Amphiphilic H‐shaped block copolymers (PTMSPMA)2PEG(PTMSPMA)2 with 91 ethylene glycol (EG) units and four PTMSPMA chains have been synthesized by atom transfer radical polymerization of trimethoxylsilylpropyl methacrylate (TMSPMA) at room temperature in methanol. The structure, molecular weight, and molecular weight distribution have been characterized by 1H NMR spectroscopy and GPC traces. These H‐shaped block copolymers can self‐assemble in DMF/water, and multiple vesicle aggregates from large‐compound vesicles, to multilayer vesicles and unilamillar vesicles are formed. These morphologies can be simply controlled by variation of the chain length ratios.
The interchain contraction and association of polystyrene in semidilute solution near the Θ temperature are studies using NET. The results reveal that during a drop of temperature, polystyrene chains pass through different states: a smooth change of conformation at temperatures above the Θ temperature, an accelerated contraction and association, aggregation of polymer chains, and then further continuous contraction below the Θ temperature. A pronounced hysteresis is observed during repeated heating. A viscosity study of the same solution was compared with the NET results. It indicates that NET can effectively be used to study conformational changes like contraction and association of polymer chains in a semidilute solution.
In four-dimensional Einstein-Gauss-Bonnet(EGB)gravity,we consider the thermodynamic and phase transitions of(charged)AdS black holes.For the negative GB coefficientα<0.the system allows two physical critical points,corresponding to the reentrant phase transition.when the charge Q>2√-α.For arbitraryα>0,the system always leads to a van der Waals phase transition.We then study the quasinormal modes(QNMs)of massless scalar perturbations to probe the van der Waals-like phase transition between small and large black holes(SBH/LBH)for(charged)AdS black holes.We find that the signature of this SBH/LBH phase transition in the isobaric process can be detected since the slopes of the QNM frequencies change dramatically in small and large black holes near the critical point.The obtained results further support that QNMs can be a dynamic probe of ther-modynamic properties in black holes. 相似文献
A novel water-soluble luminescent complex consisting of Eu(ally-dbm)\begin{document}$_3$\end{document}-2Tppo and poly(N-isopropyl acrylamide) (PNIPAM) is synthesized through a series of chemical reactions. The structure of the complex is characterized by TGA, GPC, HNMR, and the thermal-responsive fluorescence of the complex in aqueous solution is investigated. It is found that PNIPAM collapse above the lower critical solution temperature causes the coordination bond breaking, leading to weakening of the fluorescence from Eu\begin{document}$^{3+}$\end{document} and enhancing of the fluorescence from the ligands. When temperature decreases, the fluorescence from Eu\begin{document}$^{3+}$\end{document} is found to boost up and the fluorescence from ligands weakens accordingly. It is deduced from this phenomenon that the ligands re-coordinate with europium ions again along with the temperature decreasing, which is further confirmed by IR measurements. This thermal-responsive fluorescence is of reversibility, which can be used as molecular probes for biological imaging and collapse studying of PNIPAM. 相似文献
Nonlinear Dynamics - In this paper, the numerical solution of time-fractional convection diffusion equations (TF-CDEs) is considered as a generalization of classical ones, nonexponential relaxation... 相似文献
A feed-forward Common-Mode(CM) charge control circuit for a high-speed Charge-Domain(CD)pipelined Analog-to-Digital Converter(ADC) is presented herein.This study aims at solving the problem whereby the precision of CD pipelined ADCs is restricted by the variation in input CM charge,which can compensate for CM charge errors caused by a variation in CM charge input in real time.Based on the feed-forward CM charge control circuit,a 12-bit 250-MS/s CD pipelined ADC is designed and realized using a 1 P6 M 0.18-μm CMOS process.The ADC achieved a Spurious Free Dynamic Range(SFDR) of 78.1 d B and a Signal-to-Noise-and-Distortion Ratio(SNDR) of 64.6 d B for a 20.1-MHz input:a SFDR of 74.9 d B and SNDR of 62.0 d B were achieved for a 239.9-MHz input at full sampling rate.The variation in signal-to-noise ratio was less than 3 d B over a 0–1.2 V input CM voltage range.The power consumption of the prototype ADC is only 85 m W at 1.8 V supply,and it occupies an active die area of 2.24 mm~2. 相似文献