全文获取类型
收费全文 | 45962篇 |
免费 | 5887篇 |
国内免费 | 4604篇 |
专业分类
化学 | 21797篇 |
晶体学 | 320篇 |
力学 | 2083篇 |
综合类 | 294篇 |
数学 | 3246篇 |
物理学 | 11602篇 |
综合类 | 17111篇 |
出版年
2024年 | 127篇 |
2023年 | 774篇 |
2022年 | 1137篇 |
2021年 | 1354篇 |
2020年 | 1418篇 |
2019年 | 1186篇 |
2018年 | 1070篇 |
2017年 | 1023篇 |
2016年 | 1581篇 |
2015年 | 1652篇 |
2014年 | 2268篇 |
2013年 | 2613篇 |
2012年 | 3169篇 |
2011年 | 3328篇 |
2010年 | 2428篇 |
2009年 | 2288篇 |
2008年 | 2698篇 |
2007年 | 2428篇 |
2006年 | 2339篇 |
2005年 | 2156篇 |
2004年 | 1687篇 |
2003年 | 1580篇 |
2002年 | 1638篇 |
2001年 | 1518篇 |
2000年 | 1306篇 |
1999年 | 1594篇 |
1998年 | 1287篇 |
1997年 | 1262篇 |
1996年 | 1221篇 |
1995年 | 991篇 |
1994年 | 941篇 |
1993年 | 784篇 |
1992年 | 767篇 |
1991年 | 608篇 |
1990年 | 538篇 |
1989年 | 480篇 |
1988年 | 400篇 |
1987年 | 264篇 |
1986年 | 186篇 |
1985年 | 103篇 |
1984年 | 57篇 |
1983年 | 55篇 |
1982年 | 31篇 |
1981年 | 32篇 |
1980年 | 16篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1974年 | 9篇 |
1957年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 343 毫秒
11.
Li Quanxin Li Zheng He Cheng Sun Huilin Tan Shengheng Zhang Hua 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(5):2105-2115
Journal of Radioanalytical and Nuclear Chemistry - The simplified 8-oxide system (SiO2-B2O3-Na2O-Al2O3-CaO-TiO2-MoO3-La2O3) has been prepared under two types of cooling methods, and analyzed with... 相似文献
12.
Li Jun Zheng Dayong Wei Ning Sun Yunfeng Liu Li Yuan Yuan Jiang Qinghua 《Chemistry of Natural Compounds》2022,58(4):650-652
Chemistry of Natural Compounds - A new quassinoid, dehydrobruceantinol B (1), was isolated from the seeds of Brucea javanica, together with two known compounds, bruceantinol (2) and bruceine A (3).... 相似文献
13.
Donglei Wei Huili Li Chuanqing Yang Jianmin Fu Hou Chen Liangjiu Bai Wenxiang Wang Huawei Yang Lixia Yang Ying Liang 《Journal of polymer science. Part A, Polymer chemistry》2022,60(10):1588-1594
Acridone as a new kind of visible light photocatalyst has been developed to catalyze metal free atom transfer radical polymerization (ATRP). The photocatalyst possess low excited state potential as can undergo an oxidative quenching pathway to initiate ATRP of vinyl monomers. Kinetic study and light on/off reaction demonstrate the “living”/controlled nature of the polymerization by light. Block copolymers can be achieved by using PMMA as macroinitiator to reinitiate polymerization of other vinyl monomers, which shows highly preserved Br chain-end functionality in the synthesized polymers. Moreover, the polymerization can be conducted under air atmosphere as most photocatalysts need anaerobic condition, which may give inspiration of further application of this kind of photocatalyst. 相似文献
14.
15.
Dr. Yong-Sheng Wei Dr. Liming Sun Miao Wang Dr. Jinhua Hong Dr. Lianli Zou Hongwen Liu Dr. Yu Wang Dr. Mei Zhang Dr. Zheng Liu Prof. Yinwei Li Prof. Satoshi Horike Prof. Kazu Suenaga Prof. Qiang Xu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(37):16147-16156
Understanding the thermal aggregation behavior of metal atoms is important for the synthesis of supported metal clusters. Here, derived from a metal–organic framework encapsulating a trinuclear FeIII2FeII complex (denoted as Fe3) within the channels, a well-defined nitrogen-doped carbon layer is fabricated as an ideal support for stabilizing the generated iron nanoclusters. Atomic replacement of FeII by other metal(II) ions (e.g., ZnII/CoII) via synthesizing isostructural trinuclear-complex precursors (Fe2Zn/Fe2Co), namely the “heteroatom modulator approach”, is inhibiting the aggregation of Fe atoms toward nanoclusters with formation of a stable iron dimer in an optimal metal–nitrogen moiety, clearly identified by direct transmission electron microscopy and X-ray absorption fine structure analysis. The supported iron dimer, serving as cooperative metal–metal site, acts as efficient oxygen evolution catalyst. Our findings offer an atomic insight to guide the future design of ultrasmall metal clusters bearing outstanding catalytic capabilities. 相似文献
16.
17.
Analysis and pharmacokinetic study of polyphyllin H in beagle dog plasma after oral administration of Rhizoma Paridis Extracts by LC‐MS/MS
下载免费PDF全文
![点击此处可从《Biomedical chromatography : BMC》网站下载免费的PDF全文](/ch/ext_images/free.gif)
18.
19.
Qin Yin Shou-Guo Wang Xiao-Wei Liang De-Wei Gao Jun Zheng Shu-Li You 《Chemical science》2015,6(7):4179-4183
An organocatalytic asymmetric chlorinative dearomatization of naphthols was realized for the first time, providing chiral naphthalenones with a Cl-containing all-substituted stereocenter in excellent yields and enantioselectivity (up to 97% yield and 96% ee). The reaction features mild reaction conditions, good tolerance of diverse functional groups and simple reaction operation. 相似文献
20.
Mass concentration and isotopic values δ13C and 14C are presented for the water-insoluble refractory carbon(WIRC) component of total suspended particulates(TSP),collected weekly during 2003,as well as from October 2005 to May 2006 at the WMO-GAW Mt.Waliguan(WLG) site.The overall average WIRC mass concentration was(1183±120)ng/m3(n = 79),while seasonal averages were 2081 ±1707(spring),454±205(summer),650±411(autumn),and 1019±703(winter) ng/m3.Seasonal variations in WIRC mass concentrations were consistent with black carbon measurements from an aethalometer,although WIRC concentrations were typically higher,especially in winter and spring.The δ13C PDB value(-25.3 ± 0.8)%.determined for WIRC suggests that its sources are C3 biomass or fossil fuel combustion.No seasonal change in δ13C PDB was evident.The average percent Modern Carbon(pMC) for 14C in WIRC for winter and spring was(67.2 ± 7.7)%(n = 29).Lower pMC values were associated with air masses transported from the area east of WLG,while higher pMC values were associated with air masses from the Tibetan Plateau,southwest of WLG.Elevated pMC values with abnormally high mass concentrations of TSP and WIRC were measured during a dust storm event. 相似文献