A new preparative column for the vortex counter-current chromatograph was fabricated by making many (966) cylindrical separation units to a high-density polyethylene disk and then threading them with 6–40 taps. The resulting column had a total capacity of 364 mL. The performance of this vortex column was examined with three different two-phase solvent systems each using a set of suitable test samples: hexane–ethyl acetate–methanol–0.1 M hydrochloric acid (1:1:1:1, v/v) for the separation of DNP-amino acids; 1-butanol–acetic acid–water (4:1:5, v/v) for the separation of dipeptides; and hexane–acetonitrile–water (20:15:2, v/v) for the separation of Sudan dyes. Most of the separations show high partition efficiency of over a thousand theoretical plates, as expected based on the results previously obtained in preliminary separations with a small column. Overall, the results of the present study suggest that further improvement of the partition efficiency can be obtained by the modifying column configuration.
Two new meroterpenes, ‘acetoxydehydroaustin B’ ( 1 ) and ‘1,2‐dihydro‐acetoxydehydroaustin B’ ( 2 ) were isolated in the form of a mixed crystal from the mangrove endophytic fungus Aspergillus sp. 085241B. Their structures and absolute configurations were determined by extensive analysis of their spectra and X‐ray diffraction data. In a preliminary bioassay, the mixed crystal did not exhibit activities against cancer cell lines of MDA‐MB‐435, SKBR3, HepG2, HEP3B, PC‐3, and A549, as well as against α‐glucosidase and tyrosinase. 相似文献
In the crystal structure of the title compound, C12H10N4, the pyridine ring makes a dihedral angle of 1.12 (9)° with the mean plane of the complete almost planar and crystallographically centrosymmetric molecule. There are stacks of parallel molecules along the a‐axis direction, with alternate stacks having a herring‐bone arrangement relative to each other and an interplanar spacing of 3.551 Å. 相似文献
The states of S species in black shales are very complex, such as organic sulfur, pyrite sulfur and sulphate sulfur. The mineral
microtexture, sulfur content and sulfur isotope can indicate the formation conditions and diagenetic processes of the black
shales. The S species are separated perfectly and the relation between the content, mineral microtexture and sulfur isotope
composition of the sulfur mineral is assessed. These complementary approaches provide people a new insight into the formation
conditions of the black shales and redox conditions of Precambrian and Cambrian in Southwest China. 相似文献
Many applications of histogram-based techniques for the purposes of image enhancement are well known. However, these techniques often fail to produce satisfactory results for a broad variety of low-contrast images (e.g., X-ray images). In this paper, we propose a new form of histogram for image contrast enhancement. The input image is first divided into several equal-sized regions according to the intensities of gradients, their corresponding statistical values of gray levels are then modified respectively, and finally the processed histogram for the whole image is obtained by the summation of all the weighted values of regions. The fundamental characteristic of this new form of histogram is that the amplitudes of its components can objectively reflect the contribution of the gray levels to the representation of image information. Accordingly, this new histogram is called gray-level information histogram. The performance of many histogram-based enhancement techniques might be improved dramatically using the proposed histogram. Testing on the X-ray images validates the effectiveness of the new histogram. 相似文献
A new 4d–4f coordination polymer, [AgGd(pyzc)2(ox)·H2O)] (1) [pyzc = Pyrazine-2-carboxylate, ox = oxalate] has been successfully synthesized under hydrothermal conditions and structurally
determined by single-crystal X-ray diffraction, and characterized by elemental analysis, infrared spectroscopy, thermogravimetric
analysis and power X-ray diffraction. Single-crystal X-ray analysis reveals that it crystallizes in the monoclinic space group
P21/c with a = 10.0746(1) ?, b = 18.642(1) ?, c = 8.0525(2) ?, β = 112.470(1)°, Mr = 617.34, Z = 4, V = 1505.6(2) ?3, μ = 5.732, F(000) = 1164. The Gd(III) ion is nine-coordinated by two O-donors and two N-donors of two different chelating pyzc ligands,
four O-donors of two different chelating oxalate ligands, and one O-donor of another carboxylate group of one pyzc ligand.
The compound represents a 3D microporous polymeric network constructed by gadolinium–oxalate chains and Ag-pyzc subunits. 相似文献