带约束拉杆L形钢管混凝土短柱的偏压试验研究

对8个带约束拉杆L形钢管混凝土偏压短柱试件进行了试验研究,讨论其在不同约束拉杆设置、偏心率以及荷载角下的偏压性能.结果表明,约束拉杆的设置改变了钢管的屈曲模态,延迟了局部屈曲的发生,有助于L形钢管混凝土偏压短柱的承载力和延性的提高.在加载后期,处于加载肢的拉杆比处于非加载肢的拉杆对核心混凝土的约束作用明显,其中双列拉杆试件的肢端拉杆比肢内拉杆的约束作用更大.临近或达到极限承载力后,近力侧钢管壁对核心混凝土的约束作用较明显.利用纤维模型法计算的试件偏压极限承载力结果与试验结果吻合良好.     

Improved area-difference-based recovery information placement

<正> In mobile computing systems,message logging can be used to provide fault tolerance for mobilehosts.Due to the mobility of mobile hosts,their recovery information,including logged messages andcheckpoints,may spread throughout mobile support stations.During recovery,there will be a considerablecost for the collection of recovery information.To speed up recovery and to reduce the failure-freeoverhead,an improved area-difference-based scheme is proposed.It tries to keep recovery informationevenly spreading over an area.Only part of recovery information needs to be migrated for controlling thedistribution of recovery information.To reduce the migration cost,a light-weight migration is also proposed.In the performance study,we give an analysis of the probability that the light-weight migrationtakes place.     

基于柱形容器缠绕特性的控制稳定性分析

针对玻璃纤维缠绕机在工作中由于张力不稳定导致的线型变化,以及在高速缠绕模式下的张力调节不稳定的问题,设计了自适应模糊PID控制策略以及适用于高速缠绕工况的滑模控制策略。首先,针对缠绕工况建立缠绕动力学模型、张力控制模型;其次,引入模糊PID控制策略和滑模控制策略分别对不同工况下的缠绕特性进行MATLAB-Simulink仿真,寻找最优控制策略;最后,基于被验证的最优控制策略进行实验。结果表明,在模糊PID控制的调节下,不同速度变化下的缠绕张力相对于无控制得到较好改善,提高了柱形容器在缠绕时的线性稳定性和张力稳定性。模糊PID控制对缠绕时的张力调节精度优于滑模控制,为大型管道缠绕设备提供了新的研究思路。     

Synthesis of oxazole and furan derivatives via Rh2(OAc)4-catalyzed C≡X bond insertion of cyclic 2-diazo-1,3-diketones with nitriles and arylacetylenes

Abstract

A convenient and efficient procedure for the synthesis of 2-substituted-6,7-dihydrobenzo[d]oxazol-4(5H)-ones and 2-aryl-6,7-dihydrobenzofuran-4(5H)-ones through a Rh₂(OAc)₄-catalyzed C≡X (X?=?N, C) insertion of cyclic 2-diazo-1,3-diketones with nitriles and aromatic alkynes has been developed. This reaction uses readily available starting materials and stable cyclic 2-diazo-1,3-diketone compounds, with desired products formed in good to high yields. A tentative mechanism involving a C≡X bond insertion and 1,5-dipolar electrocyclization/ring opening and cyclization sequence for this reaction is proposed.     

Bifurcations and dynamics of a plant disease system under non-smooth control strategy

Nonlinear Dynamics - Mathematical models and analyses can assist in designing the control strategies to prevent the spread of infectious disease. The present paper investigates the bifurcations and...     

层状四水硫酸锆催化合成乙二醇单乙醚醋酸酯反应机理的理论研究

采用以量子化学ASED－MO（含原子对排斥的EHMO法）为基础的结构自动优化EHTOPT法,研究了层状四水硫酸锆催化合成乙二醇乙醚醋酸酯的反应机理;构筑了反应组分乙二醇单乙醚羟基上的氢原子通过氢 键与层状四水硫酸锆结晶水上的氧原子结合。同时,还研究了醋酸在四水硫酸锆表面形成正碳离子的结合状态,提出了相应的酯化反应机理,在此基础上推导出的动力学方程与实验结果相符。     

反式乙烯基联吡啶表面增强拉曼光谱的密度泛函理论研究

反式乙烯基联吡啶具有极好的拉曼散射信号,经常用做探针分子.利用密度泛函理论(DFT)理论,采用BP86,BPw91和B3LYP等方法,Ag原子使用赝式基组,H,C,N等原子使用6-31+ +G(d,p)基组,计算了反式乙烯基联吡啶与银配合物(t-BPE-Ag)的Raman光谱,并且利用势能分布(PED)计算结果对t-BPE分子Raman光谱和SERS谱进行了详细的归属,DFT理论得到结果说明根据DFT理论计算t-BPE-Ag配合物得到的Raman光谱与实验SERS谱基本一致,并且键连Ag原子越多,与实验值会更接近,t-BPE-Ag配合物HOMO与LUMO的能级差估计在449～912 nm范围内.     

半导体激光泵浦亚稳态氩气激光器实现激光振荡

采用基于体布拉格光栅的窄线宽半导体激光器作为泵浦源,以电容耦合式射频激励Ar, He混合气体放电等离子体为增益介质,在双程纵向泵浦的结构下实现了连续波模式的912 nm的激光输出。     

Frobenius manifolds and Frobenius algebra-valued integrable systems

The notion of integrability will often extend from systems with scalar-valued fields to systems with algebra-valued fields. In such extensions the properties of, and structures on, the algebra play a central role in ensuring integrability is preserved. In this paper, a new theory of Frobenius algebra-valued integrable systems is developed. This is achieved for systems derived from Frobenius manifolds by utilizing the theory of tensor products for such manifolds, as developed by Kaufmann (Int Math Res Not 19:929–952, 1996), Kontsevich and Manin (Inv Math 124: 313–339, 1996). By specializing this construction, using a fixed Frobenius algebra \({\mathcal {A}},\) one can arrive at such a theory. More generally, one can apply the same idea to construct an \({\mathcal {A}}\)-valued topological quantum field theory. The Hamiltonian properties of two classes of integrable evolution equations are then studied: dispersionless and dispersive evolution equations. Application of these ideas are discussed, and as an example, an \({\mathcal {A}}\)-valued modified Camassa–Holm equation is constructed.