基于YOLOv5s-FCS的钢材表面缺陷检测

针对传统钢材表面缺陷检测方法易出现误检、漏检和部分缺陷种类检测精度低等问题,本文设计了一种钢材表面缺陷网络YOLOv5s-FCS。首先本文引用了FReLU激活函数构建了卷积模块CBF,有效增强了网络的空间解析能力,优化了网络检测精度;其次,本文将坐标注意力机制嵌入到网络的neck部分来增强网络特征融合的能力,从而使网络能够提取更加丰富的特征信息;最后,将YOLOv5s的损失函数替换为SIoU loss,提高了预测框的回归精度。通过在NEU-DET数据集上进行消融实验、可视化对比实验,结果表明,YOLOv5s-FCS网络的mAP值达到了0.747,相较于原YOLOv5s网络提高了8.3%,相较于YOLOv3网络提高了11.8%,相较于YOLOXs网络提高了4.2%,相较于YOLOv6s提高了1.4%,验证了该方法的可行性、有效性。     

一种面向在轨服务卫星地面应用系统的软件开发方法

为解决现有在轨服务卫星地面应用系统瀑布式软件开发模型灵活性差,难以适应用户需求变化等不足,通过利用敏捷开发模型的思路,设计了一种迭代式在轨服务卫星地面应用系统软件开发方法,将用户纳入到软件开发过程中,在各个研制阶段持续与用户进行需求迭代,完成业务软件的功能升级。结果表明：该方法可提升业务软件功能与用户需求的匹配程度,并为后续在轨服务卫星地面应用系统的建设提供参考。     

不良气象微环境下桥塔横梁覆冰灾害过程模拟

冬季桥塔横梁坠冰是威胁桥梁交通安全的重大隐患之一,系统分析不良气象微环境下横梁覆冰灾害过程机制,是保证桥梁交通安全的迫切需求。本文依托FLUENT与FENSAP-ICE软件建立了桥塔横梁覆冰数值仿真模型,探讨了风速、液态水含量和环境温度等微气象参数对桥塔横梁覆冰灾害演化过程的影响规律。结果表明：本文提出的数值仿真方法在明冰及霜冰条件下均具有较高的可行性与准确性;对武汉长江二桥桥塔横梁结冰数值模拟发现,覆冰区域集中分布于横梁迎风侧前缘及上下边缘,整体呈现出“U”型分布特征,是横梁防冰、除冰的重点区域;不良气象微环境是影响横梁结冰形态、分布及覆冰量的重要因素,覆冰形状受风速、液态含水量影响较大,受温度影响较小。     

Development of Sn2+-based oxyfluoride photocatalyst with visible light response of ca.650 nm via strengthened hybridization of Sn 5s and 02p orbitals

The hybridization between the outmost s orbitals of metal (Bi3+,Sn2+,Pb2+,Ag+) and O 2p orbitals has been widely employed to develop innovative semiconductors w...     

基于帕累托最优效率模型的轨道交通沿线公交线路运行效率评价

通过建立公交运行效率评价模型,确定轨道交通沿线待优化线路,为两网融合奠定理论基础。研究首先通过定性定量法筛选出与轨道交通关联度大且有研究意义公交线路,其次以公交线网自身合理性、两网之间协同关系等数据构建评价体系,最后采用帕累托最优交叉效率模型,求解沿线公交线路运行效率。以南昌市1号线为例,筛选出沿线25条公交线路并进行实证分析。结果表明：帕累托最优交叉效率模型的评分更容易被所有的决策单元（Decision-Making Units,DUM s）接受;数据分析得出南昌公交线网自身合理性较好,但在两网协同关系方面,可优化线路走向、调整线路重复系数等加强其协同性。最后基于两者的帕累托交叉效率均值,将25条公交线路划分为4种案例,为公共交通系统的管理者和决策者提供了更实用和有价值的观点。     

基于卷积神经网络的新奇检测技术在结构损伤识别中的应用

针对新奇检测难以同时识别结构损伤时刻和损伤位置的问题,提出在新奇检测中引入卷积神经网络以实现损伤时刻和损伤位置的一次性确定。首先,采用小波包技术处理结构响应得到小波包能量,并将相邻测点对应频带的能量比作为新奇检测模型的特征向量;然后,以结构健康时的特征向量作为训练数据,建立健康模式下的基于卷积神经网络的新奇检测模型;接着,将结构实时输出的特征向量输入到新奇检测模型,所得输出与健康状态的输出进行对比,并将输出和输入的欧氏距离作为新奇指标;最后,根据新奇指标的变化识别结构损伤时刻和损伤位置。数值模拟和实验室试验验证了该方法的有效性。     

