全文获取类型
收费全文 | 10047篇 |
免费 | 1321篇 |
国内免费 | 1290篇 |
专业分类
化学 | 5573篇 |
晶体学 | 62篇 |
力学 | 284篇 |
综合类 | 83篇 |
数学 | 802篇 |
物理学 | 2100篇 |
综合类 | 3754篇 |
出版年
2024年 | 49篇 |
2023年 | 159篇 |
2022年 | 237篇 |
2021年 | 263篇 |
2020年 | 321篇 |
2019年 | 330篇 |
2018年 | 285篇 |
2017年 | 233篇 |
2016年 | 373篇 |
2015年 | 453篇 |
2014年 | 519篇 |
2013年 | 648篇 |
2012年 | 719篇 |
2011年 | 702篇 |
2010年 | 607篇 |
2009年 | 608篇 |
2008年 | 610篇 |
2007年 | 631篇 |
2006年 | 548篇 |
2005年 | 476篇 |
2004年 | 469篇 |
2003年 | 447篇 |
2002年 | 592篇 |
2001年 | 436篇 |
2000年 | 337篇 |
1999年 | 330篇 |
1998年 | 192篇 |
1997年 | 182篇 |
1996年 | 146篇 |
1995年 | 112篇 |
1994年 | 112篇 |
1993年 | 88篇 |
1992年 | 74篇 |
1991年 | 92篇 |
1990年 | 59篇 |
1989年 | 58篇 |
1988年 | 43篇 |
1987年 | 22篇 |
1986年 | 25篇 |
1985年 | 20篇 |
1984年 | 11篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1979年 | 4篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1968年 | 3篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
81.
BODIPY dyes are privileged fluorophores that are now widely used in highly diverse research fields. An overview of BODIPY dyes and a summarization of the different synthetic methodologies reported for direct C-H functionalization of the BODIPY framework have been provided. 相似文献
82.
Two new esters, methyl 4‐(prenyloxy)dihydrocinnamate and methyl 4‐(geranyloxy)dihydrocinnamate, together with fourteen known compounds have been isolated from the stem bark of Zanthoxylum pistaciiflorum. The structures of two new compounds were determined through spectral analyses. Among the isolates, four compounds exhibited effective cytotoxicities against P‐388 and HT‐29 cell lines in vitro. 相似文献
83.
TheBeckInannrearrangement,theacid-mediatedisomerizationofoximestoamides,wasfirstdiscoveredinl886l.Asoneoftheoldestandmostfamiliartransformationsinorganicchemistry,ithasbeenwidelystudiedandagreatvarietyofmethodstoconductthistfansformationhavebeenreported'.However,mostofthesemethodswerecarriedoutbyusingalargeamountofsolventswithlongreactiontime.Whatismore,thepriorpreparationofthecorrespondingketoximesisusuallyrequired,whichmakestheseprocessesinconvenientandlessattractive.Bytakingadvantageofboth… 相似文献
84.
We have developed a coarse-grained multiscale molecular simulation method for soft matter systems that directly incorporates stereochemical information. We divide the material into disjoint groups of atoms or particles that move as separate rigid bodies; we call these groups "rigid blobs," hence the name coarse-grained rigid blob model. The method is enabled by the construction of transferable interblob potentials that approximate the net intermolecular interactions, as obtained from ab initio electronic structure calculations, other all-atom empirical potentials, experimental data, or any combination of the above. We utilize a multipolar expansion to obtain the interblob potential-energy functions. The series, which contains controllable approximations that allow us to estimate the errors, approaches the original intermolecular potential as the number of terms increases. Using a novel numerical algorithm, we can calculate the interblob potentials very efficiently in terms of a few interaction moment tensors. This reduces the labor well beyond what is required in standard molecular-dynamics calculations and allows large-scale simulations for temporal scales commensurate with characteristic times of nano- and mesoscale systems. A detailed derivation of the formulas is presented, followed by illustrative applications to several systems showing that the method can effectively capture realistic microscopic details and can easily extend to large-scale simulations. 相似文献
85.
A series of leaching experiments with H2O, HCl, HNO2 and HF were carried out on a sample of pitchblende from Africa. Anomalously high231Pa/235U ratios, which were not accompanied by similar enhancements of234U/238U and235U/238U ratios, were observed in some uranium fractions. The observed231Pa/235U ratios varied between the values of 0.035±0.005 and 2,000±300 (Ci/Ci). These results are interpreted as due, primarily, to the difference in the chemical properties of protactinium and uranium, rather than to the alpha-recoil effects. 相似文献
86.
Xin Sheng Li Yao Jun Zhang Qin Xin Chun Xin Ji Yan Fen Miao Li Wang 《Reaction Kinetics and Catalysis Letters》1996,57(1):177-182
Volumetric H2-uptake measurements on an Mo2N (79 m2g–1) sample reduced at 673 K have been carried out and the uptake isotherms in the temperature range of 308–623 K have been determined. Both the total and reversible hydrogen uptake increased with the uptake temperature. The irreversible hydrogen uptake increased abruptly when the uptake temperature was raised up to 423 K. The maximum of irreversible hydrogen uptake was measured at 473 K. The HIR/Mo ratio calculated from the uptakes obtained in the temperature range of 308–623 K varies in the range of 0.0010–0.0202. One possible mechanism for hydrogen adsorption is proposed to be heterolytic dissociation on Mo-N paris, in which the molybdenum atoms are in unsaturated coordination. 相似文献
87.
88.
X. Liu X. Sheng J. K. Lee M. R. Kessler 《Journal of Thermal Analysis and Calorimetry》2007,89(2):453-457
Conversion (α) and the glass transition temperature (T
g) were investigated during the isothermal cure of endo-dicyclopentadiene (DCPD) with a Grubbs catalyst for different temperatures using differential scanning calorimetry. Conversion
vs. In (time) data at an arbitrary reference temperature were superposed by horizontal shift and the shift factors were used
to calculate an Arrhenius activation energy. Glass transition temperature vs. conversion data fell on a single curve independent of cure temperature, implying that reaction of the norbornene and cyclopentene
ring of DCPD proceeds in a sequential fashion. Implications of the isothermal reaction kinetics for self-healing composites
are discussed. 相似文献
89.
DeShengYU LiangHUANG HuiLIANG PingGONG 《中国化学快报》2005,16(7):875-878
A series of novel oxazolidinone analogues were prepared by a new and efficient synthetic method and their antibacterial activities were determined. These compounds wer echaracterized by LC-MS and ^1H NMR. 相似文献
90.