不同切型BaTiO3晶体二波耦合特性研究

分析了光折变晶体的电光系数对二波耦合特性的影响,二波耦合能量转移方向不仅依赖于晶体中光生载流子的电荷符号以及入射光与晶体ｃ轴的相对取向,而且依赖于晶体光系数各分量的相对大小;这种特性别明显地表现在相向二波耦合作用中。     

Nucleon form factors in a relativistic quark model

Electromagnetic form factors of protons and neutrons are investigated based on a relativistic quark model with the inclusion of a pion cloud. Pseudo-scalar π-quark interaction is employed to study the coupling between the nucleon and the π. The results show the important role of the pion cloud for the neutron charge form factor. Moreover, our numerical analysis indicates a difference between the relativistic and the nonrelativistic treatments. Received: 10 March 1999 / Revised version: 14 June 1999     

单模光纤开关特性的研究

首次对单模光纤的开关特性进行了分析和计算,得出了色散光纤中不仅存在开关信号的延迟,而且开关速度将受到限制,给出了计算光纤开关时间(上升时间或下降时间)的公式。公式表明,光纤的开关时间与色散绝对值的平方根成正比,与长度的平方根成正比。工作在1.55μm波长的长1km的G652光纤,其开关时间约为7ps,这一参量最终限制了由光纤构成的二光平开关器件的开关速度。     

基于压缩感知的振动数据修复方法

为解决旋转机械振动信号丢失数据修复的问题,提出一种基于压缩感知原理的振动数据修复方法.首先对采集到的不完整信号进行处理,将无信息输入时刻对应的数据用零元素填充得到有损信号,以单位矩阵为基础,根据有损信号中零元素的位置信息,构造对应于压缩感知框架下的观测矩阵;再根据待修复信号的特点并结合先验知识,构造或选择能够对振动信号进行稀疏表示的字典矩阵;然后使用高效且稳定的追踪算法,根据有损信号、观测矩阵以及字典矩阵重构原始信号,实现丢失振动数据的修复.使用仿真数据检验方法的有效性;使用实测的轴承振动状态数据验证方法对于振动数据的适用性,并通过比较完整信号、有损信号和修复信号对应的时域和频域特征值来检验数据修复效果.实验结果表明:本文方法能够有效地实现丢失数据的修复,且从统计特征的角度来看,相比于有损信号,修复信号能够更为准确地描述真实完整的振动信号.     

采用PEABr添加剂获得高效且稳定的碳基CsPbBr3太阳能电池

全无机CsPbBr₃钙钛矿材料因其本征稳定性好、成本低廉从而在光伏领域展现出巨大的应用潜力,但目前CsPbBr₃太阳能电池的光电转换效率仍远低于其他体系的钙钛矿太阳能电池.本文以无空穴传输层结构的碳基CsPbBr₃全无机钙钛矿电池作为研究对象,以多步旋涂法为基础,通过在PbBr₂(DMF)溶液中添加2-苯乙胺溴盐(PEABr)来调控CsPbBr₃薄膜的结晶质量,降低薄膜缺陷态密度,钝化晶粒间界,并对其中的关键工艺参数包括CsBr的用量(旋涂次数)、旋涂PbBr₂薄膜时的衬底预热温度以及退火温度进行了优化.最终在大气环境下获得了兼具稳定和高效的无空穴传输层结构的碳基CsPbBr₃太阳能电池,器件的光电转换效率达到8.25%,并在无封装条件下保存1500 h仍可保持90%以上的效率,对于进一步拓展CsPbBr₃钙钛矿电池的优化设计思路具有重要意义.     

双轴应变调控二维单层C2X2TM（X = O, H; TM=Fe, Cr） 的多铁性研究

基于密度泛函理论的第一性原理计算,系统地研究了过渡金属原子插层的单层氧化/氢化石墨烯的磁学性质和铁电性质.在考虑了电子在位库仑作用和自旋轨道耦合作用下,得到了过渡金属Fe、Cr插层形成的C₂X₂TM二维单层膜的稳定结构以及基态磁性结构,研究了不同应变作用下C₂X₂TM的磁性、能带、铁电极化以及电子结构的变化.结果发现,对于任何应变下的C₂X₂TM其基态磁性都为手性逆时针反铁磁结构.在无应变时体系存在一个较大的离子翻转势垒,通过外加双轴应变,可有效调控体系的势垒高度和能隙,发现25%应变下C₂O₂Cr和30%应变时C₂O₂Fe单层薄膜具有与GeS等二维铁电材料相近的铁电极化和翻转势垒,这些研究结果表明C₂O₂Fe(Cr)单层薄膜是一种新型二维多铁性材料.     

Parameter estimation of continuous variable quantum key distribution system via artificial neural networks

Continuous-variable quantum key distribution(CVQKD)allows legitimate parties to extract and exchange secret keys.However,the tradeoff between the secret key rate and the accuracy of parameter estimation still around the present CVQKD system.In this paper,we suggest an approach for parameter estimation of the CVQKD system via artificial neural networks(ANN),which can be merged in post-processing with less additional devices.The ANN-based training scheme,enables key prediction without exposing any raw key.Experimental results show that the error between the predicted values and the true ones is in a reasonable range.The CVQKD system can be improved in terms of the secret key rate and the parameter estimation,which involves less additional devices than the traditional CVQKD system.     

The Schiff Base Probe With J-aggregation Induced Emission for Selective Detection of Cu2+

Here, three Schiff bases 3a-c, differing by the substitutions (–H, –Cl, and –N(CH₃)₂) on the phenyl ring, have been designed and synthesized via the reaction of ortho-aminophenol with benzaldehyde, 2,4-dichlorobenzaldehyde and para-dimethylamine benzaldehyde in 1:1 molar ratio with favourable yields of 89–92%, respectively. Their structural characterizations were studied by FT-IR, NMR, MALDI-MS and elemental analysis. The fluorescence behaviours of compounds 3a and 3b exhibited a severe aggregation caused quenching (ACQ) effect in EtOH/water system. On the contrary, compound 3c had an obvious J-aggregation induced emission (AIE) feature in EtOH/water mixture (v/v?=?1:1), and exhibited excellent sensitivity and anti-interference towards Cu²⁺ with the limit of detection (LOD) of 1.35?×?10^–8 M. Job’s plot analysis and MS spectroscopic study revealed the 2:1 complexation of probe 3c and Cu²⁺. In addition, probe 3c was successfully applied to the determination of Cu²⁺ in real aqueous samples.

     

格子Boltzmann模型平衡分布边界条件和多棱柱排列渗流流场的数值模拟

介绍了适用于多种流场数值模拟的无滑动格子Boltzmann平衡分布边界条件，这一边界条件是以Bounce-Back方法为基础并满足质量、动量守恒的准则.数值计算结果表明平衡分布边界条件克服了Bounce-Back方法在边界上所产生的滑动速度误差效应.利用平衡分布边界条件数值模拟了由棱柱形充填粒子构成的微尺度渗流流场中的Darcy-Forchheimer方程，通过与Lee 和Yang的数值结果比较，该预测结果是足够可靠的. 关键词： 平衡分布边界条件 渗流介质 Darcy-Forchheimer阻力