Electronic states in mixed Cd1−xPbxF2 crystals

A parameterized tight binding model for the band structures of fluorite-type compounds is used in a CPA study of the electronic structure of substitutional non-isoelectronic alloys Cd_1−xPb_xF₂. The calculated densities of states are used to interpret the experimental UPS spectra and the peculiar concentration development of the absorption edge in these compounds.     

Electrical properties of antimony-doped p-type Hg0.78Cd0.22Te liquid-phase-epitaxy films

Hall measurements have been performed on antimony-doped p-type Hg_0.78Cd_0.22Te LPE (Liquid-Phase-Epitaxy) films between 20 and 150 K. The ionization energy of isolated shallow acceptors was estimated to be about 11 meV. From the analysis of the Hall coefficient and the hole mobility data, we found that compensation in the films is not enough to explain the typically low hole mobility at low temperatures.     

Charge-transfer complexes of nitric oxide,tri or tetravalent halides and aromatic hydrocarbons

Complexes of nitric oxide, some aromatic hydrocarbons and the halides BF₃, BCl₃, AlCl₃, FeCl₃, SiCl₄, GeF₄, SnCl₄ and TiCl₄ have been identified and characterized by spectroscopic measurements.     

局域表面等离子体共振效应在光催化技术中的应用

表面等离子激元是物理效应在光催化技术应用中的典型代表之一,作为新型光场调控技术为光催化技术的发展开辟了新的方向和思路,能够从全新的角度解决光催化技术的发展瓶颈,在过去十年来得到了广泛的研究。局域表面等离子体共振效应能够通过调节纳米颗粒的组成、形貌和介质环境等因素调控光催化体系的光谱响应范围。除此之外还能够通过增强光散射、热电子注入、诱导产生强烈的局域电场、加热周围环境等方法来增加光催化剂的氧化-还原反应速度、物质传输以及极化光催化材料表面的吸附分子,从而进一步增强材料的光催化性能。将这些优势集成到光催化材料体系中,能够显著提高传统光催化材料的太阳能转换效率,这是一个非常值得关注的发展方向。本文综述了局域表面等离子体共振效应在光催化技术中应用的基本原理、调控规律和应用等方面的研究进展,着重讨论了热电子的产生和迁移过程,贵金属中带间跃迁和表面等离子体共振效应的制约关系。最后,总结了表面等离子体光催化剂所面临的问题和挑战,并进行了相应的研究展望。     

点态化Fuzzy幂群的转移定理

从F uz zy点的角度来研究F uz zy幂群,建立F uz zy幂群的转移定理,然后通过转移定理将分明幂群的许多概念和结论直接转到F uz zy幂群,揭示了F uz zy幂群与分明幂群的关系。     

水蒸气活化制备烟杆基颗粒活性炭的研究

以烟杆废弃物为原料,以木焦油为主的复合粘结剂,通过水蒸气活化制备了烟杆基颗粒活性炭.对影响颗粒活性炭吸附性能和收率的因素如活化温度、活化时间、水蒸气流量进行了系统研究,得到了最佳工艺条件:活化温度为900℃,活化时间为60 min,水蒸气流量为3.31 g/min.该工艺条件下,烟杆基颗粒活性炭对碘的吸附值为1028 mg/g,对亚甲基蓝的吸附值为285 mg/g,收率为24.39%.同时,测定了该活性炭氮吸附,通过BET计算了活性炭的比表面积,并通过密度函数理论(DFT)表征了活性炭的孔结构.结果表明,该活性炭为微孔型,BET比表面积为1073 m2/g,总孔容为0.8152 ml/g.     

The bifurcation and exact travelling wave solutions of (1+2)-dimensional nonlinear Schrödinger equation with dual-power law nonlinearity

By using the method of dynamical systems, this paper researches the bifurcation and the exact traveling wave solutions for a (1+2)-dimensional nonlinear Schrödinger equation with dual-power law nonlinearity. Exact parametric representations of all wave solutions are given.     

Effect of inertial mass on a linear system driven by dichotomous noise and a periodic signal

A linear system driven by dichotomous noise and a periodic signal is investigated in the underdamped case. The exact expressions of output signal amplitude and signal-to-noise ratio (SNR) of the system are derived. By means of numerical calculation, the results indicate that (i) at some fixed noise intensities, the output signal amplitude with inertial mass exhibits the structure of a single peak and single valley, or even two peaks if the dichotomous noise is asymmetric; (ii) in the case of asymmetric dichotomous noise, the inertial mass can cause non-monotonic behaviour of the output signal amplitude with respect to noise intensity; (iii) the curve of SNR versus inertial mass displays a maximum in the case of asymmetric dichotomous noise, i.e., a resonance-like phenomenon, while it decreases monotonically in the case of symmetric dichotomous noise; (iv) if the noise is symmetric, the inertial mass can induce stochastic resonance in the system.     

露天煤矿的台阶高度对抛掷率的影响

以黑岱沟露天煤矿为例,在理论分析和现场实验的基础上,探讨台阶高度对抛掷爆破效果的影响。 现场实验结果表明:爆堆最远抛距和抛掷率随台阶高度的增加而增大,爆堆形态也变得更平滑;随台阶高度 的进一步增加,抛掷率增大的幅度逐渐减小。当炸药单耗q=0.70kg/m3,台阶高度H 37m 时,随台阶高 度的增大,抛掷率的提高不明显,甚至是停留在47%左右,此时单靠提高台阶高度来获取较高抛掷率的方法 将受采场条件和钻采机械设备的限制。     

含磷杯芳烃及其配合物的合成与应用

含磷杯芳烃作为一类特殊杯芳烃主体分子,可以通过不同的方式与众多的客体分子作用,形成主体-客体配合物。无论是母体含磷杯芳烃或其配合物都在分子识别、自组装、生物酶模拟、药物设计、化学传感器和金属催化剂的开发等方面显示出广阔的应用潜力。本文综述了近十年来含磷杯芳烃及其配合物的研究进展。对一些新型含磷杯芳烃及其配合物的合成方法与应用作了重点介绍,并展望了研究和发展方向。