Direct Intermediate Regulation Enabled by Sulfur Containers in Working Lithium–Sulfur Batteries

Polysulfide intermediates (PSs), the liquid-phase species of active materials in lithium–sulfur (Li-S) batteries, connect the electrochemical reactions between insulative solid sulfur and lithium sulfide and are key to full exertion of the high-energy-density Li-S system. Herein, the concept of sulfur container additives is proposed for the direct modification on the PSs species. By reversible storage and release of the sulfur species, the container molecule converts small PSs into large organosulfur species. The prototype di(tri)sulfide-polyethylene glycol sulfur container is highly efficient in the reversible PS transformation to multiply affect electrochemical behaviors of sulfur cathodes in terms of liquid-species clustering, reaction kinetics, and solid deposition. The stability and capacity of Li-S cells was thereby enhanced. The sulfur container is a strategy to directly modify PSs, enlightening the precise regulation on Li-S batteries and multi-phase electrochemical systems.     

对高职数控专业毕业综合实训的探讨

本文探讨了数控技术专业毕业综合实训的改革思路，提出按职业资格标准强化技能培训，使学生在毕业前获得数控机床操作职业资格证书，切实提高学生的职业素质与就业竞争能力。     

现代教学媒体及其应用的探讨

教学媒体是现代教育技术的重要组成部分，它是人类社会发展的成果之一，文章对各类现代教学媒体进行了探讨。     

Temperature effects on surface activity and application in oxidation of toluene derivatives of CTAB-SDS with KMnO4

The γ_cmc values of CTAB-SDS decrease from 63.67 mN/m at 10‡C to 36.38 mN/m at 90‡C, slightly lower than those of either CTAB or SDS. Correspondingly, the CMC of CTAB-SDS decreases almost by half. The increase of surface activity of CTAB-SDS can be attributed to the relatively weak electrostatic interaction at high temperature, which is supported by the increase of solubility of CTAB-SDS with rise in temperature. Catalytic effect on oxidation of toluene derivatives with potassium permanganate follows the order CTAB-SDS > SDS > CTAB. This is not caused by the dissociative effect of CTAB-SDS with low surface activity at low temperature, as seen from the fact that almost all oxidative products can be retrieved for different toluene derivatives and surfactants by mimicking the conditions of reaction. In the emulsifications of toluene derivatives at 90‡C, the time that turbid water layers of surfactant solutions take to become clear is the same as that of the catalytic effect on oxidation of toluene derivatives. Thus, it can be inferred that surfactants can improve the oxidation yields of toluene derivatives by increasing the contact between two reacting phases.     

集成电路设计产业产品创新趋势研究——国际片上系统（SOC）IP核发展现状及对策分析

基于国际集成电路设计产业的分析，系统阐述了国际SOCIP核的发展状况，指出SOC设计将是集成电路设计企业技术创新的发展方向。提出了一些国际SOCIP核发展的对策，包括口核标准化、SOC技术平台开发及加强与Foundry的合作。     

论会计模拟实验的建立与发展

现行的会计实验教学环节不能满足新形势下会计专业培养目标的要求,建立和发展会计模拟实验是当务之急。     

数项级数审敛的思路与技巧

本文通过典型例题的求解与评析,探讨了级数敛散性的解题思路与技巧,对学生判定数项级数敛散时经常出现的错误与问题,提出了具有针对性的解决方法。     

电磁场中带电粒子束运动的力学模拟

研究以不同初速度进入互相垂直的匀强磁场和均强电场中的带电粒子束的运动情形，并同相似的力学运动相比拟，建立了直观的力学模型。     

A new molecular rectifier device and some research in its processing

Organic materials of D-π-A type MR-X (MR-1: p-dimethylaminophenylethenetrica-rbonitrile and MR-2: p-diphenylaminophenylethene tricarbonitrile) were designed and synthesized. The device with a sandwich structure shows good rectificative phenomena. The highest rectification ratio 10000 was achieved in device Cu/MR-1/Ag, and about 100 in other device M/MR-X/M (M: Cu, Ag). It has been found that rectificative phenomena exist only in the atmosphere-liquid interface region by means of liquid adsorption, and electric field could help form the oriented molecular film. __________ Translated from Journal of Fudan University (Natural Science), 2005, 44(4) (in Chinese)     

碳钢膏剂无孔渗硅工艺的研究

本研究用膏剂法进行无孔渗硅研究,透射电镜、电子探针和M351腐蚀仪分析证实:获得了致密、无孔隙、具有良好耐磨性和耐腐蚀性的渗硅层,并分析了渗硅层形成机理及表层疏松层以及内部孔隙成因。