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941.
Polycrystalline perovskite La0.67Ca0.33MnO3 was synthesized by a sol–gel method. Its adiabatic temperature change ΔTad induced by a magnetic field change was measured directly. At 268 K, near its Curie temperature TC, ΔTad of La0.67Ca0.33MnO3 induced by a magnetic field change of 2.02 T reaches 2.4 K. The latent heat Q and magnetic entropy change −ΔSM induced by a magnetic field change were calculated from the temperature dependence of ΔTad and zero-field heat capacity Cp. The maximum values of Q and −ΔSM in La0.67Ca0.33MnO3 induced by a magnetic field change of 2.02 T are 1.85 J g−1 and 6.9 J kg−1 K−1, respectively. The former is larger than the phase transition latent heat of heating or cooling, which is about 1.70 J g−1. 相似文献
942.
943.
944.
Yu ZHANG Ji Tao SUN 《数学学报(英文版)》2006,22(3):813-818
In this paper, we will extend the strict stability to impulsive differential equations. By using Lyapunov functions, we will get some criteria for the strict stability of impulsive differential equations, and we can see that impulses do contribute to the system's strict stability behavior. An example is also given in this paper to illustrate the efficiency of the obtained results. 相似文献
945.
采用高斯分解法(GD)对大非线性相移下的Z扫描特性进行了分析,通过对数值算法的优化,将GD推广到对脉冲入射激光下大非线性相移下的Z扫描理论分析.对不同条件下大非线性相移Z扫描曲线峰谷结构的比较,发现在大非线性相移的情况下,Z扫描曲线的峰和谷随透过光阑或入射光强变化表现出某些新的特性.随着透过光阑孔径的增加,Z扫描曲线峰的变化要明显快于谷的变化,而且在谷明显存在的情况下,峰很快消失.采用皮秒脉冲激光下的纯二硫化碳实验对理论结果加以验证,实验结果和理论分析相一致.我们的分析结果对大非线性相移下Z扫描测量有一定的指导性意义,避免在大非线性相移下对Z扫描结果产生错误的分析.
关键词:
大非线性相移
高斯分解法
Z扫描 相似文献
946.
Xiujie Li Weiping Zhang Shenglin Liu Xiuwen Han Longya Xu Xinhe Bao 《Journal of molecular catalysis. A, Chemical》2006,250(1-2):94-99
The interfacial interaction of Mo species with the HBeta zeolite was studied by multinuclear MAS NMR, XRD and N2 adsorption. As proved by the quantitative 27Al MAS NMR, this interaction is so strong as to dealuminate the framework of HBeta, and leads to a new peak appearing at −14 ppm, which indicates the formation of crystalline Al2(MoO4)3. This can also be detected by XRD measurements when the Mo loading is as high as 9.0 wt.%. The corresponding quantitative 29Si and 1H MAS NMR spectra show that the amount of silanols and Brønsted acidic sites decrease obviously with increasing Mo loading. This also reveals an interaction between Mo species and HBeta support through an oxygen bridge resulting from condensation with the hydroxyls on the support. At higher Mo loadings, the interaction is so strong that it results in an extraction of aluminum from the zeolite framework, and subsequently appearance of Al2(MoO4)3 and loss of Brønsted acidic sites. These can be correlated to the low catalytic activity of Mo/HBeta in metathesis of ethylene and 2-butylene to propylene. 相似文献
947.
Dongheng Zhang Wen-Hua Sun Junxian Hou Suyun Jie Fei Chang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):264-272
The polymerization of cyclopentadiene (CPD) was effectively initiated by methylaluminoxane (MAO) to generate poly(cyclopentadiene) (polyCPD). The effects on the polymerization of some reaction parameters such as the monomer concentration, the initiator concentration, and solvents were investigated. The conversion of CPD was monitored with gas chromatography to investigate the reaction kinetics. The polymerization rate was proportional to the concentrations of MAO in the first order and of the CPD monomer in the second order, and a reasonable cationic polymerization mechanism was suggested on the basis of the kinetic study. PolyCPD obtained at a low temperature could be dissolved in toluene or chloroform, and this indicated lower cross‐coupling during the polymerization reaction. 1H NMR and IR analysis of the polymer indicated that there were almost equal amounts of 1,2‐enchainment and 1,4‐enchainment in the polymer chain. The measurement of polyCPD showed its unique properties as a potential candidate for stable wrappings or electronic packaging materials. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 264–272, 2006 相似文献
948.
