating a thin layer of the composite of graphite and ZIF-8 nanoparticles on the carbon surface and then rubbing the layer to form a stable seed layer. The graphite in the composite acting as binding agent could have two functions: (1) anchoring the ZIF-8 seeds onto the carbon surface; (2) smoothing the coarse surface of the macroporous carbon tube, thus forming a high quality ZIF-8 membrane. The as-prepared membrane was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and single gas permeation and was proved to be continuous and low-defect. The ideal selectivity of H₂/CH₄ is 7.9 with a H₂ permeance of 7.15×10⁻⁸ mol Pa⁻¹ s⁻¹ m⁻², which is higher than its corresponding Knudsen diffusion value. We could therefore expect the ZIF-8 membrane supported on macroporous tubular carbon to achieve a high selectivity of H₂ over CH₄ through a molecular sieving effect.     

GeO分子激发态的电子结构和跃迁性质的组态相互作用方法研究

应用多参考组态相互作用方法计算了GeO分子的第一解离极限(Ge(³P_g)+O(³P_g))对应的18个Λ-S电子态的电子结构. 计算中纳入了Ge原子的3d轨道电子的内壳层-价壳层电子关联效应、标量相对论效应和Davidson修正. 基于计算的电子态的电子结构, 通过求解径向Schrödinger方程获得了束缚电子态的光谱常数R_e, T_e, ω_e, ω_eχ_e, B_e, 理论计算给出的这些电子态的光谱常数与之前的实验结果符合得很好. 计算了电子态的电偶极矩随核间距的变化, 分析了电子态的组态成分的变化对电偶极矩的影响. 计算的势能曲线表明, 激发态A¹Π, 1¹Σ^-, D¹Δ, a³Π, a’³Σ⁺, d³Δ 和 e³Σ^-的绝热激发能密集地分布于26000-37000 cm^-1范围内, 这些密集分布的电子态之间的相互作用对振动波函数有明显扰动作用. 借助于激发态之间的自旋-轨道耦合矩阵元, 阐明了邻近的激发态对A¹Π和a³Π的扰动作用. 基于计算的A¹Π-X¹Σ⁺和A’¹Σ⁺-X¹Σ⁺跃迁的电偶极跃迁矩和Franck-Condon 因子, 给出了A¹Π 和A’¹Σ⁺态的最低的六个振动能级的辐射寿命.     

EV自回归模型的一个相合估计

考虑带有测量误差的自回归模型,在不对替代变量和真实变量之间的关系做任何模型假设的情况下,借助核实数据,给出未知参数的一个基于核实与替代两方面信息的最小二乘估计量,并证得该估计量是相合估计.     

Packet error rate analysis of OOK, DPIM and PPM modulation schemes for ground-to-satellite optical communications

Packet error rate of OOK, DPIM and PPM modulation schemes are researched for ground-to-satellite optical communication systems. Analysis process is based on threshold detection for OOK and DPIM, and optimal detection for PPM. Packet error rate of these three modulation schemes are compared for both uplink and downlink, with consideration of the turbulence introduced intensity fluctuation in the ground-to-satellite laser link. Numerical results are given, and based on it, the advantages of PPM and DPIM are discussed, with the comparison to OOK. This work can be helpful for modulation scheme selection in the ground-to-satellite laser communication system design.