2,2’—二硫代双(4,6—二叔丁基苯酚)的晶体和分子结构

一种塑解剂经高压液体色谱分离制备出主要成份2,2′—二硫代双(4,6二叔丁基苯酚)。由质谱分析得到分子量为474化学式为C_(28)H_(2)O_2S_2、晶体呈现孪生。基体单晶属三斜晶系,空间群为(?)PI(NO.2),晶体结构用直接法解出,=0.07。研究结果表明该分子是二硫代酚类化合物。在EI场中,S—S键断裂是主要断裂过程。晶体中,分子的一个环上的羟基是无序分布的。羟基与最邻近的硫原子形成氢键。     

Approximation of signals from local averages

This work is concerned with approximation of a signal from local averages. It improves a result of Butzer and Lei [P.L. Butzer, J. Lei, Approximation of signals using measured sampled values and error analysis, Commun. Appl. Anal. 4 (2000) 245–255].     

Fabrication of magnetic composite nanofibers of poly(ε-caprolactone) with FePt nanoparticles by coaxial electrospinning

In this article, composite nanofibers of poly(ε-caprolactone) (PCL) with iron–platinum (FePt) nanoparticles were successfully fabricated via coaxial electrospinning. The structure and morphology of FePt/PCL composite nanofibers were observed using transmission electron microscope and scanning electron microscope, respectively. The magnetic behavior of FePt/PCL composite nanofibers was investigated by alternating gradient magnetometer at room temperature.     

Nanoparticle composites: FePt with wide-band-gap semiconductor

We present a simple way to synthesize FePt and ZnO (wide-band-gap semiconductor) nanoparticle composites. The FePt nanoparticles were fabricated using the method reported by Sun et al. By controlling the heating rate, 3 nm FePt nanoparticles were synthesized. Well-dispersed FePt and ZnO nanoparticle composites were prepared by further adding zinc acetate and oleyl amine into the 3 nm FePt nanoparticle dispersion. By controlling the molar ratio of the FePt and zinc acetate, FePt and ZnO nanoparticle composites with different FePt particle fractions were obtained. The intensity of photo luminescence spectra of the nanoparticle composites increases very much with decreasing FePt particle fraction, whereas the peak position shifts a little. After annealing at 550 °C for half an hour, the nanoparticle composites become magnetically hard or semi-hard with coercivity much dependent on the FePt particle volume fraction. The coercivity of the composites increases with annealing temperature. The composites hold the promise of applications in new generation recording and/or optical devices.     

Evaluation of gap length fluctuation with harmonic analysis method

Gap length (GL) of reading head is one of the most critical parameters for high-density magnetic recording systems. A novel method is proposed for quantitative evaluation of the GL fluctuation among a batch of magneto-resistive/giant magneto-resistive heads with same structure design. The method works at head-gimbal assembly level and the evaluation can be done with any read/write analysis equipment. The testing process is based on harmonic analysis of the readback signal. The testing system consists of a selected reference head and sample heads for evaluation. A GL variation function is introduced for the evaluation of GL deviation between the reference head and sample head. This method proved to be easy for implementation and results suggest that variation of GL is considerable and has obvious effect on recording performance in high recording density systems.     

一类非定常对流占优扩散问题差分-流线扩散法的后处理

讨论了一类非定常对流占优扩散方程的差分-流线扩散格式(FDSD),利用插值后处理技术,提高了特殊网格下该FDSD格式在双线性元空间的精度,从而按L∞(L2(Ω) 模达到最优．     

LD端抽运平直腔Nd:YVO4固态激光器的输出功率特性研究

对LD端抽运平直腔Nd:YVO₄固态激光器输出功率特性受激光器内在诸因素(热透镜效应、腔长、激活孔径等)的制约关系进行了研究.并用传播圆-变换圆图解分析方法给出了合理的解释，同时，对进一步提高其输出功率特性指出了方向. 关键词： 固体激光器 热透镜 变换圆 平直腔     

设备诊断专家系统的层次诊断模型

本文在讨论复杂机电系统故障特征之后,提出了诊断专家系统的层次诊断模型.该模型以对象系统的结构分级为基础,使用作者提出的征兆分析法、功能分析法和综合信号分析法等三种具体诊断方法,得到了分层适应诊断的层次诊断模型.最后介绍了以层次诊断模型为基础的汽车发动机诊断专家系统的概况.     

Bending-torsion vibration of a partially submerged cylinder with an arbitrary cross-section

An analytical method is presented to investigate the bending-torsion vibration characteristics of a cylinder with an arbitrary cross-section and partially submerged in water. The compressibility and the free surface waves of the water are considered simultaneously in the analysis. The exact solution of structure–water interaction is obtained mathematically. Firstly, the analytical expression of the velocity potential of the water is derived by using the method of separation of variables. The unknown coefficients in the velocity potential are determined by the longitudinal and circumferential Fourier expansions along the outer surface of the cylinder and are expressed in the form of integral equations including the unknown dynamic bending deflection and torsional angle of the cylinder. Secondly, the force and torque acting on the cylinder per unit length, provided by the water, are obtained by integrating the water dynamic pressure along the circumference of the cylinder. The general solution of bending-torsion vibration of the cylinder under the water dynamic pressure is derived analytically. The integral equations included in the velocity potential of the water can be solved exactly. Finally, the eigenfrequency equation of cylinder–water interaction is obtained by means of the boundary conditions of the cylinder. Some numerical examples for elliptical columns partially submerged in water are provided to show the application of the present method.     

带有奇异项的临界增长p-Laplace方程的非平凡解

本文研究了一种带有奇异项的临界增长p-Laplace方程在N维空间中的有界集上非平凡解的问题,利用山路引理和集中紧性原理,得出方程在非线性项满足一定条件下有非平凡解的结果.