Amphiphilic biodegradable block copolymers [poly(sebacic anhydride)–poly(ethylene glycol)–poly(sebacic anhydride)] were synthesized by the melt polycondensation of poly(ethylene glycol) and sebacic anhydride prepolymers. The chemical structure, crystalline nature, and phase behavior of the resulting copolymers were characterized with 1H NMR, Fourier transform infrared, gel permeation chromatography, and differential scanning calorimetry. Microphase separation of the copolymers occurred, and the crystallinity of the poly(sebacic anhydride) (PSA) blocks diminished when the sebacic anhydride unit content in the copolymer was only 21.6%. 1H NMR spectra carried out in CDCl3 and D2O were used to demonstrate the existence of hydrophobic PSA domains as the core of the micelle. In aqueous media, the copolymers formed micelles after precipitation from water‐miscible solvents. The effects on the micelle sizes due to the micelle preparation conditions, such as the organic phase, dropping rate of the polymer organic solution into the aqueous phase, and copolymer concentrations in the organic phase, were studied. There was an increase in the micelle size as the molecular weight of the PSA block was increased. The diameters of the copolymer micelles were also found to increase as the concentration of the copolymer dissolved in the organic phase was increased, and the dependence of the micelle diameters on the concentration of the copolymer varied with the copolymer composition. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1271–1278, 2006 相似文献
949.
Z. X. Li L. Q. Lin W. M. Zhang T. Wu J. L. Pu 《Journal of polymer science. Part A, Polymer chemistry》2006,44(3):1291-1298
A series of new polyimides were prepared via the polycondensation of (3‐amino‐2,4,6‐trimethylphenyl)‐(3′‐aminophenyl)methanone and aromatic dianhydrides, that is, 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA), 4,4′‐oxydiphthalic anhydride, 3,3′,4,4′‐benzophenone tetracarboxylic dianhydride, and 2,2′‐bis(3,4‐dicarboxyphenyl) hexafluoropropane dianhydride. The structures of the polyimides were characterized by Fourier transform infrared and NMR measurements. The properties were evaluated by solubility tests, ultraviolet–visible analysis, differential scanning calorimetry, and thermogravimetric analysis. The two different meta‐position‐located amino groups with respect to the carbonyl bridge in the diamine monomer provided it with an unsymmetrical structure. This led to a restriction on the close packing of the resulting polymer chains and reduced interchain interactions, which contributed to the solubility increase. All the polyimides except that derived from BPDA had good solubility in strong aprotic solvents, such as N‐methyl‐2‐pyrrolidinone, N,N′‐dimethylacetamide, N,N‐dimethylformamide, and dimethyl sulfone, and in common organic solvents, such as cyclohexanone and chloroform. In addition, these polyimides exhibited high glass‐transition values and excellent thermal properties, with an initial thermal decomposition temperature above 470 °C and glass‐transition temperatures in the range of 280–320 °C. The polyimide films also exhibited good transparency in the visible‐light region, with transmittance higher than 80% at 450 nm and a cutoff wavelength lower than 370 nm. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1291–1298, 2006 相似文献
950.
Nianchen Zhou Wenjian Xu Yu Zhang Jian Zhu Xiulin Zhu 《Journal of polymer science. Part A, Polymer chemistry》2006,44(4):1522-1528
2,2,6,6‐Tetramethyl‐4‐[d‐(+)‐10‐camphorsulfonyl]‐1‐piperidinyloxy was synthesized and used as a chiral nitroxide for the bulk polymerizations of styrene initiated with benzoyl peroxide (BPO), tetraethylthiuram disulfide (TETD), and thermal initiation. The results showed that the polymerizations proceeded in a controlled/living way; that is, the kinetics presented approximately first‐order plots, and the number‐average molecular weights of the polymers with narrow molecular weight distributions (weight‐average molecular weight/number‐average molecular weight) increased with the monomer conversion linearly. The molecular weight distributions in the case of thermal initiation were narrower than those in the case of BPO and TETD, whereas the polymerization rate with BPO or TETD as an initiator was obviously faster than that with thermal initiation. In addition, successful chain‐extension reactions were carried out, and the structures of the obtained polymers were characterized by gel permeation chromatography and 1H NMR. The specific rotations of the polymers were also measured by polarimetric analysis. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1522–1528, 2006 相似文献