一种简易新型长光程薄层光谱电化学池

设计并制作了一种新型长光程薄层光谱电化学池，其具有光程长、灵敏度高、重现性好等特点，且组装简便，电极容易更换，溶液未补偿电阻小，溶液用量少．易清洗．电解池以石墨为工作电极，分别用循环伏安、交流阻抗技术、光谱恒电位技术对其性能进行测试，得到比较满意的结果．     

基于层面信息的路径优化

根据分层物体快速成型（LOM）中零件逐层累积的特点，从缩短加工时间、提高制件效率方面着手阐述了路径优化的必要性，针对LOM机的运动机理和软件数据结构，给出了扫描路径优化的原理，将图论中的便宜算法用于LOM机的扫描路径优化。     

HPLC法测定阿奇霉素葡萄糖注射液中阿奇霉素的含量

利用高效液相色谱法，以VP-ODS型色谱柱，乙腈-异丙醇-水-氨水（60：25：15：0.1)为流动相，于210nm波长处测定了阿奇霉素葡萄糖注射液中阿奇霉素葡萄糖注射液中阿奇霉素的含量。阿奇霉素的浓度在0.75-1.75mg/mL线性关系良好，线性方程的A=881910.4c-16208.2，相关系数r=0.9999。阿奇霉素的平均回收率为99.59%，测定结果的相对标准偏差为1.31%。     

WAXS studies on block copolymers of ethylene and propylene

Wide-angle X-ray scattering from presumed block copolymers of polypropylene (PP) and ethylene-propylene copolymer (EPR), i.e., PP-EPR and PP-EPR-PP, synthesized by sequential polymerization with δ-TiCl₃? Et₂AlCl, was examined and compared with WAXS of mechanical blends and chain-transfer mixtures of PP and EPR with comparable compositions. The peak at 2θ = 20° for both the copolymers and the mixtures was attributed to the γ modification of PP in EPR. A strong variation in the ratio of diffraction intensities I₀₄₀/I₁₁₀ of PP in block copolymers and mixtures was explained in terms of crystallite growth in different directions. Analysis of the patterns and calculation of crystallinity, crystallite size, and lattice parameters led to the conclusion that block structure existed in the prepared copolymers.     

Pd (II)‐catalyzed vinyl addition polymerization of novel functionalized norbornene bearing dimethyl carboxylate groups

Three novel functionalized polynorbornenes (PNB) with pendant dimethyl carboxylate group (carboxylates—acetate, propionate, and butyrate) are synthesized as a vinyl‐type with a palladium (II) catalyst in high yield. The effects of size of substitutents, molar ratio of monomer to catalyst, solvent polarity, reaction time, and temperature on the polymerization of exo‐norbornene dimethyl propionate were systematically investigated. The low molar ratio and temperature, as well as high polarity of solvent, and long reaction time, are favorable for the enhancement of the monomer conversion, especially, the solvent have an obvious effect on the catalyst activity. The resulting poly(cis‐norbornene‐exo‐2,3‐dimethyl carboxylates) (PNB‐dimethyl carboxylates) show good solubility in common organic solvent and high thermal stability up to 360 °C. The glass transition temperature was detected by DMA at 331, 324, and 318 °C for acetate, propionate, and butyrate, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3391–3399, 2007     

Evaluation of compatibility in polymer blend systems by simultaneous DSC-FTIR measurement

The concept of crystallization dynamics method evaluating the miscibility of binary blend system including crystalline component was proposed. Three characteristic rates, nucleation, crystal growth rates (N*, G*) and growth rate of conformation (G _c*) were used to evaluate the miscibility of PVDF/at-PMMA and PVDF/iso-PMMA by the simultaneous DSC-FTIR. N*, G* and G _c* depended remarkably on both temperature and blend fraction (ϕ_PMMA) for PVDF/at-PMMA system, which indicated the miscible system. PVDF/iso-PMMA showed small ϕ_PMMA dependency of N*, G* and G _c*, was estimated the immiscible system. The ΔT/T _m⁰ values, corresponding to Gibbs energy required to attend the constant G* and G _c*, evaluated from G* and G _c* showed the good linear relationships with different slope. The experimental results suggested that the concentration fluctuation existed in PVDF/iso-PMMA system.     

ON THE QUOTIENT RING OF COMMUTATIVE RINGS WITH ACC^{\perp}ON ANNIHILATOR IDEALS.

The author concludes that every commutative ring with ascending chain condition an annihilator ideals has a Kasch quotient ring, which generalizes the Theorem^{[1]} that every commutative noetherian ring has a Kasch quosient ring. If follows that if R is a commutative ting with acc^{\perp}，then that Q(R) is semiprimary is equivalent to that it is perfect, or to that R satisfies regular condition. Besides, that Q(R) is quasi-frobenius equals that Q(R) is FPF or PF, and that Q(R) is artinian equals that R/N, are of finite dimension, i=1,2,\ldots,n. N_{i}=J^{i}\cap R.     

ICP-AES中Ca、Al之间相互干扰的研究

本文在不同条件下比较详细地研究了Ca与Al在ICP-AES中的相互干扰,结果表明:这种干扰的垂直空间分布与其它元素的基体效应不同,特别在低观察区域Ca、Al之间呈现较为明显的相互抑制效应,说明Ca和Al之间产生了溶质挥发干扰。对分析条件特别是入射功率、载气流量及观察高度进行最优化可以使这种干扰减至最小。     

A necessary and sufficient condition of existence of positive solutions for nonlinear singular differential systems

In this paper, by means of monotone iterative technique, a necessary and sufficient condition of the existence of positive solution for a class of nonlinear singular differential system is established, the results of the existence and uniqueness of the positive solution and the iterative sequence of solution are given. In the end, two classes extending boundary value differential systems are discussed and some further results are obtained.     

Impoverishment of Soil Nutrients in Gully Erosion Areas in Yuanmou Basin

The impoverishment of soil nutrients of nine gully head areas in Yuanmou Basin is assessed through an integrated evaluation method established on the basis of Fuzzy mathematics and multivariate mathematical theory. Results show that soil erosion of gully erosion area in Yuanmou basin has resulted in severe impoverishment of soil nutrients. All gully head areas are at high leves of impoverishment except for one at middle. By probing into and analyzing the mechanism of impoverishment of soil nutrients, we find that soil erosion has led to impoverishment of soil nutrients in a way of compacting soil, heightening position of obstacle horizon, and reducing the content of organic matter, as well as the direct loss of nutrient elements. Finally, this paper points out that soil and water conservation arming at the prevention of soil erosion is the most effective way against impoverishment of soil nutrients in Yuanmou basin.