全文获取类型
收费全文 | 26525篇 |
免费 | 2839篇 |
国内免费 | 3334篇 |
专业分类
化学 | 10841篇 |
晶体学 | 223篇 |
力学 | 882篇 |
综合类 | 239篇 |
数学 | 1995篇 |
物理学 | 5484篇 |
综合类 | 13034篇 |
出版年
2024年 | 58篇 |
2023年 | 255篇 |
2022年 | 494篇 |
2021年 | 617篇 |
2020年 | 587篇 |
2019年 | 628篇 |
2018年 | 602篇 |
2017年 | 621篇 |
2016年 | 855篇 |
2015年 | 1062篇 |
2014年 | 1419篇 |
2013年 | 1705篇 |
2012年 | 1836篇 |
2011年 | 2078篇 |
2010年 | 1847篇 |
2009年 | 1903篇 |
2008年 | 2080篇 |
2007年 | 1973篇 |
2006年 | 1788篇 |
2005年 | 1644篇 |
2004年 | 1296篇 |
2003年 | 1187篇 |
2002年 | 1443篇 |
2001年 | 1196篇 |
2000年 | 890篇 |
1999年 | 620篇 |
1998年 | 348篇 |
1997年 | 312篇 |
1996年 | 270篇 |
1995年 | 179篇 |
1994年 | 164篇 |
1993年 | 141篇 |
1992年 | 112篇 |
1991年 | 100篇 |
1990年 | 94篇 |
1989年 | 76篇 |
1988年 | 64篇 |
1987年 | 45篇 |
1986年 | 22篇 |
1985年 | 21篇 |
1984年 | 7篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 14篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1974年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
12.
利用樊福卓构造的地区专业化综合指数,结合1998—2012年度安徽省17个主要城市15个产业对安徽省地区近年来的专业化程度进行度量,分析安徽省的地区专业化特征,为安徽省产业布局提供新的理论思路。 相似文献
13.
Cuixia Cui Yong Gao Dr. Jun Li Chao Yang Meng Liu Prof. Dr. Huile Jin Prof. Dr. Zhenhai Xia Prof. Dr. Liming Dai Prof. Dr. Yong Lei Prof. Dr. Jichang Wang Prof. Dr. Shun Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(20):8002-8007
Although tremendous efforts have been devoted to understanding the origin of boosted charge storage on heteroatom-doped carbons, none of the present studies has shown a whole landscape. Herein, by both experimental evidence and theoretical simulation, it is demonstrated that heteroatom doping not only results in a broadened operating voltage, but also successfully promotes the specific capacitance in aqueous supercapacitors. In particular, the electrolyte cations adsorbed on heteroatom-doped carbon can effectively inhibit hydrogen evolution reaction, a key step of water decomposition during the charging process, which broadens the voltage window of aqueous electrolytes even beyond the thermodynamic limit of water (1.23 V). Furthermore, the reduced adsorption energy of heteroatom-doped carbon consequently leads to more stored cations on the heteroatom-doped carbon surface, thus yielding a boosted charge storage performance. 相似文献
14.
Sung Hwan Koo Dong Jun Li Taeyeong Yun Dong Sung Choi Kyung Eun Lee Gil Yong Lee Youngtak Oh Joonwon Lim Suchithra Padmajan Sasikala Ho Jin Lee In Ho Kim Hong Ju Jung Rishabh Jain Sang Ouk Kim 《Particle & Particle Systems Characterization》2019,36(7)
Efficient water electrolysis catalyst is highly demanded for the production of hydrogen as a sustainable energy fuel. It is reported that cobalt derived nanoparticle (CoS2, CoP, CoS|P) decorated reduced graphene oxide (rGO) composite aerogel catalysts for highly active and reliable hydrogen evolution reaction electrocatalysts. 7 nm level cobalt derived nanoparticles are synthesized over graphene aerogel surfaces with excellent surface coverage and maximal expose of active sites. CoS|P/rGO hybrid aerogel composites show an excellent catalytic activity with overpotential of ≈169 mV at a current density of ≈10 mA cm?2. Accordingly, efficient charge transfer is attained with Tafel slope of ≈52 mV dec?1 and a charge transfer resistance (Rct) of ≈12 Ω. This work suggests a viable route toward ultrasmall, uniform nanoparticles decorated graphene surfaces with well‐controlled chemical compositions, which can be generally useful for various applications commonly requiring large exposure of active surface area as well as robust interparticle charger transfer. 相似文献
15.
