Analysis of Paeoniae Radix by high-performance liquid chromatography-electrospray ionization-mass spectrometry.

A method has been developed for the qualitative analysis of paeonol, paeoniflorin and their derivatives in Paeoniae Radix by high-performance liquid chromatography-electrospray ionization-mass spectrometry (HPLC-ESI-MS). Gradient elution with acetonitrile-water solvent system was employed in an HPLC-ESI-MS study. The negative-ion ESI mode was suitable for these compounds. The peaks were identified by their mass spectra, UV spectra and fragments of their MS2 spectra. The structures of three unknown compounds are inferred in this paper.     

Formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber blends: Effects of preparation method,composition, and thermal condition

The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007     

歧义容忍度在二语习得中的研究

英语学习者在学习过程中经常不可避免的接触到各种语言层面的歧义现象,比如:语法层面、词汇层面、句法层面等。本文从心理和语言的角度介绍了歧义容忍度的概念。接着分析了歧义容忍度和二语学习的关系。在此基础上,介绍了歧义容忍度的测量方法。最后,文章概括性的讨论了歧义容忍度对二语习得的启示。     

CFG桩施工引起桩周土体开裂的原因探讨

由于郑东新区特殊的工程地质条件，长螺旋CFG（Cement Flyash Gravel）桩施工常常引起桩周土体开裂和周围建筑物开裂等施工事故。本文通过郑州某工地现场试验分析，否定了空桩效应引起桩周土体开裂的猜想，并分析了郑东新区由于CFG桩施工引起桩周土体开裂的原因。     

山西省部分非试点县农村新型合作医疗的调查

建立推广新型合作医疗的要点是:加大宣传力度;加强领导,发挥政府主导作用;强化监督,加强管理,确保基金安全平稳运行;创新服务机制,完善便民措施,实现服务管理一体化。     

蒸汽机车水垢形成机理及解决方法

蒸汽机车锅炉水垢对机车的安全运行及工作效能有很大的影响,对蒸汽机车水垢的处理极其重要。蒸汽机车水垢是经过复杂的物理、化学变化而形成的。由于水垢的形成,造成锅炉的传热效率低,大量浪费燃料;降低锅炉出力危及锅炉安全运行;缩短使用寿命增大检修量,浪费工时、原料。为了缓解机车水垢的形成,可以采取尽量降低软化水硬度、确保洗修质量、合理安排排污时机和次数,提高排污效果等措施,并在实际运用中取得了一定的效果。     

西藏公务员工作满意度调查与分析

通过对西藏公务员工作满意度的调查,分析影响西藏公务员工作满意度的主要因素以及工作满意度体现在人口统计变量上的差异,并对此提出相应的对策建议。     

Synthesis of some chiral liquid crystals and study of the effect of intramolecular hydrogen bonding on the phase behaviour

The synthesis of three new series of chiral Schiff's bases containing benzilideneaniline and 2-hydroxybenzilideneaniline moieties as mesogenic cores is presented. Differential scanning calorimetry, optical polarizing microscopy and X-ray diffraction measurements were used to study the phase transition temperatures and behaviour. The results reveal that most of these materials show chiral smectic mesomorphism.     

水轮发电机组H∞状态反馈综合最优控制系统

根据实际工程应用的特点，改进了Ｈ_∞状态反馈控制的算法，并给出了一种选择Ｈ_∞权矩阵的方法；以此为基础设计及研究了一种能综合控制水轮发电机组的励磁和导叶开度，集励磁调节器、调速器功能于一体的综合控制系统．结果表明，该控制器在基本不影响系统响应性能的情况下，能明显地改善系统的鲁棒性．