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151.
152.
A formal synthesis of semiaquilegin A is achieved starting from readily available oridonin in 19 linear steps. The absolute configuration of the natural product has been established. A variety of useful analogues were prepared through this synthetic route. 相似文献
153.
《Communications in Nonlinear Science & Numerical Simulation》2011,16(12):4596-4601
This paper studies the dynamics of a system composed of a collection of particles that exhibit collisions between them. Several entropy measures and different impact conditions of the particles are tested. The results reveal a Power Law evolution both of the system energy and the entropy measures, typical in systems having fractional dynamics. 相似文献
154.
The reaction of vicinal diimines and acyl chlorides in the presence of triethylamine produces 3-imino-β-lactams and/or bis-β-lactams chemo-, regio-, and stereoselectively, which are important intermediates in pharmaceutical and organic synthesis. The selectivities in the reaction have been investigated. The results indicate that all diimines react with various ketenes generated from acyl chlorides in the presence of triethylamine to give rise to cis-4-imino-β-lactams (mono-cis-β-lactams) diastereoselectively due to the electron-withdrawing property of the imino group in the vicinal diimines. Bis-β-lactams were obtained from diimines via the mono-cis-β-lactams as intermediates. Only ketenes with strong electron-donating substituents can react with the mono-cis-β-lactams to yield bis-β-lactams, affording a pair of C2-symmetric cis-bis-β-lactams with symmetric diimines, two or four pairs of diastereomeric bis-β-lactams with ketoaldehyde-derived unsymmetric diimines depending on the steric hindrance of their N-substituents. The current investigation provides very important information for the selective preparation of mono- and bis-β-lactams from vicinal diimines. 相似文献
155.
Polymer concretes represent challenging materials in the Civil Engineering field, with them being characterized by a high value of the compressive strength and ultimate compressive strain, as well as by a good chemical resistance when compared to that of traditional concretes. These innovative materials exhibit a limited value of the strength in tension and therefore need to be reinforced with either steel or FRP pultruded internal bars. Moreover, their structural performance is strongly affected by the rheological behavior of the resin as well as the internal bars, if made of FRP. In this paper, a mechanical model capable of analytically evaluating the long term behavior of reinforced polymer concrete beams is presented, which accounts for the linear viscoelastic behavior of the constituent materials. 相似文献
156.
《Electrochemistry communications》2007,9(4):596-598
Hard carbon spherule (HCS) has been investigated as a counter electrode for dye-sensitized solar cells. The overall conversion efficiency of the cell reached 5.7%, which is comparable to 6.5% of the counter electrode of platinum-sputtered fluorine-doped tin oxide used in Grätzel-type solar cells under the same experimental condition. It is found that the photovoltaic performance was strongly affected by the specific surface areas of the carbon materials. 相似文献
157.
《Nuclear Physics B》2005,729(3):317-360
By electron or hole doping quantum antiferromagnets may turn into high-temperature superconductors. The low-energy dynamics of antiferromagnets are governed by their Nambu–Goldstone bosons—the magnons—and are described by an effective field theory analogous to chiral perturbation theory for the pions in strong interaction physics. In analogy to baryon chiral perturbation theory—the effective theory for pions and nucleons—we construct a systematic low-energy effective theory for magnons and electrons or holes in an antiferromagnet. The effective theory is universal and makes model-independent predictions for the entire class of antiferromagnetic cuprates. We present a detailed analysis of the symmetries of the Hubbard model and discuss how these symmetries manifest themselves in the effective theory. A complete set of linearly independent leading contributions to the effective action is constructed. The coupling to external electromagnetic fields is also investigated. 相似文献
158.
《Solid State Ionics》2006,177(1-2):149-157
The synthesis and performance of (La0.75Sr0.25)(Cr0.5Mn0.5)O3/Y2O3–ZrO2 (LSCM/YSZ) composites are investigated as alternative anodes for the direct utilization of methane (i.e., natural gas) in solid oxide fuel cells. Addition of YSZ phase greatly improves the adhesion and reduces the electrode polarization resistance of the LSCM/YSZ composite anodes. LSCM/YSZ composite anodes show reasonably good performance for the methane oxidation reaction in wet CH4 and the best electrode performance was achieved for the composite with LSCM contents of 50–60 wt.% with polarization resistances of 2–3 Ω cm2 in 97% CH4/3% H2O at 850 °C. The electrode impedance for the methane oxidation in wet CH4 on the LSCM/YSZ composite anodes was characterized by three separable arcs and the electrode behavior could be explained based on the ALS model for the reaction on the MIEC electrode. The results indicate that electrocatalytic activity of the LSCM/YSZ composite anodes for the methane oxidation is likely limited by the oxygen vacancy diffusion in the substituted lanthanum chromite-based materials. 相似文献
159.
Ultrasonic-assisted treatment is an eco-friendly and cost-effective emulsification method, and the acoustic cavitation effect produced by ultrasonic equipment is conducive to the formation of stable emulsion. However, its effect on the underlying stability of low-molecular-weight oyster peptides (LOPs) functional-nutrition W1/O/W2 double emulsion has not been reported. The effects of different ultrasonic power (50, 75, 100, 125, and 150 W) on the stability of double emulsions and the ability to mask the fishy odor of LOPs were investigated. Low ultrasonic power (50 W and 75 W) treatment failed to form a well-stabilized double emulsion, and excessive ultrasound treatment (150 W) destroyed its structure. At an ultrasonic power of 125 W, smaller particle-sized double emulsion was formed with more uniform distribution, more whiteness, and a lower viscosity coefficient. Meanwhile, the cavitation effect generated by 125 W ultrasonic power improved storage, and oxidative stabilities, emulsifying properties of double emulsion by reducing the droplet size and improved sensorial acceptability by masking the undesirable flavor of LOPs. The structure of the double emulsion was further confirmed by optical microscopy and confocal laser scanning microscopy. The ultrasonic-assisted treatment is of potential value for the industrial application of double emulsion in functional-nutrition foods. 相似文献
160.
《International Journal of Multiphase Flow》2005,31(10-11):1181-1197
The air bubble rise velocity in still water depends mainly on the bubble size and is basically influenced by buoyancy, viscosity and surface tension. In high-speed flows the number of forces acting on air bubbles increases with turbulence, non-hydrostatic pressure gradient, shear forces, bubble clouds and free-surface entrainment. Air bubbles in these flows are used for cavitation protection of hydraulic structures such as chutes, spillways and bottom outlets. Here, air is normally added by means of aerators upstream of regions where the cavitation number falls below a critical value mainly to reduce the sonic velocity of the fluid and cushion the cavitation bubble collapse process. The distance between successive aerators depends basically on the bubble rise velocity. Until today, the bubble rise velocity in high-speed flows was not thoroughly investigated because of limited laboratory instrumentation. The present project focused on the streamwise development of air concentrations in high-speed flows along a 14 m long model chute. The bubble rise velocity was indirectly derived from the air detrainment gradient of the air concentration contour lines downstream of an aeration device. It accounts for the main hydraulic parameters chute slope, Froude number and air concentration. It is demonstrated that the bubble rise velocity in high-speed flow and stagnant water differ significantly due to fracturing processes, turbulence, and the ambient air concentration. 相似文献