Synthesis and micellization of amphiphilic poly(sebacic anhydride)–poly(ethylene glycol)–poly(sebacic anhydride) block copolymers

Amphiphilic biodegradable block copolymers [poly(sebacic anhydride)–poly(ethylene glycol)–poly(sebacic anhydride)] were synthesized by the melt polycondensation of poly(ethylene glycol) and sebacic anhydride prepolymers. The chemical structure, crystalline nature, and phase behavior of the resulting copolymers were characterized with ¹H NMR, Fourier transform infrared, gel permeation chromatography, and differential scanning calorimetry. Microphase separation of the copolymers occurred, and the crystallinity of the poly(sebacic anhydride) (PSA) blocks diminished when the sebacic anhydride unit content in the copolymer was only 21.6%. ¹H NMR spectra carried out in CDCl₃ and D₂O were used to demonstrate the existence of hydrophobic PSA domains as the core of the micelle. In aqueous media, the copolymers formed micelles after precipitation from water‐miscible solvents. The effects on the micelle sizes due to the micelle preparation conditions, such as the organic phase, dropping rate of the polymer organic solution into the aqueous phase, and copolymer concentrations in the organic phase, were studied. There was an increase in the micelle size as the molecular weight of the PSA block was increased. The diameters of the copolymer micelles were also found to increase as the concentration of the copolymer dissolved in the organic phase was increased, and the dependence of the micelle diameters on the concentration of the copolymer varied with the copolymer composition. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1271–1278, 2006     

Degradation of 4-chlorophenol in aqueous solution by γ-radiation and ozone oxidation

The application of radiation technology in the en-vironmental protection was listed as one of the mostimportant research fields by the International AtomicEnergy Agency (IAEA) for the peaceful use of nuclearenergy. It has great research value and potential appli-cation. Because of their broad-spectrum antimicrobialproperties, Cholophenols (CPs) have been used aspreservative agents for wood, paints, vegetable fibersand leather and as disinfectants. In addition, they havebeen widely employed…     

一种新型频域均衡器在水声通信中的应用

在传统频域均衡器的基础上,结合多载波频移键控调制方式的频谱结构,利用接收信号和参考信号的相关性及均衡器的滤波系数,提出了一种兼具均衡与解调功能的新型频域均衡器结构.该均衡器简单、有效地克服了水声信道中多径传播产生的码间干扰和频率选择性衰落等问题,简化了水声通信系统接收机的复杂度. 新型频域均衡器的解调原理以非相关解调算法为基础,但由于利用了均衡器的计算结果,其差错性能优于传统的非相关解调算法,计算机仿真试验表明,改进后的方法使差错性能提高了2 dB;实际水声通信实验表明,该均衡器能够有效地提高水声通信系统的可靠性,具有很好的应用前景.     

代数基本定理的另一证明

在复变函数论中,用了两种不同的方法证明了代数基本定理。文章从另一种角度:用映射的观点证明该定理。     

干部、人事档案的动态材料收集浅议

干部、人事档案是组织考察、使用干部的主要依据之一,是干部工作的重要组成部分,而干部、人事档案又是在动态管理之中产生的.因此,必须加强对干部、人事档案工作的领导,明确责任,严格审查,认真核对,确保干部、人事档案收集及时、完整真实.     

鲁北地区商周时期的海盐业

采用XRD和XRF分析测试方法，研究了山东省渤海湾地区滨州市阳信县李屋遗址和寿光市大荒北央遗址出土的商代晚期的陶器——盔形器及附着土壤．样品的Na元素和Cl元素XRF分析结果表明：李屋遗址和大荒北央遗址出土的盔形器的含盐量明显高于其他样品，显示这二地的盔形器与早期海盐生产有关．李屋遗址出土的盔形器表面附着土样用去离子水过滤后，滤液结晶体的XRD分析结果，进一步表明该盔形器是商周时期渤海湾地区海盐生产的器物．大荒北央遗址出土的盔形器的内壁沉淀物与长江三峡中坝遗址出土的花边陶釜的内壁沉淀物具有基本相同的物相，这进一步表明其与海盐生产有关．     

对现代财务报表的探讨

现代财务报表主要包括资产负债表和损益表。它们在日常经济工作中发挥着越来越重要的作用，但是它们不可能将企业的全部经济情况都反映出来。了解和关注现代财务报表所反映的问题，有利于我们对企业的发展状况做出正确评价，避免决策失误和利益损失，并对财务报表给予足够重视，使之能够更确切地全面反映企业的真实情况。     

折衷范式下我国商业银行国际化分析

文章从国际生产的角度分析了银行业的国际化,并在邓宁的折衷范式下具体阐述了我国商业银行进行对外直接投资所具有的所有权优势、区位优势和内部化优势.认为我国的商业银行已具备了这三个方面较强的优势,随着我国经济的发展和非金融企业对外投资的增加,其对外直接投资规模会不断扩大,但政府也需为其营造一个有利的环境.     

水稻苯达松敏感致死基因的RAPD标记的克隆及测序

用3S Spin DNA Agarose Gel Purification Kit试剂盒将与水稻苯达松敏感致死基因相连锁的RAPD遗传标记S20—420和S316—600回收纯化，连接于pGEM—T载体并克隆测序，得到了S20—420和S316—600的全序列，其长度分别为423bp、606bp．将两端序列设计特异PCR扩增引物可用于检测水稻苯达松敏感致死基因和标记辅助育种．