Controllable cross-Kerr interaction between microwave photons in circuit quantum electrodynamics

We propose a scheme to enable a controllable cross-Kerr interaction between microwave photons in a circuit quantum electrodynamics(QED) system.In this scheme we use two transmission-line resonators(TLRs) and one superconducting quantum interference device(SQUID) type charge qubit,which acts as an artificial atom.It is shown that in the dispersive regime of the circuit-QED system,a controllable cross-Kerr interaction can be obtained by properly preparing the initial state of the qubit,and a large cross-phase shift between two microwave fields in the two TLRs can then be reached.Based on this cross-Kerr interaction,we show how to create a macroscopic entangled state between the two TLRs.     

Photocatalytic hydrogen generation of Pt-Sr(Zr1 − x Y x )O3 − δ -TiO2 heterojunction under the irradiation of simulated sunlight

The Pt-Sr(Zr_{1 − x} Y _x )O_{3 − δ} -TiO₂(Pt-SZYT) heterojunction photocatalysts were prepared by a photodeposition method. The composite particles were characterized by XRD, SEM, UV-Vis DRS, and PL techniques. Photocatalytic hydrogen generation in H₂C₂O₄ aqueous solution under the irradiation of simulated sunlight was used as a probe reaction to evaluate the photocatalytic activity of the photocatalysts. The effects of the content of Pt loading and the concentration of oxalic acid on the photocatalytic activity of the catalyst were discussed. The continuous photocatalytic activity of the Pt-SZYT and the relationship between PL intensity and hydrogen generation were also discussed. The results show that Pt-SZYT catalysts had high photocatalytic activity of hydrogen generation. The content of Pt loading and the concentration of oxalic acid have important influence on the photocatalytic hydrogen generation. The optimal loading content of platinum was 0.90 mass%. Under this condition, the average rate of photocatalytic hydrogen generation was 1.68 mmol·h⁻¹ when the concentration of oxalic acid was 50 mmol·L⁻¹. The higher the photocatalytic activity, the weaker the PL intensity, which was demonstrated by the analysis of PL spectra. __________ Translated from Acta Chimica Sinica, 2008, 61 (in Chinese)     

用光的干涉和衍射测量金属的线胀系数

在光的干涉实验中只要测出干涉条纹随金属温度变化的个数,进而求出金属长度随温度的变化量,在光的衍射实验中则利用衍射条纹的间距与缝宽之间的关系,通过测量衍射条纹的间距求出温度变化时待测金属的长度变化量,从而计算出待测金属的线胀系数。     

光调制法测量光速的研究

采用光调制法测量光速,直接对光进行调制得到调幅波,采用差频技术测量高频信号的相差,根据相位变化测量波长,得出光速并分析了误差。提出了改进方法,明显减小了实验误差。     

大学物理实验教学创新改革研究

本文介绍了湖南理工学院大学物理实验室在大学物理实验教学中对实验体系、实验内容、实验方法、实验手段及实验考核等方面进行的创新性改革研究及其成果。     

植物油酸新戊二醇对苯二甲酸复合酯的合成及性能

用新戊二醇(NPG)和对苯二甲酰氯(TPA)反应生成“低聚物”中间体,当n(NPG)/n(TPA)由2.4增加至3.0时,中间体的聚合度(m)在3.5~1.45之间,收率75.5%。再将中间体与油酸、菜籽油酸进行酯化得到复合酯,收率88.5%。结果表明,复合酯的粘度随着分子量的增大而增大,粘度指数大于125,凝点低于－27℃,氧化稳定性随分子量的增大而提高,生物降解率＞70%,最大无卡咬负荷(PB)为784N,磨斑直径0.41mm,热分解温度＞250 ℃,因此植物油酸新戊二醇对苯二甲酸复合酯是性能良好的绿色润滑剂。     

基于手性配体交换反应立体选择性萃取分离氧氟沙星对映体

基于配体交换反应,研究了氧氟沙星对映体在含有Cu²⁺和N-n-十二烷基-L-脯氨酸手性配体(L)两相体系中的分配平衡.在不同pH条件下,考察了Cu²⁺在含有N-n-十二烷基-L-脯氨酸两相中的分布;研究了pH,Cu²⁺浓度,手性配体浓度等因素对氧氟沙星对映体在两相中的分配系数(K)和分离因子(α)的影响.实验结果表明,N-n-十二烷基-L-脯氨酸对R-氧氟沙星对映体萃取能力大于对S-对映体的萃取能力;pH对K和α的影响很大,在pH值小于3.5时,L₂Cu二元配合物的生成在热力学上看是不适宜的,萃取时pH宜大于3.5;手性配体和Cu²⁺摩尔比为2:1,K和α最佳;使用2×1中空纤维膜对氧氟沙星对映体进行萃取分离,出口水相氧氟沙星对映体浓度比值(S/R)约为1.72.     

马氏环境中可数马氏链的Poisson极限率

研究了马氏环境中的可数马氏链,主要证明了过程于小柱集上的回返次数是渐近地服从Poisson分布。为此,引入熵函数h,首先给出了马氏环境中马氏链的Shannon-Mc Millan-Breiman定理,还给出了一个非马氏过程Posson逼近的例子。当环境过程退化为一常数序列时,便得到可数马氏链的Poisson极限定理。这是有限马氏链Pitskel相应结果的拓广。     

对叔丁基杯[8]芳烃醚类衍生物的合成

以对叔丁基苯酚和甲醛为原料,在碱催化下,采用一步法合成了对叔丁基杯[8]芳烃(1)。对1的下缘酚羟基改性,用碘甲烷、碘乙烷、正溴丙烷、正溴丁烷为烷基化试剂,在氢化钠作用下,制备了一系列全O-烷基化的杯[8]芳烃醚衍生物,其结构经1HNMR和IR表征。