12 W高功率高可靠性915 nm半导体激光器设计与制作

本文设计并制作了一种高效率、高可靠性的915 nm半导体激光器。半导体激光器是光纤激光器的关键部件,为了最大限度地提高器件的电光转换效率,在设计上采用双非对称大光腔波导结构,同时对量子阱结构、波导结构、掺杂以及器件结构进行了系统优化。器件模拟表明,在25℃环境温度下,器件的最高电光转换效率达到67%。采用金属有机气相沉积(MOCVD)法进行材料生长,随后制备了发光区域宽度为95μm、腔长为4.8 mm的激光芯片。测试表明,封装后器件的效率以及其它参数指标达到国际先进水平,在室温下阈值电流为1 A,斜率效率为1.18 W/A,最高电光转换效率达66.5%,输出功率12 W时,电光转换效率达到64.3%,测试结果与器件理论模拟高度吻合。经过约6 000 h的寿命加速测试,器件功率没有出现衰减,表明制作的高功率915 nm激光芯片具有很高的可靠性。     

官能团及修饰位点对金属有机骨架化合物（MOFs）CO2/CH4分离性能的影响：蒙特卡洛模拟研究

In order to explore the in uence of modification sites of functional groups on landfill gas (CO₂/CH₄) separation performance of metal-organic frameworks (MOFs), six types of organic linkers and three types of functional groups (i.e. -F, -NH₂, -CH₃) were used to construct 36 MOFs of pcu topology based on copper paddlewheel. Grand canonical Monte Carlo simulations were performed in this work to evaluate the separation performance of MOFs at low (vacuum swing adsorption) and high (pressure swing adsorption) pressures, respectively. Simulation results demonstrated that CO₂ working capacity of the unfunctionalized MOFs generally exhibits pore-size dependence at 1 bar, which increases with the decrease in pore sizes. It was also found that -NH₂ functionalized MOFs exhibit the highest CO₂ uptake due to the enhanced Coulombic interactions between the polar -NH₂ groups and the quadrupole moment of CO₂ molecules, which is followed by -CH₃ and -F functionalized ones. Moreover, positioning the functional groups -NH₂ and -CH₃ at sites far from the metal node (site b) exhibits more significant enhancement on CO₂/CH₄ separation performance compared to that adjacent to the metal node (site a).