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121.
Ou Zhimin Sun Xingyuan Shi Hanbing Bi Hongxia 《Applied biochemistry and biotechnology》2012,168(8):2297-2308
(S) -3-Chloro-1-(2-thienyl)-1-propanol was synthesized by the asymmetric reduction of 3-chloro-1-(2-thienyl)propanone with liquid-core immobilized Candida pseudotropicalis 104. The optimum time was 28?h for the re-cultivation of immobilized cells. The optimum film solvent for the liquid-core capsule was 0.3?% chitosan (M w 1.0?×?105). Conversion decreased with the increase of the liquid-core capsule diameter and with the addition of more substrates at the same reduction time. The immobilized cells show good reduction ability in a potassium phosphate buffer (pH 6.6~7.2). The material outside the spread speed of immobilized cells was not restricted when the shaking speed was higher than 160?r/min. Liquid-core immobilized cells can be reused 11 times. Compared with the batch reduction, the continuous reduction of 3-chloro-1-(2-thienyl)propanone in the membrane reactor with liquid-core immobilized cells as catalyst can relieve the inhibition from a high-concentration substrate. Conversion and enantiometric excess of (S)-3-chloro-1-(2-thienyl)-1-propanol reached 100?% and >99?% in a continuous reduction of 12?g/L 3-chloro-1-(2-thienyl)propanone for 10?days. 相似文献
122.
123.
Wenhe Du Hengjun Zhu Daosen Liu Zhongmin Yao Chengjiang Cai Xiufeng Du Ruibo Ai 《Journal of Russian Laser Research》2012,33(5):456-463
In the past half a century, satellite laser communication has caught the attention of scientists due to its distinct advantages in comparison with conventional satellite microwave communication. For ground-to-satellite and satellite-to-ground data links, the atmosphere is a part of the communication channel; thus, atmospheric turbulence severely degrades the performance of satellite laser communication systems. In general, the Kolmogorov turbulence model is used to study the effect of atmosphere turbulence on satellite laser communications since it has been confirmed by numerous direct measurements of temperature and humidity fluctuations in the atmospheric boundary layer. However, increasing experimental evidence and theoretical investigations have shown that the Kolmogorov theory is sometimes inadequate to describe atmospheric statistics properly, in particular, in some domains of the atmosphere. We analyze the joint influence of Kolmogorov turbulence from the ground to 6 km and non-Kolmogorov turbulence above 6 km on the spot size associated with the uplink and downlink propagation channels for a satellite laser communication system in the geosynchronous orbit, using a power spectrum of non-Kolmogorov turbulence with power law ?5 that describes the refractiveindex fluctuations in the atmosphere above 6 km and considering the combined power spectrum of Kolmogorov and non-Kolmogorov turbulence. Before this analysis, we study the joint influence of the Kolmogorov turbulence from the ground to 6 km and non-Kolmogorov turbulence above 6 km on the scintillation indices of laser beams. 相似文献
124.
研究了一类带有周期边界条件的三维拟抛物粘性扩散方程有限差分解的长时间行为.证明了数值解的存在唯一性,离散系统全局吸引子的存在性,差分格式的长时间稳定性和收敛性.此外,我们给出了上半连续性. 相似文献
125.
Theoretical study of potential energy curves,spectroscopic constants,and radiative lifetimes of low-lying states in an SeO molecule
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<正>The low-lying potential energy curves of the SeO molecule are computed by means of an ab initio multireference configuration interaction technique,taking into account relativistic(scalar plus spin-orbit coupling) effects.The spectroscopic constants ofΩstates for X~3∑~-,a~1△,b~1∑~+,A~3Π,A′~3△,and A″~3∑~+ states are obtained,and they are in good accordance with available experimental values.The Franck-Condon factors and transition dipole moments to the ground state are computed,and the natural radiative lifetimes of low-lyingΩstates are theoretically obtained. Comparisons of the natural lifetimes ofΩstates with previous experimental results and those of isovalent TeO molecule are made. 相似文献
126.
《Tetrahedron: Asymmetry》2001,12(16):2289-2293
The chiral [5-(4-hydroxybutyl)-5′-methyl-2,2′-bipyridine]-bis(2,2′-bipyridine)-ruthenium(II)-bis(hexafluoroantimonate) complex 3 was prepared and characterized by different NMR techniques and successfully separated into enantiomers by electrokinetic chromatography using anionic carboxymethyl-β-cyclodextrin as chiral mobile phase additive (CMPA). The optimum separation conditions were obtained with 40 mM borate buffer at pH 9.5 and 7.5 mg/mL of the chiral selector at 20°C. 相似文献
127.
《Trends in analytical chemistry : TRAC》2001,20(6-7):296-303
Trends in detection techniques for ion chromatographic separations of inorganic anions and cations are reviewed. Special attention is paid to conductivity, UV-vis absorbance, amperometric and potentiometric detection, mass spectrometry (MS) (including inductively coupled plasma MS and atmospheric pressure ionization MS) and post-separation reaction detection. The benefits and drawbacks of the different methods are discussed and examples are given for applications published within the last few years. 相似文献
128.
采用顶空液相微萃取与气相色谱联用技术测定雷尼替丁中二氯甲烷和三氯甲烷的残留量。自制了萃取液保护装置。考察了萃取溶剂的种类、萃取时间、萃取温度、萃取液的体积对二氯甲烷和三氯甲烷萃取效果的影响。以正十三烷为萃取剂,在60 ℃下萃取30 min,萃取液滴体积2 μL。二氯甲烷含量在1~10 μg/g范围内与色谱峰高呈线性关系,相关系数(r2)为0.9733;三氯甲烷含量在1~10 μg/g范围内与色谱峰高呈线性关系,r2为0.9724。二氯甲烷和三氯甲烷的最低检出限分别为0.0273 μg/g和0.0410 μg/g,加标回收率分别为93.6%~102%和98.1%~103%。方法简便易行,测定结果准确。 相似文献
129.
研究了基于G-N模型与三项延迟模型的热弹性波的传播特征.在各种广义热弹性理论中,热位移概念的引入使得G-N模型具有独特性质而引起广泛的关注和应用.基于G-N模型,最近一个三相延迟模型被提出.主要研究了这两种模型下第一和第二声波(耦合热弹性波)的色散和衰减特性,分析了温度场和位移场在两种模型下的振幅比和相位差.结果发现三... 相似文献
130.
针对通信设备故障发生随机性强,影响因素多,对应的故障诊断有高度非线性和不确定性的特点,采用BP神经网络算法,优化的GA-BP神经网络算法和POS-BP神经网络算法分别搭建基站设备故障诊断模型,提取设备故障历史数据进行MATLAB仿真,准确预测设备故障类型,帮助提高代维公司调度管理的智能化水平,提高基站设备运维的执行效率。仿真结果表明:本文的BP,GA-BP和POS-BP神经网络算法都能够实现设备故障类别的预测,且GA-BP神经网络算法相比BP和POS-BP神经网络算法对通信设备故障诊断有更好的适应性。 相似文献