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101.
102.
Kai Cai Yu-Ping Zhang Pinaki S. Bhadury Bin Liu De-Yu Hu Weiming Xu 《Chromatographia》2010,72(9-10):933-939
A reliable and sensitive method for determination of MCPA in soil by derivatization through p-toluenesulfonic acid and 1,3-dichloro-2-propanol followed by gas chromatographic detection under ECD mode has been established. After treatment with hydrochloric acid, the soil samples were directly extracted without any clean-up with dichloromethane by vortexing. After derivatization and liquid–liquid extraction, the product was subjected to GC analysis. Under optimized conditions, recovery of MCPA reached 87–91%; intra- and inter-day precision values were recorded in the range 3.4–6.4% and 7.4–8.7%, respectively. Excellent linear relationship was observed within 0.1–10 μg mL?1 (0.005–0.5 mg kg?1) with linear correlation coefficient (R) of 0.9997. The LOD and LOQ were 0.001 and 0.0026 mg kg?1, respectively, and the overall sensitivity for detection was found to be in the same range as with the conventional GC-MS technique. 相似文献
103.
The slightly water-soluble anticancer drug camptothecin (CPT) and its inclusion complexes with cucurbit[n = 7, 8]uril (Q[n] (n = 7, 8)) were investigated. The formation of 1:2 complexes with Q[n] (n = 7, 8) in aqueous solution was confirmed by fluorescence spectroscopy and the apparent stability constants were determined to be higher than 3.01 × 1012 L2/mol2. The solid inclusion complexes of CPT and Q[n] (n = 7, 8) were also prepared by the co-evaporation method and characterized by Fourier transformation-infrared spectroscopy, differential scanning calorimetry and powder X-ray diffraction. Aqueous solubility and dissolution studies indicate that the complexes exhibited significantly increased dissolution rates compared with the pure drug and physical mixtures. The potential of Q[7] or Q[8] for stabilizing lactone modality of CPT was investigated by the High Performance Liquid Chromatography (HPLC) method. The results reveal more than 63% CPT lactone form (active form) in CPT-Q[7] or Q[8] complexes compared to only 36% CPT lactone form in the absence of Q[7] or Q[8] after being incubated in the phosphate buffer solution (pH 7.4 at 37°C) for 5 h. 相似文献
104.
考虑具有导子的李三系.由李三系和一个导子称为LietsDer对.定义系数在表示中的LietsDer对的上同调理论.研究LietsDer对的中心扩张.接下来,将形变理论推广到由李三系和导子构成LietsDer对上,它由带有系数的LietsDer对的上同调所支配. 相似文献
105.
利用G3和CBS-QB3的理论方法研究CF3OH分子裂解成FCFO和HF,并考虑大气中双分子和氨气对CF3OH分子裂解的催化作用. 理论计算表明:由于在G3的理论水平下,计算的能垒为188.52 kJ/mol,所以CF3OH分子在大气条件下不可能发生单分子裂解;当氨气和双分子水被加入时,能垒都被降到25.08 kJ/mol,起了强的催化作用. 除此之外,应用过渡态理论对速率常数进行了计算,计算结果表明:氨气催化CF3OH分子的速率常数是单分子和双分子催化CF3OH分子裂解速率常数的109和105倍. 考虑到大气中这些物质的浓度,计算结果预测了氨气催化CF3OH分子裂解在大气中起到重要的作用. 相似文献
106.
This paper carries out first principles calculation of the structure,electronic and optical properties of Be x Zn 1 x O alloys based on the density-functional theory for the compositions x = 0.0,0.25,0.5,0.75,1.0.The lattice constants deviations of alloys obey Vegard’s law well.The Be x Zn 1 x O alloys have the direct band gap(Γ-Γ) character,and the bowing coefficients are less than the available theoretical values.Moreover,it investigates in detail the optical properties(dielectric functions,absorption spectrum and refractive index) of these ternary mixed crystals.The obtained results agree well with the available theoretical and experimental values. 相似文献
107.
合成了一种席夫碱结构的罗丹明B衍生物.研究表明,该衍生物能与Fe3+形成稳定配合物,同时伴随显著的荧光增敏和吸收增强.衍生物不仅对Fe3+呈现良好的荧光及比色探针性能,其与金属离子形成的配合物也是一种研究牛血清白蛋白的高灵敏荧光探钊. 相似文献
108.
利用硫杂杯[4]芳烃衍生物与罗丹明乙二胺发生酰化反应,合成了2个具有双罗丹明基团的1,3-硫杂杯[4]罗丹明乙二胺酰胺衍生物.在实验条件下,衍生物与Fe3+均能形成1:1配合物,配合物的形成诱导了衍生物分子中罗丹明基螺环开环,而表现出良好的荧光和比色探针性能.1,3-硫杂杯[4]罗丹明酰胺-2,4-酯对Fe3+的选择性... 相似文献
109.
110.
《Communications in Nonlinear Science & Numerical Simulation》2014,19(6):2060-2070
The parameter space of the two dimensional Rulkov chaotic neuron model is taken into account by using the qualitative analysis, the co-dimension 2 bifurcation, the center manifold theorem, and the normal form. The goal is intended to clarify analytically different dynamics and firing regimes of a single neuron in a two dimensional parameter space. Our research demonstrates the origin that there exist very rich nonlinear dynamics and complex biological firing regimes lies in different domains and their boundary curves in the two dimensional parameter plane. We present the parameter domains of fixed points, the saddle-node bifurcation, the supercritical/subcritical Neimark–Sacker bifurcation, stability conditions of non hyperbolic fixed points and quasiperiodic solutions. Based on these parameter domains, it is easy to know that the Rulkov chaotic neuron model can produce what kinds of firing regimes as well as their transition mechanisms. These results are very useful for building-up a large-scale neuron network with different biological functional roles and cognitive activities, especially in establishing some specific neuron network models of neurological diseases. 相似文献