Hejia Hu Linlin Wu Mei Li Cun Xue Guangcheng Wang Siying Chen Yong Huang Lin Zheng Aimin Wang Yueting Li Zipeng Gong 《Biomedical chromatography : BMC》2020,34(1):e4714
Eucommia ulmoides Oliv. (E. ulmoides) is a valuable and nourishing medicinal herb in China that has been used in the treatment of hypertension. Given the fact that most traditional Chinese medicine is mainly used to treat disease, investigating the pharmacokinetics of traditional Chinese medicines in the pathological state is more useful than that in the normal state. However, the differences in the absorption kinetics of active ingredients of E. ulmoides extract between pathological and physiological conditions have not been reported. Therefore, in this study, the rat intestinal in situ circulatory perfusion model was used to investigate the differences in absorption kinetics of seven active ingredients of E. ulmoides extract in normal and spontaneously hypertensive rats, namely, genipinic acid, protocatechuic acid, neochlorogenic acid, chlorogenic acid, cryptochlorogenic acid, (+)-pinoresinol di-O-β-D -glucopyranoside and (+)-pinoresinol 4′-O-β-D -glucopyranoside. Our results indicate that the pathological state of spontaneous hypertension may change the absorption of active components of E. ulmoides extracts, and these findings may provide a reference for improving the rational use of E. ulmoides in the clinic. 相似文献
16.
Guangrui Chen Yuxing Yan Dr. Jie Wang Prof. Yong Sik Ok Guiyuan Zhong Prof. Bu Yuan Guan Prof. Yusuke Yamauchi 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(44):19831-19836
Mesoporous core–shell nanostructures with controllable ultra-large open channels in their nanoshells are of great interest. However, soft template-directed cooperative assembly to mesoporous nanoshells with highly accessible pores larger than 30 nm, or even above 50 nm into macroporous range, remains a significant challenge. Herein we report a general approach for precisely tailored coating of hierarchically macro-/mesoporous polymer and carbon shells, possessing highly accessible radial channels with extremely wide pore size distribution from ca. 10 nm to ca. 200 nm, on diverse functional materials. This strategy creates opportunities to tailor the interfacial assembly of irregular mesostructured nanounits on core materials and generate various core–shell nanomaterials with controllable pore architectures. The obtained Fe,N-doped macro-/mesoporous carbon nanoshells show enhanced electrochemical performance for the oxygen reduction reaction in alkaline condition. 相似文献
17.
The use of supercritical fluid carbon dioxide (SF-CO_2) in extraction of lanolin and its alcohol issuperior to the conventional solvent extractionmethod. Its distinctive advantages include highextractive ratio, nontoxic and nonflammablesolvents, and minimal by-product pollution. The 相似文献
18.
根据塔机起重臂的实际结构 ,建立双弹簧悬吊超静定简支梁的力学模型 ,进行动态分析 ,并以TC80型塔式起重机为例 ,利用有限元方法求解 ,引入梁单元和边界单元 ,得到塔机起重臂的多阶固有频率和主振型 ,其结果对于塔机的动态响应分析具有实际意义 相似文献
19.
解勇 《科技情报开发与经济》2004,14(4):241-242
侯马铁路北站担负着南同蒲、侯月、侯西线到发货物列车的改编和中转作业,随着南同蒲、侯月、侯西线不断增量,侯北站堵塞情况时有发生。强化调度指挥,优化运输组织,提高无调中转比重,对侯北枢纽畅通至关重要。 相似文献
20.
国民经济动员中医护人员组成形式数据建模 总被引:1,自引:0,他引:1
提出一种医护人员在国民经济动员中组合形式的解决方案,并由此建立数据模型。用UML对已建立的模型进行描述并加以改进,便于系统的实现。 相似文献