All-silicon chiral metasurfaces and wavefront shaping assisted by interference

The usage of full-color imaging in digital pathology produces significant results. Compared with a grayscale image or a pseudocolor image containing contrast information, a full-color image can identify and detect the target object better with color texture information. Fourier ptychographic microscopy(FPM) is a high-throughput computational imaging technique that breaks the tradeoff between high resolution(HR) and a large field of view. It also eliminates the artifacts of scanning and stitching in digital pathology and improves its imaging efficiency. However, the conventional full-color digital pathology based on FPM is still time-consuming because of the repeated experiments with tri-wavelengths. A color transfer FPM approach termed "CFPM" was reported. The color texture information of a low-resolution full-color pathologic image is directly transferred to the HR grayscale FPM image captured by only a single wavelength. Both of the color space of FPM based on the standard CIE-XYZ color model and the display based on the standard RGB color space were established. Different FPM colorization schemes were analyzed and compared with 30 biological samples. Three types of evaluation approaches were provided, including the root-mean-square error(RMSE), the difference maps, and the image histogram cosine similarity. The average RMSE values of the conventional method and CFPM compared with the ground truth were 5.3% and 5.7%, respectively. Therefore, the reconstruction time is significantly reduced by 2/3 with the sacrifice of precision of only 0.4%. The CFPM method is also compatible with advanced fast FPM approaches to further reduce computation time.     

Comparison of the solutions from a novel variational method with numerical results for the study of beam propagation in a Kerr medium with nonlinear absorption

We present results from a novel variational method for the study of beam propagation in a Kerr medium with nonlinear absorption. This new method combines the variational method and a nonlinear absorption equation and gives a concise expression for the combination. The results obtained with this method show good quantitative agreement with numerical solutions obtained with the finite-difference method. It is shown that the variational method takes much less time than a numerical simulation with the finite-difference method for analysis of beam propagation in a thick medium with nonlinear absorption and nonlinear refraction. The new method makes detailed analysis of beam propagation in a Kerr medium with nonlinear absorption very simple and fast.     

毛细管电泳法分离联萘酚对映体

利用新的手性选择剂苄基氯化辛可宁，在非水相中成功地分离了联萘酚的对映体，并对分离的机理作了初步地探讨。     

cis‐Di­chloro­(di­methyl­aminomethyl­ene)­(tri­phenyl­phosphine)palladium(II) acetone solvate

The synthesis and X‐ray structural analysis of the title compound, [PdCl₂(C₃H₇N)(C₁₈H₁₅P)]·C₃H₆O, are described. The crystal structure contains discrete monomeric mol­ecules of the carbene complex and solvent mol­ecules separated by normal van der Waals distances. The Pd atom is four‐coordinate in an essentially square‐planar environment, with the chlorine ligands mutually cis; Pd—P = 2.2495 (7), Pd—Cl = 2.3508 (7) and 2.3600 (7), Pd—C 1.948 (2) and N—C(carbene) 1.274 (3) Å.     

Photo-Activated Circularly Polarized Luminescence Film Based on Aggregation-Induced Emission Copper(I) Cluster-Assembled Materials

In this study, a pair of chiral copper(I) cluster-assembled materials (R/S- 2 ) was prepared, exhibiting unique photo-response characteristics with a concentration-wavelength correlation property in DMSO solution. By the combination of R/S- 2 with a polymethyl methacrylate (PMMA) matrix, the first photo-activated circularly polarized luminescence (CPL) film was developed, the CPL signal (g_lum=9×10⁻³) of which could be induced by UV light irradiation. Moreover, the film exhibited a reversible photo-response and extremely good fatigue resistance. Mechanism study revealed that the photo-response properties of the R/S- 2 solution and film are attributed to the aggregation-induced emission (AIE) characteristics of R/S- 2 and a photo-induced deoxygenation process. This study enriches the types of luminescent cluster-assembled molecules and provides a new strategy for the construction of metal cluster-based stimuli-responsive composite materials.     

Rapid finding and quantification of the major antioxidant in water extracts of three marine drug organisms from China by online HPLC-DAD/MS-DPPH

A method based on high-performance liquid chromatography (HPLC) with diode array detector coupled with electrospray ionisation-mass spectrometry and an online detection system for radical scavenging was established and used to rapidly find and quantify antioxidant compounds in the water extracts of Hippocampus japonicus Kaup, Hippocampus kuda Bleeker and Syngnathus acus Linnaeus. The online screening results revealed the presence of one major radical scavenging compound identified as hypoxanthine by comparison of mass data and retention time with the standard. Subsequently, the developed HPLC method was applied to quantify hypoxanthine in different H. japonicus, H. kuda and S. acus samples. The results indicated that the developed HPLC method is simple and reliable for the quantification of hypoxanthine with a detection limit at 0.002 μg mL(-1), and a high recovery from 96.3% to 102.1%. This method provides a powerful tool for rapid identification and quantification of free radical scavenging compounds in complex marine natural products.     

Studies on the thermodynamics of solvent extraction of indium (III) with HDEHMTPCA

The equilibrium molalities In³⁺ in {In₂(SO₄)₃ + Na₂SO₄ + HDEHMTPCA + n-C₈H₁₈ + water} were measured at ionic strength from (0.1 to 2.0) mol · kg⁻¹ containing Na₂SO₄ as supporting electrolyte in aqueous phase and at constant molality extractant at temperatures from (278.15 to 303.15) K in organic phase. The standard extraction constants K⁰ at various temperatures were obtained by methods of extrapolation and polynomial approximation. Thermodynamic quantities for the extraction process were calculated.     

杯芳烃及其衍生物在色谱和毛细管电泳中的应用

杯芳烃是由多个苯酚在2,6位与亚甲基相连形成的大环化合物,具有分子识别功能,是继环糊精和冠醚之后第三代主体分子,它在现代分离科学中有着广泛的应用,本文综述了近年来杯芳烃及其衍生物在色谱和毛细管电泳中的应用进展。     

巯基乙酸锑(Ⅲ)配合物合成与晶体结构

以三氧化二锑和巯基乙酸在水溶液中反应合成了配合物HSb(SCH2COO)2,并通过元素分析、红外光谱、X射线粉末衍射进行了表征,利用单晶X射线四圆衍射法测定了晶体结构,结果表明该配合物晶体属于单斜晶系,C2/c空间群,晶胞参数为:a=1.40005(8)nm,b=1.19121(8)nm,c=1.23588(8)nm,β=126.822(1)°,V=1.6499(2)nm^3,Dc=2.439g·cm^-3,Z=8,R1=0.0250。并对X射线粉末衍射数据进行了指标化,其结果与单晶数据吻合。