石榴枯萎病的生防木霉菌株的筛选及鉴定

目的 石榴枯萎病是由甘薯长喙壳菌引起,对石榴有严重危害的土传病害。利用拮抗微生物抑制病原菌的繁殖是石榴枯萎病绿色防控的有效手段。通过筛选具有对石榴枯萎病原菌产生拮抗效果的微生物,研究其抑制菌作用,以期为石榴枯萎病生物防控提供菌种资源。方法 从石榴的根际土壤中分离出真菌,根据产孢量、生长速率、拮抗系数及平板对峙结果进行筛选,对防效较好的真菌根据形态学和分子系统学进行鉴定,通过盆栽实验评估其对石榴枯萎病的防治效果。结果 能有效抑制石榴枯萎病菌菌丝的生长的菌株T9经鉴定为非洲哈茨木霉菌（Trichoderma afroharzianum）,盆栽防治效果最高可达71.35%。结论 该菌株展现出了对石榴枯萎病的生物防治效果,具有应用价值。     

Facile synthesis of sulfenyl-substituted isocoumarins,heterocycle-fused pyrones and 3-(inden-1-ylidene)isobenzofuranones by FeCl3-promoted regioselective annulation of o-(1-alkynyl)benzoates and o-(1-alkynyl)heterocyclic carboxylates with disulfides

Reported herein is the FeCl₃-promoted intermolecular sulfoesterification of o-(1-alkynyl)benzoates with disulfides, which provides a convenient and efficient method for synthesis of 4-sulfenylisocoumarins. Various functional groups such as methoxy, halides, ester, cyano and silicon groups in the substrates are tolerated, and heterocycle-fused chalcogenylpyrones are also successfully achieved directly from the corresponding heterocyclic precursors under the same reaction conditions. In addition, starting from diynylbenzoate, this reaction sequence can be combined with a bicyclization step leading to the tetracyclic (E)-3-(2-phenyl-3-phenylchalcogenylinden-1-ylidene)isobenzofuranone frameworks with high regiospecificity and exclusive trans stereoselectivity.     

Immobilized palladium on surface-modified Fe3O4/SiO2 nanoparticles: as a magnetically separable and stable recyclable high-performance catalyst for Suzuki and Heck cross-coupling reactions

A palladium-based catalyst (Fe₃O₄/SiO₂/HPG–OPPh₂–PNP) supported on chlorodiphenylphosphine-functionalized magnetic nanoparticles was successfully prepared from Fe₃O₄/SiO₂ with sequential attachment of glycerol and chlorodiphenylphosphine, followed by treatment of an ethanolic solution of palladium chloride with hydrazine. The as-prepared catalyst was characterized by ICP-AES, FTIR, XRD, SEM, and TEM. The Fe₃O₄/SiO₂/HPG–OPPh₂–PNP was found as a magnetically separable and highly active catalyst for Suzuki coupling reactions of aryl iodides, bromides, and chlorides as well as Heck reactions of aryl iodides and bromides. Under appropriate conditions, all reactions afforded the desired products in moderate to excellent yields. Moreover, this catalyst can be easily recovered by using a magnetic field and directly reused for at least six cycles without significant loss of its activity.     

A new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep and its application in asymmetric hydrogenation

A new electronically deficient atropisomeric diphosphine ligand (S)-CF₃O-BiPhep was synthesized from 1-bromo-3-(trifluoromethoxy)benzene in high yield. The key steps included oxidative coupling with anhydrous ferric chloride and optical resolution by (+)-DMTA. The ligand afforded high performance for Ir-catalyzed asymmetric hydrogenation of quinolines with ee up to 92% and TON up to 25,000. It was also successfully applied to the Pd-catalyzed asymmetric hydrogenation of simple indoles with ee up to 87% and Rh-catalyzed asymmetric 1,4-addition of phenylboronic acid to 2-cyclohexenone with 97% ee.